
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
10th Edition
ISBN: 9781305957510
Author: ZUMDAHL, Steven S.; Zumdahl, Susan A.; DeCoste, Donald J.
Publisher: Cengage Learning
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Chapter 20, Problem 6Q
Interpretation Introduction
Interpretation: The structure of hard substance silicon carbide
Concept introduction: Silicon carbide
To propose: The structure of hard substance Silicon carbide
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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy
level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention
to your units.
A. What is the partition function for this system?
B. What are the populations of each level?
Now instead, consider a system with energy levels of 0 J mol
C. Now what is the partition function?
D. And what are the populations of the two levels?
E. Finally, repeat the second calculation at 500 K.
and 500 J mol 1 at 300 K.
F. What do you notice about the populations as you increase the temperature? At what temperature
would you expect the states to have equal populations?
30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in
class, but the partition function that describes the translational and rotational motion of a homonuclear
diatomic molecule is given by
Itrans (V,T) =
=
2πmkBT
h²
V
grot (T)
4π²IKBT
h²
Where h is Planck's constant and I is molecular moment of inertia.
The overall partition function is qmolec Qtrans qrot.
Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational
modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a
volume of 1 m³. Here is some useful data:
Moment of inertia:
I2 I 7.46 x 10-
45
kg m²
2
O2 I 1.91 x 101
-46
kg m²
K
for each reaction step.
Be sure to account for all bond-breaking and bond-making
steps.
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Chapter 20 Solutions
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
Ch. 20 - What are the two most abundant elements by mass in...Ch. 20 - Prob. 2RQCh. 20 - Prob. 3RQCh. 20 - What is the valence electron configuration for the...Ch. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Table 19-14 lists some common nitrogen compounds...Ch. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQ
Ch. 20 - Prob. 1QCh. 20 - Prob. 2QCh. 20 - Prob. 3QCh. 20 - Diagonal relationships in the periodic table exist...Ch. 20 - Prob. 6QCh. 20 - Prob. 7QCh. 20 - Prob. 8QCh. 20 - All the Group 1A (1) and 2A (2) metals are...Ch. 20 - Prob. 10QCh. 20 - Prob. 11QCh. 20 - The major industrial use of hydrogen is in the...Ch. 20 - Prob. 13QCh. 20 - Prob. 14QCh. 20 - Prob. 17ECh. 20 - Prob. 18ECh. 20 - Prob. 19ECh. 20 - Prob. 20ECh. 20 - Prob. 21ECh. 20 - Prob. 22ECh. 20 - Prob. 23ECh. 20 - Prob. 24ECh. 20 - Prob. 25ECh. 20 - Electrolysis of an alkaline earth metal chloride...Ch. 20 - Prob. 28ECh. 20 - Prob. 29ECh. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - Prob. 32ECh. 20 - Boron hydrides were once evaluated for possible...Ch. 20 - Prob. 34ECh. 20 - Prob. 35ECh. 20 - Prob. 36ECh. 20 - Prob. 37ECh. 20 - Prob. 38ECh. 20 - Prob. 39ECh. 20 - Prob. 40ECh. 20 - The following illustration shows the orbitals used...Ch. 20 - Prob. 42ECh. 20 - Silicon is produced for the chemical and...Ch. 20 - Prob. 44ECh. 20 - The compound Pb3O4 (red lead) contains a mixture...Ch. 20 - Prob. 46ECh. 20 - Prob. 47ECh. 20 - Prob. 48ECh. 20 - Prob. 49ECh. 20 - Prob. 50ECh. 20 - Prob. 51ECh. 20 - Prob. 52ECh. 20 - Prob. 53ECh. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - Phosphate buffers are important in regulating the...Ch. 20 - Prob. 57ECh. 20 - Trisodium phosphate (TSP) is an effective grease...Ch. 20 - Prob. 59ECh. 20 - Prob. 60ECh. 20 - Prob. 61ECh. 20 - Complete and balance each of the following...Ch. 20 - Prob. 63ECh. 20 - Prob. 64ECh. 20 - How can the paramagnetism of O2 be explained using...Ch. 20 - Describe the bonding in SO2 and SO3 using the...Ch. 20 - Write the Lewis structure for O2F2. Predict the...Ch. 20 - Give the Lewis structure, molecular structure, and...Ch. 20 - Prob. 69ECh. 20 - Prob. 70ECh. 20 - Prob. 71ECh. 20 - Prob. 72ECh. 20 - Prob. 73ECh. 20 - Prob. 74ECh. 20 - Prob. 75ECh. 20 - Prob. 76ECh. 20 - Prob. 77ECh. 20 - Prob. 78ECh. 20 - Prob. 79AECh. 20 - The inert-pair effect is sometimes used to explain...Ch. 20 - How could you determine experimentally whether the...Ch. 20 - Prob. 82AECh. 20 - Prob. 83AECh. 20 - Prob. 84AECh. 20 - Prob. 85AECh. 20 - Hydrazine is somewhat toxic. Use the following...Ch. 20 - Prob. 87AECh. 20 - Draw Lewis structures for the AsCl4+ and AsCl6...Ch. 20 - There are two forms of solid sulfur: rhombic and...Ch. 20 - Prob. 90AECh. 20 - Prob. 91AECh. 20 - What is a disproportionation reaction? Use the...Ch. 20 - Sulfur forms a wide variety of compounds in which...Ch. 20 - Prob. 94AECh. 20 - Prob. 95CWPCh. 20 - Prob. 96CWPCh. 20 - Prob. 97CWPCh. 20 - Prob. 98CWPCh. 20 - Prob. 99CWPCh. 20 - Nitrous oxide (N2O) can be produced by thermal...Ch. 20 - What is the hybridization of the central atom in...Ch. 20 - Prob. 102CWPCh. 20 - Prob. 103CWPCh. 20 - Prob. 104CWPCh. 20 - Prob. 105CPCh. 20 - Prob. 106CPCh. 20 - Lead forms compounds in the +2 and +4 oxidation...Ch. 20 - Prob. 108CPCh. 20 - Prob. 109CPCh. 20 - Prob. 110CPCh. 20 - You travel to a distant, cold planet where the...Ch. 20 - Prob. 112CPCh. 20 - Prob. 113CPCh. 20 - Provide a reasonable estimate for the number of...Ch. 20 - Prob. 116IPCh. 20 - Prob. 117IPCh. 20 - Although nitrogen trifluoride (NF3) is a thermally...Ch. 20 - While selenic acid has the formula H2SeO4 and thus...Ch. 20 - Prob. 120MPCh. 20 - Prob. 121MP
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