The combination of ester and Grignard reagent required for the formation of given tertiary alcohols is to be identified. Concept Introduction: The reaction between esters and Grignard reagent results in the formation of tertiary alcohols. In the first step of this reaction, nucleophilic attack of Grignard reagent takes place on the carbonyl carbon of ester and forms an intermediate. In the next step, removal of leaving group takes place from the intermediate which results in the formation of a ketone . Then, neuclophilic attack of Grignard reagent takes place on the carbonyl carbon of ketone followed by acidic hydrolysis which results in the formation of tertiary alcohol.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20.11, Problem 15P

Interpretation Introduction

Interpretation:

The combination of ester and Grignard reagent required for the formation of given tertiary alcohols is to be identified.

Concept Introduction:

The reaction between esters and Grignard reagent results in the formation of tertiary alcohols.

In the first step of this reaction, nucleophilic attack of Grignard reagent takes place on the carbonyl carbon of ester and forms an intermediate.

In the next step, removal of leaving group takes place from the intermediate which results in the formation of a ketone.

Then, neuclophilic attack of Grignard reagent takes place on the carbonyl carbon of ketone followed by acidic hydrolysis which results in the formation of tertiary alcohol.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Don't used hand raiting and don't used Ai solution

2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Complete the spectroscopy with structure

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20.11, Problem 15P

Interpretation Introduction

Interpretation:

The combination of ester and Grignard reagent required for the formation of given tertiary alcohols is to be identified.

Concept Introduction:

The reaction between esters and Grignard reagent results in the formation of tertiary alcohols.

In the first step of this reaction, nucleophilic attack of Grignard reagent takes place on the carbonyl carbon of ester and forms an intermediate.

In the next step, removal of leaving group takes place from the intermediate which results in the formation of a ketone.

Then, neuclophilic attack of Grignard reagent takes place on the carbonyl carbon of ketone followed by acidic hydrolysis which results in the formation of tertiary alcohol.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20.11, Problem 15P

Interpretation Introduction

Interpretation:

The combination of ester and Grignard reagent required for the formation of given tertiary alcohols is to be identified.

Concept Introduction:

The reaction between esters and Grignard reagent results in the formation of tertiary alcohols.

In the first step of this reaction, nucleophilic attack of Grignard reagent takes place on the carbonyl carbon of ester and forms an intermediate.

In the next step, removal of leaving group takes place from the intermediate which results in the formation of a ketone.

Then, neuclophilic attack of Grignard reagent takes place on the carbonyl carbon of ketone followed by acidic hydrolysis which results in the formation of tertiary alcohol.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 20.11, Problem 15P

Interpretation Introduction