Chemistry
12th Edition
ISBN: 9780078021510
Author: Raymond Chang Dr., Kenneth Goldsby Professor
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 20, Problem 20.48QP
Describe the removal of SO2 by CaO (to form CaSO3) in terms of a Lewis acid-base reaction.
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Write the reaction quotient, Qc, for each of the following reactions:(a) The first step in nitric acid production, NH3(g) + O2(g) ⇌ NO(g) + H2O(g)(b) The disproportionation of nitrogen monoxide, NO(g) ⇌ N2O(g) + NO2(g)
The reaction of calcium hydride, CaH2, with water can be characterized as a Lewis acid-base reaction:
Identify the Lewis acid and the Lewis base among the reactants. The reaction is also an oxidation-reduction reaction. Identify the oxidizing agent, the reducing agent, and the changes in oxidation number that occur in the reaction.
How does CaO or CaCO2 remove SO2 from flue gases?
Chapter 20 Solutions
Chemistry
Ch. 20.2 - Calculate the wavelength (in nm) of a photon...Ch. 20.5 - Prob. 2PECh. 20.8 - Prob. 3PECh. 20 - Prob. 20.1QPCh. 20 - Prob. 20.2QPCh. 20 - Prob. 20.3QPCh. 20 - Prob. 20.4QPCh. 20 - Prob. 20.5QPCh. 20 - Prob. 20.6QPCh. 20 - Prob. 20.7QP
Ch. 20 - Prob. 20.8QPCh. 20 - Prob. 20.9QPCh. 20 - Prob. 20.10QPCh. 20 - Prob. 20.11QPCh. 20 - The green color observed in aurora borealis is...Ch. 20 - Prob. 20.13QPCh. 20 - Prob. 20.14QPCh. 20 - Prob. 20.15QPCh. 20 - Prob. 20.16QPCh. 20 - Prob. 20.17QPCh. 20 - Prob. 20.18QPCh. 20 - Prob. 20.19QPCh. 20 - Prob. 20.20QPCh. 20 - Prob. 20.21QPCh. 20 - Prob. 20.22QPCh. 20 - Prob. 20.23QPCh. 20 - Prob. 20.24QPCh. 20 - Prob. 20.25QPCh. 20 - Prob. 20.26QPCh. 20 - Prob. 20.27QPCh. 20 - Prob. 20.28QPCh. 20 - Prob. 20.29QPCh. 20 - Prob. 20.30QPCh. 20 - Prob. 20.31QPCh. 20 - Prob. 20.32QPCh. 20 - Prob. 20.33QPCh. 20 - Prob. 20.34QPCh. 20 - Prob. 20.35QPCh. 20 - Prob. 20.36QPCh. 20 - Prob. 20.37QPCh. 20 - Prob. 20.38QPCh. 20 - Prob. 20.39QPCh. 20 - Calcium oxide or quicklime (CaO) is used in...Ch. 20 - The molar heat capacity of a diatomic molecule is...Ch. 20 - Prob. 20.42QPCh. 20 - Prob. 20.43QPCh. 20 - List three detrimental effects of acid rain.Ch. 20 - Briefly discuss two industrial processes that lead...Ch. 20 - Discuss ways to curb acid rain.Ch. 20 - Prob. 20.47QPCh. 20 - Describe the removal of SO2 by CaO (to form CaSO3)...Ch. 20 - Prob. 20.49QPCh. 20 - Prob. 20.50QPCh. 20 - Prob. 20.51QPCh. 20 - Prob. 20.52QPCh. 20 - Identify the gas that is responsible for the brown...Ch. 20 - The safety limits of ozone and carbon monoxide are...Ch. 20 - Prob. 20.55QPCh. 20 - In which region of the atmosphere is ozone...Ch. 20 - Assume that the formation of nitrogen dioxide:...Ch. 20 - The gas-phase decomposition of peroxyacetyl...Ch. 20 - On a smoggy day in a certain city the ozone...Ch. 20 - Which of the following settings is the most...Ch. 20 - Prob. 20.61QPCh. 20 - Prob. 20.62QPCh. 20 - Prob. 20.63QPCh. 20 - Prob. 20.64QPCh. 20 - A concentration of 8.00 102 ppm by volume of CO...Ch. 20 - Prob. 20.66QPCh. 20 - Briefly describe the harmful effects of the...Ch. 20 - The equilibrium constant (KP) for the reaction is...Ch. 20 - As stated in the chapter, carbon monoxide has a...Ch. 20 - Instead of monitoring carbon dioxide, suggest...Ch. 20 - In 1991 it was discovered that nitrous oxide (N2O)...Ch. 20 - A glass of water initially at pH 7.0 is exposed to...Ch. 20 - A 14-m by 10-m by 3.0-m basement had a high radon...Ch. 20 - Ozone in the troposphere is formed by the...Ch. 20 - Prob. 20.75QPCh. 20 - Prob. 20.76QPCh. 20 - A person was found dead of carbon monoxide...Ch. 20 - The carbon dioxide level in the atmosphere today...Ch. 20 - What is funny about the following cartoon?Ch. 20 - Calculate the standard enthalpy of formation (Hf )...Ch. 20 - Prob. 20.81QPCh. 20 - Prob. 20.82QPCh. 20 - Prob. 20.83QPCh. 20 - Peroxyacetyl nitrate (PAN) undergoes thermal...Ch. 20 - How are past temperatures determined from ice...Ch. 20 - The balance between SO2 and SO3 is important in...Ch. 20 - Prob. 20.87QPCh. 20 - The HO3 radical was once thought of as a temporary...Ch. 20 - What is the difference between weather and...Ch. 20 - Estimate the annual production of carbon dioxide...
