Chemistry: Structure and Properties Plus Mastering Chemistry with Pearson eText -- Access Card Package (2nd Edition) (New Chemistry Titles from Niva Tro)
2nd Edition
ISBN: 9780134436524
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 21, Problem 120E
Interpretation Introduction
To determine:
The missing reactant, product and reagents in the given organic reaction for one
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The reaction sequence shown in Scheme 5 demonstrates the synthesis of a
substituted benzene derivative Q.
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NH2
NaNO2, HCI
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CHINO₂
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O
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Scheme 5
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(i)
Draw the structure of intermediate O.
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(ii) Draw the mechanism for the transformation of aniline N to intermediate O.
Spoilage
(b)
[6 marks]
(iii) Identify the reagent X used to convert compound O to the iodinated compound
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P.
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(iv) Identify the possible structures of compound Q.
[2 marks]
[2 marks]
[shom 2]
(v)
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Draw the mechanism for the transformation of intermediate P to compound Q.
[5 marks]
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(vi) Account for the regiochemical outcome observed in the reaction forming
compound Q.
[3 marks]
PROBLEM 4 Solved
Show how 1-butanol can be converted into the following compounds:
a.
PROBLEM 5+
b.
d.
-C=
N
Which alkene is the major product of this dehydration?
OH
H2SO4
heat
Chapter 21 Solutions
Chemistry: Structure and Properties Plus Mastering Chemistry with Pearson eText -- Access Card Package (2nd Edition) (New Chemistry Titles from Niva Tro)
Ch. 21 - Prob. 1ECh. 21 - Prob. 2ECh. 21 - Prob. 3ECh. 21 - Prob. 4ECh. 21 - Prob. 5ECh. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - What are the main classifications of hydrocarbons?...Ch. 21 - Prob. 9ECh. 21 - What are structural isomers? How do the properties...
Ch. 21 - Prob. 11ECh. 21 - Define each term related to optical isomerism:...Ch. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Explain geometric isomerism in alkenes. How do the...Ch. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Prob. 18ECh. 21 - Prob. 19ECh. 21 - Prob. 20ECh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Name each alkane.Ch. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Draw a structure for each alkane. a....Ch. 21 - Prob. 45ECh. 21 - Complete and balance each hydrocarbon combustion...Ch. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Name each alkene.Ch. 21 - Prob. 52ECh. 21 - Prob. 53ECh. 21 - Name each alkyne.Ch. 21 - Draw the correct structure for each compound. a....Ch. 21 - Prob. 56ECh. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - Prob. 61ECh. 21 - Prob. 62ECh. 21 - Prob. 63ECh. 21 - Prob. 64ECh. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Prob. 69ECh. 21 - Prob. 70ECh. 21 - Prob. 71ECh. 21 - Prob. 72ECh. 21 - Prob. 73ECh. 21 - Prob. 74ECh. 21 - Prob. 75ECh. 21 - Prob. 76ECh. 21 - Prob. 77ECh. 21 - Prob. 78ECh. 21 - Prob. 79ECh. 21 - Prob. 80ECh. 21 - Prob. 81ECh. 21 - Prob. 82ECh. 21 - Prob. 83ECh. 21 - Prob. 84ECh. 21 - Prob. 85ECh. 21 - Prob. 86ECh. 21 - Prob. 87ECh. 21 - Prob. 88ECh. 21 - Identify each organic compound as an alkane,...Ch. 21 - Identify each organic compound as an alkane,...Ch. 21 - Prob. 91ECh. 21 - Prob. 92ECh. 21 - Prob. 93ECh. 21 - Determine whether each pair of structures are...Ch. 21 - Prob. 95ECh. 21 - Prob. 96ECh. 21 - Classify each organic reaction as combustion,...Ch. 21 - Prob. 98ECh. 21 - Prob. 99ECh. 21 - Prob. 100ECh. 21 - Prob. 101ECh. 21 - Prob. 102ECh. 21 - Prob. 103ECh. 21 - Prob. 104ECh. 21 - Prob. 105ECh. 21 - Prob. 106ECh. 21 - Prob. 107ECh. 21 - Prob. 108ECh. 21 - Prob. 109ECh. 21 - Prob. 110ECh. 21 - Prob. 111ECh. 21 - Prob. 112ECh. 21 - Prob. 113ECh. 21 - Prob. 114ECh. 21 - Draw the structure and name a compound with the...Ch. 21 - Prob. 116ECh. 21 - Prob. 117ECh. 21 - Prob. 118ECh. 21 - Prob. 119ECh. 21 - Prob. 120ECh. 21 - Prob. 121ECh. 21 - Prob. 1SAQCh. 21 - Prob. 2SAQCh. 21 - Prob. 3SAQCh. 21 - Prob. 4SAQCh. 21 - Prob. 5SAQCh. 21 - Prob. 6SAQCh. 21 - Prob. 7SAQCh. 21 - Prob. 8SAQCh. 21 - Prob. 9SAQCh. 21 - Prob. 10SAQ
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