Chemistry
14th Edition
ISBN: 9781264243709
Author: Chang, Raymond
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Chapter 20, Problem 20.43QP
Interpretation Introduction
Interpretation:
The gas which largely cause acid rain has to be given.
Concept Introduction:
Acid rain:
Acid rain is a kind of precipitation which is acidic that is it has more hydrogen ions. It occurs due to emission of sulfur dioxide and nitrogen oxide which reacts with water to form acid rain. It affects buildings, plants and animals.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 20 Solutions
Chemistry
Ch. 20.2 - Calculate the wavelength (in nm) of a photon...Ch. 20.5 - Prob. 2PECh. 20.5 - Prob. 1RCFCh. 20.8 - Prob. 3PECh. 20 - Prob. 20.1QPCh. 20 - Prob. 20.2QPCh. 20 - Prob. 20.3QPCh. 20 - Prob. 20.4QPCh. 20 - Prob. 20.5QPCh. 20 - Prob. 20.6QP
Ch. 20 - Prob. 20.7QPCh. 20 - Prob. 20.8QPCh. 20 - Prob. 20.9QPCh. 20 - Prob. 20.10QPCh. 20 - Prob. 20.11QPCh. 20 - The green color observed in aurora borealis is...Ch. 20 - Prob. 20.13QPCh. 20 - Prob. 20.14QPCh. 20 - Prob. 20.15QPCh. 20 - Prob. 20.16QPCh. 20 - Prob. 20.17QPCh. 20 - Prob. 20.18QPCh. 20 - Prob. 20.19QPCh. 20 - Prob. 20.20QPCh. 20 - Prob. 20.21QPCh. 20 - Prob. 20.22QPCh. 20 - Prob. 20.23QPCh. 20 - Prob. 20.24QPCh. 20 - Prob. 20.25QPCh. 20 - Prob. 20.26QPCh. 20 - Prob. 20.27QPCh. 20 - Prob. 20.28QPCh. 20 - Prob. 20.29QPCh. 20 - Prob. 20.30QPCh. 20 - Prob. 20.31QPCh. 20 - Prob. 20.32QPCh. 20 - Prob. 20.33QPCh. 20 - Prob. 20.34QPCh. 20 - Prob. 20.35QPCh. 20 - Prob. 20.36QPCh. 20 - Prob. 20.37QPCh. 20 - Prob. 20.38QPCh. 20 - Prob. 20.39QPCh. 20 - Calcium oxide or quicklime (CaO) is used in...Ch. 20 - The molar heat capacity of a diatomic molecule is...Ch. 20 - Prob. 20.42QPCh. 20 - Prob. 20.43QPCh. 20 - List three detrimental effects of acid rain.Ch. 20 - Briefly discuss two industrial processes that lead...Ch. 20 - Discuss ways to curb acid rain.Ch. 20 - Prob. 20.47QPCh. 20 - Describe the removal of SO2 by CaO (to form CaSO3)...Ch. 20 - Prob. 20.49QPCh. 20 - Prob. 20.50QPCh. 20 - Prob. 20.51QPCh. 20 - Prob. 20.52QPCh. 20 - Identify the gas that is responsible for the brown...Ch. 20 - The safety limits of ozone and carbon monoxide are...Ch. 20 - Prob. 20.55QPCh. 20 - In which region of the atmosphere is ozone...Ch. 20 - Assume that the formation of nitrogen dioxide:...Ch. 20 - The gas-phase decomposition of peroxyacetyl...Ch. 20 - On a smoggy day in a certain city the ozone...Ch. 20 - Which of the following settings is the most...Ch. 20 - Prob. 20.61QPCh. 20 - Prob. 20.62QPCh. 20 - Prob. 20.63QPCh. 20 - Prob. 20.64QPCh. 20 - A concentration of 8.00 102 ppm by volume of CO...Ch. 20 - Prob. 20.66QPCh. 20 - Briefly describe the harmful effects of the...Ch. 20 - The equilibrium constant (KP) for the reaction is...Ch. 20 - As stated in the chapter, carbon monoxide has a...Ch. 20 - Instead of monitoring carbon dioxide, suggest...Ch. 20 - In 1991 it was discovered that nitrous oxide (N2O)...Ch. 20 - A glass of water initially at pH 7.0 is exposed to...Ch. 20 - A 14-m by 10-m by 3.0-m basement had a high radon...Ch. 20 - Ozone in the troposphere is formed by the...Ch. 20 - Prob. 20.75QPCh. 20 - Prob. 20.76QPCh. 20 - A person was found dead of carbon monoxide...Ch. 20 - The carbon dioxide level in the atmosphere today...Ch. 20 - What is funny about the following cartoon?Ch. 20 - Calculate the standard enthalpy of formation (Hf )...Ch. 20 - Prob. 20.81QPCh. 20 - Prob. 20.82QPCh. 20 - Prob. 20.83QPCh. 20 - Peroxyacetyl nitrate (PAN) undergoes thermal...Ch. 20 - How are past temperatures determined from ice...Ch. 20 - The balance between SO2 and SO3 is important in...Ch. 20 - Prob. 20.87QPCh. 20 - The HO3 radical was once thought of as a temporary...Ch. 20 - What is the difference between weather and...Ch. 20 - Estimate the annual production of carbon dioxide...
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