Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
expand_more
expand_more
format_list_bulleted
Videos
Question
Chapter 20, Problem 62P
Interpretation Introduction
Interpretation: The reason for giving different penalties to person A and B for taking steroids in their sports should be explained.
Concept Introduction:The characterization of steroids is done by the presence of four ring structures arranged in a specific configuration in the compound. They are found in the cell membrane and influence the fluidity of the membrane. They work by decreasing inflammation and reducing the activity of the immune system.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any.
If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers).
If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products.
If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each)
3. What starting material would you use to synthesize 3-hydroxypentanoic acid using a
NaBH4 reduction?
1. Give stereochemical (Fischer projection) formulas for all (but no extras) the
stereoisomers that could theoretically form during the reduction of
a. the carbonyl group of 2-methyl-3--pentanone
b. both carbonyl groups of 2,4-pentanedione (careful!)
2. Predict the products of the reduction of O=CCH2CH2CH2C=O with
a. LiAlH4
b. NaBH4
CH3
OH
Chapter 20 Solutions
Introduction to General, Organic and Biochemistry
Ch. 20.2 - Prob. 20.1QCCh. 20.4 - Prob. 20.2QCCh. 20.5 - Prob. 20.3QCCh. 20.7 - Prob. 20.4QCCh. 20.8 - Prob. 20.5QCCh. 20.9 - Prob. 20.6QCCh. 20.10 - Prob. 20.7QCCh. 20.13 - Prob. 20.8QCCh. 20 - Prob. 1PCh. 20 - 21-2 Why are fats a good source of energy for...
Ch. 20 - 21-3 Proteins, nucleic acids, and carbohydrates...Ch. 20 - Prob. 4PCh. 20 - Prob. 5PCh. 20 - Draw the line-angle structure for the following:...Ch. 20 - Prob. 7PCh. 20 - What is the difference between the -system and...Ch. 20 - Prob. 9PCh. 20 - Prob. 10PCh. 20 - Prob. 11PCh. 20 - Prob. 12PCh. 20 - For the diglycerides in Problem 12 , predict which...Ch. 20 - 21-8 Predict which acid in each pair has the...Ch. 20 - Prob. 15PCh. 20 - Prob. 16PCh. 20 - Prob. 17PCh. 20 - Prob. 18PCh. 20 - 21-13 Rank the following in order of increasing...Ch. 20 - Prob. 20PCh. 20 - Prob. 21PCh. 20 - Prob. 22PCh. 20 - Prob. 23PCh. 20 - Prob. 24PCh. 20 - Prob. 25PCh. 20 - Prob. 26PCh. 20 - Prob. 27PCh. 20 - Prob. 28PCh. 20 - 21-29 Name all the groups of complex lipids that...Ch. 20 - Prob. 30PCh. 20 - Prob. 31PCh. 20 - Prob. 32PCh. 20 - Prob. 33PCh. 20 - Prob. 34PCh. 20 - Prob. 35PCh. 20 - Prob. 36PCh. 20 - Prob. 37PCh. 20 - Prob. 38PCh. 20 - 21-39 How does VLDL become LDL?Ch. 20 - Prob. 40PCh. 20 - Prob. 41PCh. 20 - Prob. 42PCh. 20 - Prob. 43PCh. 20 - 21-44 Describe the difference in structure between...Ch. 20 - Prob. 45PCh. 20 - Prob. 46PCh. 20 - Prob. 47PCh. 20 - 21-48 List all of the functional groups that make...Ch. 20 - 21-49 Explain how the constant elimination of bile...Ch. 20 - Prob. 50PCh. 20 - Prob. 51PCh. 20 - 21-52 What are the chemical and physiological...Ch. 20 - 21-53 How does aspirin, an anti-inflammatory drug,...Ch. 20 - Prob. 54PCh. 20 - Prob. 55PCh. 20 - For each of the processes below, tell whether it...Ch. 20 - Prob. 57PCh. 20 - Prob. 58PCh. 20 - Prob. 59PCh. 20 - Prob. 60PCh. 20 - Prob. 61PCh. 20 - Prob. 62PCh. 20 - Prob. 63PCh. 20 - Prob. 64PCh. 20 - Prob. 65PCh. 20 - Prob. 66PCh. 20 - Prob. 67PCh. 20 - Prob. 68PCh. 20 - Prob. 69PCh. 20 - 21-68 