The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected. Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain. The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix. Names of branches that occur commonly as side chains are listed below:

Question

I

Answer 1

Question

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Draw the anti-Markovnikov product of the hydration of this alkene. this problem. Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for esc esc ☐ Explanation Check F1 1 2 F2 # 3 F3 + $ 14 × 1. BH THE BH3 2. H O NaOH '2 2' Click and drag to start drawing a structure. F4 Q W E R A S D % 905 LL F5 F6 F7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility < & 6 7 27 8 T Y U G H I F8 F9 F10 F11 F12 9 0 J K L P + // command option Z X C V B N M H H rol option command

AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N

Answer 2

Question

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Answer 3

Question

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Answer 4

Question

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

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Answer 5

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 6

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 7

Chapter 2, Problem 45P

(a)

Interpretation Introduction

Interpretation: The structures corresponding to 2-methyl-3-propylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 8

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 9

(b)

Interpretation Introduction

Interpretation: The structures corresponding to 5-(1,1-dimethylpropyl)nonane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 10

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 11

(c)

Interpretation Introduction

Interpretation: The structures corresponding to 2,3,4-trimethyl-4-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 12

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 13

(d)

Interpretation Introduction

Interpretation:The structures corresponding to 4-tert-butyl-5- isopropyhexane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 14

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 15

(e)

Interpretation Introduction

Interpretation: The structures corresponding to 4-(2-ethylbutyl)decane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 16

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 17

(f)

Interpretation Introduction

Interpretation:The structures corresponding to 2,4,4-trimethylpentane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 18

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 19

(g)

Interpretation Introduction

Interpretation: The structures corresponding to 4-sec-butylheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 20

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 21

(h)

Interpretation Introduction

Interpretation: The structures corresponding to isoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 22

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 23

(i)

Interpretation Introduction

Interpretation: The structures corresponding to neoheptane should be drawn and the incorrect IUPAC names should be corrected.

Concept introduction: As per IUPAC recommendations longest chain found in a continuous manner in a branched molecule is chosen as parent chain.

The IUPAC name begins with prefix to designate the number of C atoms in the longest chosen parent alkane followed by the suffix −ane. The positions of side chains or substituents are indicated by lowest numeral places before prefix.

Names of branches that occur commonly as side chains are listed below:

Answer 24

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Answer 35

Ch. 2.1 - Prob. 2.1E Ch. 2.1 - Prob. 2.2E Ch. 2.1 - Prob. 2.3E Ch. 2.1 - Prob. 2.5TIY Ch. 2.1 - Prob. 2.6E Ch. 2.1 - Prob. 2.7E Ch. 2.2 - Prob. 2.8E Ch. 2.3 - Prob. 2.9E Ch. 2.3 - Prob. 2.10E Ch. 2.3 - Prob. 2.11E

Solution Summary: The author recommends that the structures corresponding to 2-methyl-3-propylpentane be drawn and the incorrect IUPAC names be corrected.

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