Lehninger Principles of Biochemistry
Lehninger Principles of Biochemistry
7th Edition
ISBN: 9781464126116
Author: David L. Nelson, Michael M. Cox
Publisher: W. H. Freeman
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Chapter 20, Problem 8P
Summary Introduction

To determine: How venturicidin affects oxygen evolution in a suspension of well illuminated chloroplasts.

Introduction:

Venturicidin is an antifungal compound which inhibits the ATP synthesis from mitochondria. It inhibits the F0 present in ATP synthase enzyme and inhibits the ATP synthesis by oxidative phosphorylation mechanism.

Summary Introduction

To determine: Whether the answer change if the experiment were done in the presence of an uncoupling reagent such as 2,4-dinitrophenol (DNP).

Introduction:

Photophosphorylation could be uncoupled from the flow of electron by the uncoupling reagent like 2,4-dinitrophenol (DNP) which provides path for the proton transport through thylakoid membrane.

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Write the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.
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3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)
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