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- Explain why the bond between B and Cl in the molecule BCl3 is shorter than would be expected for a single B—Cl bond.arrow_forwardCalculate the fraction of intact H2PO3 molecules in an aqueous solution of phosphorous acid at (a) pH = 5.0 and (b) pH =9.0.arrow_forwardThe value of Ka for nitrous acid 1HNO22 at 25 °C is given in Appendix D. (a) Write the chemical equation for the equilibrium that corresponds to Ka.arrow_forward
- Write the balanced chemical equation for conversion of Al(s) to KAl(SO4)2·12H2O(s) in aqueous solution.arrow_forward1. Write the reaction quotient, Qc. for each of the following reactions: (a) The first step in nitric acid production, NH3(g) + O2(g) NO(g) + H₂O(g) (b) The disproportionation of nitrogen monoxide, NO(g) N₂O(g) + NO₂(g)arrow_forwardCompounds such as NaBH₄, Al(BH₄)₃, and LiAlH₄ arecomplex hydrides used as reducing agents in many syntheses.(a) Give the oxidation state of each element in these compounds.(b) Write a Lewis structure for the polyatomic anion in NaBH₄,and predict its shape.arrow_forward
- An impurity sometimes found in Ca₃(PO₄)₂ is Fe₂O₃, whichis removed during the production of phosphorus as ferrophos-phorus(Fe₂P). (a) Why is this impurity troubling from an eco-nomic standpoint? (b) If 50. metric tons of crude Ca₃(PO₄)₂ contains 2.0% Fe₂O₃ by mass and the overall yield of phospho-rus is 90.%, how many metric tons of P₄ can be isolated?arrow_forwardWrite the chemical reaction involved in the preparation of sulphur sol.arrow_forwardConsider the series of reactions to synthesize the alum (KAl(SO4 )2 · xH2O(s)) from the introduction. Assuming an excess of the other reagents, from one mole of potassium hydroxide KOH, how many moles of alum will be produced?arrow_forward
- Write the balanced reaction for the synthesis of Al2O3 from its elements?arrow_forwardChlorine dioxide gas (ClO2) is used as a commercial bleachingagent. It bleaches materials by oxidizing them. In thecourse of these reactions, the ClO2 is itself reduced. (a)What is the Lewis structure for ClO2? (b) Why do you thinkthat ClO2 is reduced so readily? (c) When a ClO2 moleculegains an electron, the chlorite ion, ClO2-, forms. Draw theLewis structure for ClO2-. (d) Predict the O—Cl—O bondangle in the ClO2- ion. (e) One method of preparing ClO2is by the reaction of chlorine and sodium chlorite:Cl2(g) + 2 NaClO2(s)------>2 ClO2(g) + 2 NaCl(s)If you allow 15.0 g of NaClO2 to react with 2.00 L of chlorinegas at a pressure of 1.50 atm at 21 °C, how many gramsof ClO2 can be prepared?arrow_forward(i) How is HNO3 prepared commercially?(ii) Write chemical equations of the reactions involved.(iii) What concentration by mass of HNO3 is obtained?arrow_forward
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