Owlv2 With Ebook, 1 Term (6 Months) Printed Access Card For Kotz/treichel/townsend/treichel's Chemistry & Chemical Reactivity, 10th
Owlv2 With Ebook, 1 Term (6 Months) Printed Access Card For Kotz/treichel/townsend/treichel's Chemistry & Chemical Reactivity, 10th
10th Edition
ISBN: 9781337791182
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 20, Problem 40PS
Interpretation Introduction

Interpretation: The amount of coal burnt to produce the given amount of SO2 has to be determined.

Concept introduction:

Enthalpy of combustion: At standard conditions when one mole of substance is burnt completely in presence of oxygen, the enthalpy change involved is called enthalpy of combustion.

ΔH0comb=nΔH0fproducts-nΔH0freactants

General unit conversion:

1Gg=1000ton

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C This question shows how molecular orbital (MO) theory can be used to understand the chemical properties of elemental oxygen O₂ and its anionic derivative superoxide Oz. a) Draw the MO energy diagram for both O2 and O2. Clearly label your diagram with atomic orbital names and molecular orbital symmetry labels and include electrons. Draw the Lewis structure of O2. How does the MO description of O2 differ from the Lewis structure, and how does this difference relate to the high reactivity and magnetic properties of oxygen? ) Use the MO diagram in (a) to explain the difference in bond length and bond energy between superoxide ion (Oz, 135 pm, 360 kJ/mol) and oxygen (O2, 120.8 pm, 494 kJ/mol).
Please draw
-Page: 8 nsition metal ions have high-spin aqua complexes except one: [Co(HO)₁]". What is the d-configuration, oxidation state of the metal in [Co(H:O))"? Name and draw the geometry of [Co(H2O)]? b) Draw energy diagrams showing the splitting of the five d orbitals of Co for the two possible electron configurations of [Co(H2O)]: Knowing that A = 16 750 cm and Пl. = 21 000 cm, calculate the configuration energy (.e., balance or ligand-field stabilization energy and pairing energy) for both low spin and high spin configurations of [Co(H2O)]. Which configuration seems more stable at this point of the analysis? (Note that 349.76 cm = 1 kJ/mol) Exchange energy (IT) was not taken into account in part (d), but it plays a role. Assuming exchange an occur within t29 and within eg (but not between tz, and ea), how many exchanges are possible in the low in configuration vs in the high spin configuration? What can you say about the importance of exchange energy 07

Chapter 20 Solutions

Owlv2 With Ebook, 1 Term (6 Months) Printed Access Card For Kotz/treichel/townsend/treichel's Chemistry & Chemical Reactivity, 10th

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