ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<
ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<
3rd Edition
ISBN: 9781119781448
Author: Klein
Publisher: WILEY
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Chapter 20, Problem 63PP
Interpretation Introduction

Interpretation:

The given starting compounds and reagents used to accomplish the target products transformation should be draw and identified.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Hydrolysis Reaction: This type of reaction involving the braking of a carbon-carbon triple, double bonds in a molecules using water.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π -bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

To identify: The synthetic route to accomplish the given transformation.

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3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomer
curved arrows are used to illustate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction mechanism steps

Chapter 20 Solutions

ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<

Ch. 20.5 - Prob. 11CCCh. 20.6 - Prob. 12CCCh. 20.6 - Prob. 13CCCh. 20.7 - Prob. 1LTSCh. 20.7 - Prob. 14PTSCh. 20.7 - Prob. 15ATSCh. 20.8 - Prob. 16CCCh. 20.8 - Prob. 17CCCh. 20.8 - Prob. 18CCCh. 20.9 - Prob. 19CCCh. 20.10 - Prob. 20CCCh. 20.10 - Prob. 21CCCh. 20.11 - Prob. 22CCCh. 20.11 - Prob. 23CCCh. 20.12 - Prob. 24CCCh. 20.12 - Prob. 25CCCh. 20.12 - Prob. 26CCCh. 20.13 - Prob. 27CCCh. 20.13 - Prob. 28CCCh. 20.13 - Prob. 29CCCh. 20.14 - Prob. 2LTSCh. 20.14 - Prob. 30PTSCh. 20.14 - Prob. 31ATSCh. 20.14 - Prob. 3LTSCh. 20.14 - Prob. 32PTSCh. 20.14 - Prob. 33ATSCh. 20.15 - Prob. 34CCCh. 20 - Prob. 35PPCh. 20 - Prob. 36PPCh. 20 - Prob. 37PPCh. 20 - Prob. 38PPCh. 20 - Prob. 39PPCh. 20 - Prob. 40PPCh. 20 - Prob. 41PPCh. 20 - Prob. 42PPCh. 20 - Prob. 43PPCh. 20 - Prob. 44PPCh. 20 - Prob. 45PPCh. 20 - Prob. 46PPCh. 20 - Prob. 47PPCh. 20 - Prob. 48PPCh. 20 - Prob. 49PPCh. 20 - Prob. 50PPCh. 20 - Prob. 51PPCh. 20 - Prob. 52PPCh. 20 - Prob. 53PPCh. 20 - Prob. 54PPCh. 20 - Prob. 55PPCh. 20 - Prob. 56PPCh. 20 - Prob. 57PPCh. 20 - Prob. 58PPCh. 20 - Prob. 59PPCh. 20 - Prob. 60PPCh. 20 - Prob. 61PPCh. 20 - Prob. 62PPCh. 20 - Prob. 63PPCh. 20 - Prob. 64PPCh. 20 - Prob. 65PPCh. 20 - Prob. 66PPCh. 20 - Prob. 67PPCh. 20 - Prob. 68PPCh. 20 - Prob. 69PPCh. 20 - Prob. 70IPCh. 20 - Prob. 72IPCh. 20 - Prob. 73IPCh. 20 - Prob. 74IPCh. 20 - Prob. 75IPCh. 20 - Prob. 76IPCh. 20 - Prob. 77IPCh. 20 - Prob. 78IPCh. 20 - Prob. 79IPCh. 20 - Prob. 80IPCh. 20 - Prob. 81IPCh. 20 - Prob. 82IPCh. 20 - Prob. 83IPCh. 20 - Prob. 84IPCh. 20 - Compound 3 (below) was used as an intermediate in...Ch. 20 - The m- and p-substituted methyl benzoates listed...Ch. 20 - Prob. 87IPCh. 20 - Prob. 88IPCh. 20 - Prob. 89IPCh. 20 - Prob. 90CPCh. 20 - Prob. 91CPCh. 20 - Prob. 92CPCh. 20 - Prob. 93CP
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