Elements of Physical Chemistry
7th Edition
ISBN: 9780192522764
Author: Peter Atkins; Julio de Paula
Publisher: Oxford University Press Academic UK
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Chapter 2, Problem 2.8P
Interpretation Introduction
Interpretation:
The molar enthalpy of vaporization of isopropanol at its boiling point has to be calculated.
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1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
2000
1800
1600
1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Draw the Michael Adduct and the final product of the Robinson annulation reaction. Ignore inorganic byproducts.
Chapter 2 Solutions
Elements of Physical Chemistry
Ch. 2 - Prob. 2A.1STCh. 2 - Prob. 2A.2STCh. 2 - Prob. 2B.1STCh. 2 - Prob. 2B.2STCh. 2 - Prob. 2B.3STCh. 2 - Prob. 2B.4STCh. 2 - Prob. 2B.5STCh. 2 - Prob. 2C.1STCh. 2 - Prob. 2C.2STCh. 2 - Prob. 2D.1ST
Ch. 2 - Prob. 2D.2STCh. 2 - Prob. 2E.1STCh. 2 - Prob. 2E.2STCh. 2 - Prob. 2E.3STCh. 2 - Prob. 2F.1STCh. 2 - Prob. 2F.2STCh. 2 - Prob. 2F.3STCh. 2 - Prob. 2F.4STCh. 2 - Prob. 2F.5STCh. 2 - Prob. 2F.6STCh. 2 - Prob. 2A.2ECh. 2 - Prob. 2A.3ECh. 2 - Prob. 2A.4ECh. 2 - Prob. 2A.5ECh. 2 - Prob. 2A.6ECh. 2 - Prob. 2A.7ECh. 2 - Prob. 2A.8ECh. 2 - Prob. 2B.1ECh. 2 - Prob. 2B.2ECh. 2 - Prob. 2B.3ECh. 2 - Prob. 2B.4ECh. 2 - Prob. 2B.5ECh. 2 - Prob. 2C.1ECh. 2 - Prob. 2C.2ECh. 2 - Prob. 2D.1ECh. 2 - Prob. 2D.2ECh. 2 - Prob. 2D.3ECh. 2 - Prob. 2D.4ECh. 2 - Prob. 2D.5ECh. 2 - Prob. 2D.6ECh. 2 - Prob. 2E.1ECh. 2 - Prob. 2E.2ECh. 2 - Prob. 2E.3ECh. 2 - Prob. 2E.4ECh. 2 - Prob. 2E.5ECh. 2 - Prob. 2E.6ECh. 2 - Prob. 2E.7ECh. 2 - Prob. 2E.8ECh. 2 - Prob. 2E.9ECh. 2 - Prob. 2F.1ECh. 2 - Prob. 2F.2ECh. 2 - Prob. 2F.3ECh. 2 - Prob. 2F.4ECh. 2 - Prob. 2F.5ECh. 2 - Prob. 2F.6ECh. 2 - Prob. 2F.7ECh. 2 - Prob. 2F.8ECh. 2 - Prob. 2F.9ECh. 2 - Prob. 2F.10ECh. 2 - Prob. 2.1DQCh. 2 - Prob. 2.2DQCh. 2 - Prob. 2.3DQCh. 2 - Prob. 2.4DQCh. 2 - Prob. 2.5DQCh. 2 - Prob. 2.6DQCh. 2 - Prob. 2.7DQCh. 2 - Prob. 2.8DQCh. 2 - Prob. 2.9DQCh. 2 - Prob. 2.10DQCh. 2 - Prob. 2.11DQCh. 2 - Prob. 2.12DQCh. 2 - Prob. 2.13DQCh. 2 - Prob. 2.14DQCh. 2 - Prob. 2.15DQCh. 2 - Prob. 2.16DQCh. 2 - Prob. 2.1PCh. 2 - Prob. 2.2PCh. 2 - Prob. 2.3PCh. 2 - Prob. 2.4PCh. 2 - Prob. 2.5PCh. 2 - Prob. 2.6PCh. 2 - Prob. 2.7PCh. 2 - Prob. 2.8PCh. 2 - Prob. 2.9PCh. 2 - Prob. 2.10PCh. 2 - Prob. 2.12PCh. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - Prob. 2.17PCh. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - Prob. 2.23PCh. 2 - Prob. 2.25PCh. 2 - Prob. 2.1PRCh. 2 - Prob. 2.2PRCh. 2 - Prob. 2.3PRCh. 2 - Prob. 2.4PRCh. 2 - Prob. 2.5PRCh. 2 - Prob. 2.6PRCh. 2 - Prob. 2.8PRCh. 2 - Prob. 2.9PRCh. 2 - Prob. 2.10PR
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