Organic Chemistry: Principles And Mechanisms
Organic Chemistry: Principles And Mechanisms
2nd Edition
ISBN: 9780393630756
Author: KARTY, Joel
Publisher: W.w. Norton & Company,
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Chapter 20, Problem 20.11YT
Interpretation Introduction

Interpretation:

The following scheme outlines the mechanism for the LiAlH4 reduction of the acid chloride equation 20-19. The appropriate curved arrows are to be supplied. The name of the elementary step is to be written underneath each reaction arrow, and the tetrahedral intermediate is to be identified.

Organic Chemistry: Principles And Mechanisms, Chapter 20, Problem 20.11YT

Concept introduction:

In general, LiAlH4 can be used to convert a ketone to a secondary alcohol and an aldehyde to a primary alcohol. The hydride ion from LiAlH4 is an excellent nucleophile. The hydride nucleophile can react with acid derivatives in nucleophilic addition-elimination reaction. Here the carbonyl group is converted into primary alcohol.

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Chapter 20 Solutions

Organic Chemistry: Principles And Mechanisms

Ch. 20 - Prob. 20.11PCh. 20 - Prob. 20.12PCh. 20 - Prob. 20.13PCh. 20 - Prob. 20.14PCh. 20 - Prob. 20.15PCh. 20 - Prob. 20.16PCh. 20 - Prob. 20.17PCh. 20 - Prob. 20.18PCh. 20 - Prob. 20.19PCh. 20 - Prob. 20.20PCh. 20 - Prob. 20.21PCh. 20 - Prob. 20.22PCh. 20 - Prob. 20.23PCh. 20 - Prob. 20.24PCh. 20 - Prob. 20.25PCh. 20 - Prob. 20.26PCh. 20 - Prob. 20.27PCh. 20 - Prob. 20.28PCh. 20 - Prob. 20.29PCh. 20 - Prob. 20.30PCh. 20 - Prob. 20.31PCh. 20 - Prob. 20.32PCh. 20 - Prob. 20.33PCh. 20 - Prob. 20.34PCh. 20 - Prob. 20.35PCh. 20 - Prob. 20.36PCh. 20 - Prob. 20.37PCh. 20 - Prob. 20.38PCh. 20 - Prob. 20.39PCh. 20 - Prob. 20.40PCh. 20 - Prob. 20.41PCh. 20 - Prob. 20.42PCh. 20 - Prob. 20.43PCh. 20 - Prob. 20.44PCh. 20 - Prob. 20.45PCh. 20 - Prob. 20.46PCh. 20 - Prob. 20.47PCh. 20 - Prob. 20.48PCh. 20 - Prob. 20.49PCh. 20 - Prob. 20.50PCh. 20 - Prob. 20.51PCh. 20 - Prob. 20.52PCh. 20 - Prob. 20.53PCh. 20 - Prob. 20.54PCh. 20 - Prob. 20.55PCh. 20 - Prob. 20.56PCh. 20 - Prob. 20.57PCh. 20 - Prob. 20.58PCh. 20 - Prob. 20.59PCh. 20 - Prob. 20.60PCh. 20 - Prob. 20.61PCh. 20 - Prob. 20.62PCh. 20 - Prob. 20.63PCh. 20 - Prob. 20.64PCh. 20 - Prob. 20.65PCh. 20 - Prob. 20.66PCh. 20 - Prob. 20.67PCh. 20 - Prob. 20.68PCh. 20 - Prob. 20.69PCh. 20 - Prob. 20.70PCh. 20 - Prob. 20.71PCh. 20 - Prob. 20.1YTCh. 20 - Prob. 20.2YTCh. 20 - Prob. 20.3YTCh. 20 - Prob. 20.4YTCh. 20 - Prob. 20.5YTCh. 20 - Prob. 20.6YTCh. 20 - Prob. 20.7YTCh. 20 - Prob. 20.8YTCh. 20 - Prob. 20.9YTCh. 20 - Prob. 20.10YTCh. 20 - Prob. 20.11YTCh. 20 - Prob. 20.12YTCh. 20 - Prob. 20.13YT
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