SMARTWORKS FOR CHEMISTRY: ATOMS FOCUSED
2nd Edition
ISBN: 9780393644777
Author: Gilbert
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Predicting the pr
Predict the major products of the following organic reaction:
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• Draw the major product, or products, of the reaction in the drawing area below.
• If there aren't any products, because no reaction will take place, check the box below the drawing area instead.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are
enantiomers.
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Chapter 20 Solutions
SMARTWORKS FOR CHEMISTRY: ATOMS FOCUSED
Ch. 20 - Prob. 20.1VPCh. 20 - Prob. 20.2VPCh. 20 - Prob. 20.3VPCh. 20 - Prob. 20.4VPCh. 20 - Prob. 20.5VPCh. 20 - Prob. 20.6VPCh. 20 - Prob. 20.7VPCh. 20 - Prob. 20.8VPCh. 20 - Prob. 20.9VPCh. 20 - Prob. 20.10VP
Ch. 20 - Prob. 20.11QACh. 20 - Prob. 20.12QACh. 20 - Prob. 20.13QACh. 20 - Prob. 20.14QACh. 20 - Prob. 20.15QACh. 20 - Prob. 20.16QACh. 20 - Prob. 20.17QACh. 20 - Prob. 20.18QACh. 20 - Prob. 20.19QACh. 20 - Prob. 20.20QACh. 20 - Prob. 20.21QACh. 20 - Prob. 20.22QACh. 20 - Prob. 20.23QACh. 20 - Prob. 20.24QACh. 20 - Prob. 20.25QACh. 20 - Prob. 20.26QACh. 20 - Prob. 20.27QACh. 20 - Prob. 20.28QACh. 20 - Prob. 20.29QACh. 20 - Prob. 20.30QACh. 20 - Prob. 20.31QACh. 20 - Prob. 20.32QACh. 20 - Prob. 20.33QACh. 20 - Prob. 20.34QACh. 20 - Prob. 20.35QACh. 20 - Prob. 20.36QACh. 20 - Prob. 20.37QACh. 20 - Prob. 20.38QACh. 20 - Prob. 20.39QACh. 20 - Prob. 20.40QACh. 20 - Prob. 20.41QACh. 20 - Prob. 20.42QACh. 20 - Prob. 20.43QACh. 20 - Prob. 20.44QACh. 20 - Prob. 20.45QACh. 20 - Prob. 20.46QACh. 20 - Prob. 20.47QACh. 20 - Prob. 20.48QACh. 20 - Prob. 20.49QACh. 20 - Prob. 20.50QACh. 20 - Prob. 20.51QACh. 20 - Prob. 20.52QACh. 20 - Prob. 20.53QACh. 20 - Prob. 20.54QACh. 20 - Prob. 20.55QACh. 20 - Prob. 20.56QACh. 20 - Prob. 20.57QACh. 20 - Prob. 20.58QACh. 20 - Prob. 20.59QACh. 20 - Prob. 20.60QACh. 20 - Prob. 20.61QACh. 20 - Prob. 20.62QACh. 20 - Prob. 20.63QACh. 20 - Prob. 20.64QACh. 20 - Prob. 20.65QACh. 20 - Prob. 20.66QACh. 20 - Prob. 20.67QACh. 20 - Prob. 20.68QACh. 20 - Prob. 20.69QACh. 20 - Prob. 20.70QACh. 20 - Prob. 20.71QACh. 20 - Prob. 20.72QACh. 20 - Prob. 20.73QACh. 20 - Prob. 20.74QACh. 20 - Prob. 20.75QACh. 20 - Prob. 20.76QACh. 20 - Prob. 20.77QACh. 20 - Prob. 20.78QACh. 20 - Prob. 20.79QACh. 20 - Prob. 20.80QACh. 20 - Prob. 20.81QACh. 20 - Prob. 20.82QACh. 20 - Prob. 20.83QACh. 20 - Prob. 20.84QA
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- Explanation O Conjugated Pi Systems Deducing the reactants of a Diels-Alder reaction Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? ? Δ If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. • If your answer is no, check the box under the drawing area instead. Click and drag to start drawing a structure. Xarrow_forwardDiels Alder Cycloaddition: Focus on regiochemistry (problems E-F) –> match + of thedienophile and - of the diene while also considering stereochemistry (endo).arrow_forwardHELP! URGENT! PLEASE RESOND ASAP!arrow_forward
- Question 4 Determine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267 First-order, k = 0.210 hour 1 First-order, k = 0.0912 hour 1 O Second-order, k = 0.590 M1 hour 1 O Zero-order, k = 0.0770 M/hour O Zero-order, k = 0.4896 M/hour O Second-order, k = 1.93 M-1-hour 1 10 ptsarrow_forwardDetermine the rate order and rate constant for sucrose hydrolysis. Time (hours) [C6H12O6] 0 0.501 0.500 0.451 1.00 0.404 1.50 0.363 3.00 0.267arrow_forwardDraw the products of the reaction shown below. Use wedge and dash bonds to indicate stereochemistry. Ignore inorganic byproducts. OSO4 (cat) (CH3)3COOH Select to Draw ઘarrow_forward
- Calculate the reaction rate for selenious acid, H2SeO3, if 0.1150 M I-1 decreases to 0.0770 M in 12.0 minutes. H2SeO3(aq) + 6I-1(aq) + 4H+1(aq) ⟶ Se(s) + 2I3-1(aq) + 3H2O(l)arrow_forwardProblem 5-31 Which of the following objects are chiral? (a) A basketball (d) A golf club (b) A fork (c) A wine glass (e) A spiral staircase (f) A snowflake Problem 5-32 Which of the following compounds are chiral? Draw them, and label the chirality centers. (a) 2,4-Dimethylheptane (b) 5-Ethyl-3,3-dimethylheptane (c) cis-1,4-Dichlorocyclohexane Problem 5-33 Draw chiral molecules that meet the following descriptions: (a) A chloroalkane, C5H11Cl (c) An alkene, C6H12 (b) An alcohol, C6H140 (d) An alkane, C8H18 Problem 5-36 Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. How H3C CH3 many chirality centers does erythronolide B have? OH Identify them. H3C -CH3 OH Erythronolide B H3C. H3C. OH OH CH3arrow_forwardPLEASE HELP! URGENT! PLEASE RESPOND!arrow_forward
- 2. Propose a mechanism for this reaction. ہلی سے ملی N H (excess)arrow_forwardSteps and explanationn please.arrow_forwardProblem 5-48 Assign R or S configurations to the chirality centers in ascorbic acid (vitamin C). OH H OH HO CH2OH Ascorbic acid O H Problem 5-49 Assign R or S stereochemistry to the chirality centers in the following Newman projections: H Cl H CH3 H3C. OH H3C (a) H H H3C (b) CH3 H Problem 5-52 Draw the meso form of each of the following molecules, and indicate the plane of symmetry in each: OH OH (a) CH3CHCH2CH2CHCH3 CH3 H3C. -OH (c) H3C CH3 (b) Problem 5-66 Assign R or S configurations to the chiral centers in cephalexin, trade-named Keflex, the most widely prescribed antibiotic in the United States. H2N H IHH S Cephalexin N. CH3 CO₂Harrow_forward
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