Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
Quantitative Chemical Analysis 9e And Sapling Advanced Single Course For Analytical Chemistry (access Card)
9th Edition
ISBN: 9781319090241
Author: Daniel C. Harris, Sapling Learning
Publisher: W. H. Freeman
Question
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Chapter 20, Problem 20.11P

(a)

Interpretation Introduction

Interpretation:

The resolution is required for grating to resolve given wavelengths has to be calculated.

Concept introduction:

Resolution of grating:

It is useful for separate two closely merged peaks

λΔλ=nNwhere,λis wavelengthis the diffractionorderNis the number of grooves of the grating

(a)

Expert Solution
Check Mark

Answer to Problem 20.11P

The resolution is 17066.666

Explanation of Solution

Given,

Wavelengths is 512.23and 512.26nm

According to resolution of grating:

λΔλ=nNΔλ=512.26nm-512.23=0.03nm

The resolution is = λΔλ

    = 5120.03

     = 17066.666

(b)

Interpretation Introduction

Interpretation:

The given resolution is close in nm is the closest line has to be resolved.

Concept introduction:

Resolution:

It is useful for separate two closely merged peaks

λΔλ=nNwhere,λis wavelengthis the diffractionorderNis the number of grooves of the grating

(b)

Expert Solution
Check Mark

Answer to Problem 20.11P

The resolution is 0.05nm

Explanation of Solution

Given,

Given,

Wavelengths is 512.23

According to resolution of grating:

Resolution 10-4

λΔλ=nNΔλ=512.26nm-512.23=0.03nm

The resolution is = λΔλ=10000

    = 51210000

     = 0.05nm

(c)

Interpretation Introduction

Interpretation:

The fourth-order resolution of a grating has to be calculated.

Concept introduction:

Resolution of grating:

It is useful for separate two closely merged peaks

λΔλ=nNwhere,λis wavelengthis the diffractionorderNis the number of grooves of the grating

(c)

Expert Solution
Check Mark

Answer to Problem 20.11P

The fourth-order resolution of a grating is  5.9×104

Explanation of Solution

Given,

The fourth-order resolution of a grating is 8.00cm long is ruled at 185lines/mm

According to resolution,

=nN=4 (80mm) (185lines/mm) = 5.9×104

(d)

Interpretation Introduction

Interpretation:

The angle dispersion (Δϕ) between light rays with wavelengths has to be calculated.

Concept introduction:

Dispersion of grating:

It is useful to separate wavelengths differing with Δλ through the difference in angle, ϕ)

ΔφΔλ = ndcosφ

where,λis wavelengthis the diffractionorder

(d)

Expert Solution
Check Mark

Answer to Problem 20.11P

The angle dispersion (Δϕ) between light rays with wavelengths is 0.013°

Explanation of Solution

Given,

Wavelengths is 512.23and 512.26nm

According to resolution of grating

The angular dispersion (Δφ) between light rays with wavelengths of 512.23and 512.26nm nm for first-order diffraction (n = 1) and thirtieth-order diffraction from a grating with 250 lines/mm and φ = 3.0°

Δλ = 0.03 nm, d = 1/250 = 0.004 mmΔφΔλ = ndcosφ

n = 1: Δφ = nΔλdcosφ               =(0.03 nm)[0.004 mm·cos(3)]              = 7.5 x 10-6 radians =0.0004°

n = 30: Δφ = nΔλdcosφ                 = 30(7.5 x 10-6 radians)                 = 2.25 x 10-4 radians =0.013° 

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