Interpretation:
The reaction given below is product-favored or not has to be determined.
2Al(s) + Cr2O3(s) → 2Cr(s) + Al2O3(s)
Concept Introduction:
In order to find whether the reaction is product-favored or not, ΔrG° value can be used. If the value of ΔrG° is negative, then the reaction is product-favored and if the value of ΔrG° is positive, then the reaction is not product-favored.
ΔrG° = ∑[(coefficient of product) × ΔfG°(product)] −∑[(coefficient of reactant) × ΔfG°(reactant)]

Explanation of Solution
Given reaction is,
2Al(s) + Cr2O3(s) → 2Cr(s) + Al2O3(s)
ΔrG° can be calculated as shown below,
ΔrG° = ∑[(coefficient of product) × ΔfG°(product)] −∑[(coefficient of reactant) × ΔfG°(reactant)]=2 ΔfG° {Cr(s)} + ΔfG° {Al2O3(s)} − 2 ΔfG° {Al(s)} − ΔfG° {Cr2O3(s)}=2(0) + (−1528.3 kJ/mol) − 2(0) −(−1058.1 kJ/mol)=−1528.3 kJ/mol + 1058.1 kJ/mol=−470.2 kJ/mol
As the value of ΔrG° is negative, the given reaction is product-favored.
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Chapter 20 Solutions
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