(i)
Interpretation: The work done for the isothermal expansion of argon gas against a constant external pressure of
Concept introduction: The properties of the system such as temperature, pressure, enthalpy, entropy are changes in thermodynamic process. The second law of
(ii)
Interpretation: The work done for the reversible isothermal expansion of argon gas against a constant external pressure of
Concept introduction: The properties of the system such as temperature, pressure, enthalpy, entropy are changes in thermodynamic process. The second law of thermodynamics allows the classification of all processes into two main categories that is reversible and irreversible processes. The isothermal processes are those in which the temperature remains constant throughout the process. The work under the influence of an external pressure is either done by the system or on the system. The formula to calculate the work done for the reversible isothermal expansion is given below as,

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Chapter 2 Solutions
PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
- Predict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2).arrow_forward(10 pts) The density of metallic copper is 8.92 g cm³. The structure of this metal is cubic close-packed. What is the atomic radius of copper in copper metal?arrow_forwardPredict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2).arrow_forward
- Predict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2).arrow_forwardQ3: Rank the following compounds in increasing reactivity of E1 and E2 eliminations, respectively. Br ca. go do A CI CI B C CI Darrow_forwardQ5: Predict major product(s) for the following reactions. Note the mechanism(s) of the reactions (SN1, E1, SN2 or E2). H₂O דיי "Br KN3 CH3CH2OH NaNH2 NH3 Page 3 of 6 Chem 0310 Organic Chemistry 1 HW Problem Sets CI Br excess NaOCH 3 CH3OH Br KOC(CH3)3 DuckDuckGarrow_forward
- Q4: Circle the substrate that gives a single alkene product in a E2 elimination. CI CI Br Brarrow_forwardPlease calculate the chemical shift of each protonsarrow_forwardQ1: Answer the questions for the reaction below: ..!! Br OH a) Predict the product(s) of the reaction. b) Is the substrate optically active? Are the product(s) optically active as a mix? c) Draw the curved arrow mechanism for the reaction. d) What happens to the SN1 reaction rate in each of these instances: 1. Change the substrate to Br 'CI 2. Change the substrate to 3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF 4. Increase the substrate concentration by 3-fold.arrow_forward
- Q6: Provide the reagents and conditions for the following reactions to make the product with a good yield. Br Br CI она CIarrow_forwardQ2: We would not expect the following primary alkyl halide to go through an SN1 reaction. However, it can go through an SN1 mechanism. Explain why. Hint: Think about what happens when the leaving group leaves. CI NaO EtOH H བྱིས་ Harrow_forwardI performed this experiment, but I'm so confused. How do I find the first two blank columns using the data provided. What is the [I^-] mol/L and [S2O8^-2] mol/L. How do I find this? Please help!arrow_forward
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