What is the role of taurine in lipid...Ch. 20 - Prob. 71PCh. 20 - 21-70 How many different triglycerides can you...Ch. 20 - Prob. 73PCh. 20 - Prob. 74PCh. 20 - Prob. 75PCh. 20 - Prob. 76PCh. 20 - Prob. 77PCh. 20 - 21-76 Which part of LDL interacts with the LDL...Ch. 20 - Prob. 79PCh. 20 - Prob. 80PCh. 20 - Prob. 81PCh. 20 - Prob. 82PCh. 20 - Prob. 83PCh. 20 - 21-82 Suggest a reason why the same protein system...Ch. 20 - Prob. 85PCh. 20 - Prob. 86PCh. 20 - 21-85 Which of the following statements is (are)...Ch. 20 - Prob. 88PCh. 20 - 21-87 Which statements are consistent with the...Ch. 20 - Prob. 90PCh. 20 - Prob. 91PCh. 20 - 21-90 To what extent do lipids and carbohydrates...Ch. 20 - Prob. 93PCh. 20 - Prob. 94PCh. 20 - Prob. 95PCh. 20 - Prob. 96PCh. 20 - Prob. 97PCh. 20 - Prob. 98PCh. 20 - Prob. 99PCh. 20 - Prob. 100PCh. 20 - Prob. 101PCh. 20 - 21-100 What are the functions of a cell membrane?...Ch. 20 - 21-101 Glycerophospholipids tend to have both a...Ch. 20 - Prob. 104P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Which of the following compounds can be synthesized using one reaction from any alkene, as a major product? If it can be synthesized, propose a route, and you may use any other starting materials, reagents and solvents as needed. If you do not think that it can be synthesized as a major product from an alkene, explain in detail why.arrow_forwardDraw the stepwise mechanism (with arrow pushing)arrow_forwarda) Explain why product 1 is the kinetic product and product 2 is the thermodynamic product. b) Draw the reaction coordinate diagram for the reaction pathway generating each product. c) State the Arrhenius Equation and explain the terms with their physical significance. d) State and explain which reaction pathway has a higher rate constant. What happens to the rate constant if the temperature has increased?arrow_forward
- Part 1. Draw monomer units of the following products and draw their reaction mechanism 1) Bakelite like polymer Using: Resorcinol + NaOH + Formalin 2) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol 3) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium boratearrow_forwardUsing the table of Reactants and Products provided provide the correct letter that corresponds with the Carboxylic acid that is formed in the reaction below. 6 M NaOH Acid-workup WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES A) Pool of Reagents for Part B CI B) OH C) E) CI J) racemic F) K) OH N) OH P) G) OH D) HO H) L) M) HO Q) R) CI Aarrow_forwardIn the table below, the exact chemical structures for Methyl salicylate can be represented by the letter WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES CI B) A) E) Cl racemic F) J) CI K) N) OH P) Pool of Reagents for Part B OH OH G) L) OH D) HO H) M) HO Q) R) CIarrow_forward
- Draw the stepwise mechanism for the reactionsarrow_forwardPart I. a) Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone (3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forward3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below: Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life). 2 CH3 H NO2 NO2 3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s) H a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
SAR of Anticancer(Antineoplastic) Drug/ Alkylating agents/ Nitrogen Mustard; Author: Pharmacy Lectures;https://www.youtube.com/watch?v=zrzyK3LhUXs;License: Standard YouTube License, CC-BY