a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide Interpretation: Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity. Concept introduction: The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed. To arrange: Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Question

1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

Answer 1

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiCl

Answer 2

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Answer 3

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Answer 4

Question

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

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Answer 5

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Answer 6

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Answer 7

Chapter 20.SE, Problem 37AP

Interpretation Introduction

a) Magnesium acetate, magnesium hydroxide and methylmagnesium bromide

Interpretation:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

Answer 8

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Answer 9

Interpretation Introduction

b) Sodium benzoyate, sodium p-nitrobenzoate, sodium acetylide

Interpretation:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Sodium benzoyate, sodium p-nitrobenzoate and sodium acetylide are to be arranged in the increasing order of their basicity.

Answer 10

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Answer 11

Interpretation Introduction

c) Lithium hydroxide, lithium ethoxide, lithium formate

Interpretation:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Concept introduction:

The conjugate base of a strong acid is weaker. In other words, a strong acid will yield a weak base. The basicity of compounds will be reverse of the strength of acids from which they are formed.

To arrange:

Lithium hydroxide, lithium ethoxide and lithium formate are to be arranged in the increasing order of their basicity.

Answer 12

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Answer 23

Ch. 20.1 - Give IUPAC names for the following compounds:Ch. 20.1 - Draw structures corresponding to the following...Ch. 20.2 - Prob. 3P Ch. 20.2 - The Ka for dichloroacetic acid is 3.32 Ă— 10-2....Ch. 20.3 - Calculate the percentages of dissociated and...Ch. 20.4 - Which would you expect to be a stronger acid, the...Ch. 20.4 - Dicarboxylic acids have two dissociation...Ch. 20.4 - The pKa of p-cyclopropylbenzoic acid is 4.45. Is...Ch. 20.4 - Prob. 9P Ch. 20.5 - Prob. 10P

Solution Summary: The author explains that magnesium acetate, magnesium hydroxide and methylmagnesium bromide are to be arranged in the increasing order of their basicity.

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