OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)
5th Edition
ISBN: 9781285460420
Author: John W. Moore; Conrad L. Stanitski
Publisher: Cengage Learning US
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Chapter 20, Problem 42QRT
Interpretation Introduction

Interpretation:

The reaction given below is product-favored or not has to be determined.

    2Al(s)+Cr2O3(s)2Cr(s)+Al2O3(s)

Concept Introduction:

In order to find whether the reaction is product-favored or not, ΔrG° value can be used.  If the value of ΔrG° is negative, then the reaction is product-favored and if the value of ΔrG° is positive, then the reaction is not product-favored.

  ΔrG°=[(coefficientofproduct)×ΔfG°(product)][(coefficientofreactant)×ΔfG°(reactant)]

Expert Solution & Answer
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Explanation of Solution

Given reaction is,

    2Al(s)+Cr2O3(s)2Cr(s)+Al2O3(s)

ΔrG° can be calculated as shown below,

ΔrG°=[(coefficientofproduct)×ΔfG°(product)][(coefficientofreactant)×ΔfG°(reactant)]=2ΔfG°{Cr(s)}+ΔfG°{Al2O3(s)}2ΔfG°{Al(s)}ΔfG°{Cr2O3(s)}=2(0)+(1528.3kJ/mol)2(0)(1058.1kJ/mol)=1528.3kJ/mol+1058.1kJ/mol=470.2kJ/mol

As the value of ΔrG° is negative, the given reaction is product-favored.

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Chapter 20 Solutions

OWLv2 for Moore/Stanitski's Chemistry: The Molecular Science, 5th Edition, [Instant Access], 1 term (6 months)

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