
(a)
Interpretation: Standard enthalpy of the reaction and change in standard entropy of the given reaction are to be determined and the temperature at which the change in standard Gibb’s energy is zero, is to be calculated.
Concept introduction: The standard enthalpy of the reaction is calculated by the formula,
The change in standard Gipp’s free energy of the reaction is calculated as,
To determine: Standard enthalpy of the reaction and change in standard entropy of the given reaction.
(a)

Answer to Problem 87CWP
Standard enthalpy of the reaction and change in standard entropy of the given reaction is
Explanation of Solution
Hydrogen gas is produced by reacting graphite with water.
The standard enthalpy of formation of
The standard enthalpy of formation of
The standard enthalpy of formation of
The standard enthalpy of the reaction is calculated by the formula,
Therefore, the above equation becomes,
Substitute the value of
Therefore, the standard enthalpy of the reaction is
The standard entropy of
The standard entropy of
The standard entropy of
The standard entropy of
The standard entropy change of the reaction is calculated by the formula,
Therefore, the above equation becomes,
Substitute the value of
Therefore, the standard entropy change of the reaction is
(b)
Interpretation: Standard enthalpy of the reaction and change in standard entropy of the given reaction are to be determined and the temperature at which the change in standard Gibb’s energy is zero, is to be calculated.
Concept introduction: The standard enthalpy of the reaction is calculated by the formula,
The change in standard Gipp’s free energy of the reaction is calculated as,
To determine: The temperature at which the change in standard Gipp’s energy of the given reaction is zero.
(b)

Answer to Problem 87CWP
The temperature at which the change in standard Gipp’s energy of the given reaction is zero is
Explanation of Solution
Given
The change in standard Gipp’s energy of the given reaction is zero.
Standard enthalpy of the reaction and change in standard entropy of the given reaction is
The change in standard Gipp’s free energy of the reaction is calculated as,
Substitute the value of
Therefore, the temperature at which the change in standard Gipp’s energy of the given reaction is zero is
Want to see more full solutions like this?
Chapter 20 Solutions
Chemistry
- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forwardIdentify the missing organic reactants in the following reaction: X + Y H+ two steps Note: This chemical equation only focuses on the important organic molecules in the reaction. Additional inorganic or small-molecule reactants or products (like H2O) are not shown. In the drawing area below, draw the skeletal ("line") structures of the missing organic reactants X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. Х :arrow_forwardDraw the mechanism of friedel-crafts acylation using acetyl chloride of m-Xylenearrow_forward
- Don't used hand raiting and don't used Ai solution and correct answerarrow_forwardH R Part: 1/2 :CI: is a/an electrophile Part 2 of 2 Draw the skeletal structure of the product(s) for the Lewis acid-base reaction. Include lone pairs and formal charges (if applicable) on the structures. 4-7: H ö- H Skip Part Check X :C1: $ % L Fi Click and drag to start drawing a structure. MacBook Pro & ㅁ x G 0: P Add or increase positive formal cha Save For Later Submit ©2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centearrow_forwardDraw the friedel-crafts acylation mechanism of m-Xylenearrow_forward
- Don't used hand raiting and don't used Ai solutionarrow_forward1. Base on this experimental results, how do you know that the product which you are turning in is methyl 3-nitrobenzoate(meta substituted product ) rather than either of the other two products? 2. What observation suggests that at least a small amount of one or both of the other two isomers are in the mother liquor?arrow_forwardExplain Huckel's rule.arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning





