Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 20.6, Problem 11P
Interpretation Introduction

Interpretation:

The isoprene units has to be marked in lycopene and β-carotene and has to detect the similarity in the way which squalene, lycopene and β-carotene are biosynthesized.

Concept Introduction:

Terpenes are made by joining five-carbon units, usually in a head to tail-fashion.

Monoterpenes are those terpenes with two isoprene units-have 10 carbons, sesquiterpenes have 15 carbons, diterpenes have 20 carbons, triterpenes have 30 carbons and tetraterpenes have 40 carbons.

Isopentenyl pyrophosphate (isoprene) is the five-carbon compound used for the biosynthesis of terpenes.

Isoprene unit:

  Essential Organic Chemistry (3rd Edition), Chapter 20.6, Problem 11P , additional homework tip  1

  Essential Organic Chemistry (3rd Edition), Chapter 20.6, Problem 11P , additional homework tip  2

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv
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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."
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