Chemistry: Atoms First
18th Edition
ISBN: 9781938168154
Author: Richard Langley, Klaus Theopold, Paul Flowers
Publisher: OpenStax College
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Textbook Question
Chapter 2, Problem 28E
Explain why the
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ
Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this
system:
?
rise
Under these conditions, will the pressure of N2 tend to rise or fall?
☐ x10
fall
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of N2 will tend to rise, can that be
changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of N2 will tend to fall, can that be changed to a tendency to rise
by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
☐
atm
☑
5
00.
18
Ar
Chapter 2 Solutions
Chemistry: Atoms First
Ch. 2 - In the following drawing, the green spheres...Ch. 2 - Which postulate of Dalton’s theory is consistent...Ch. 2 - Identify the postulate of Dalton’s theory that is...Ch. 2 - Samples of compound X, Y, and Z are analyzed, with...Ch. 2 - The existence of isotopes violates one of the...Ch. 2 - How are electrons and protons similar? How are...Ch. 2 - How are protons and neutrons similar? How are they...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - Predict and test the behavior of a particles fired...Ch. 2 - In what way are isotopes of a given element always...
Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Write the symbol for each of the following ions:...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Open the Build an Atom simulation...Ch. 2 - Determine the number of protons, neutrons, and...Ch. 2 - The following are properties of isotopes of two...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Give the number of protons, electrons, and...Ch. 2 - Click on the site...Ch. 2 - Click on the site...Ch. 2 - An element has the following natural abundances...Ch. 2 - Average atomic masses listed by JUPAC are based on...Ch. 2 - Variations in average atomic mass may be observed...Ch. 2 - The average atomic masses of some elements may...Ch. 2 - The 18O:16O abundance ratio in some meteorites is...Ch. 2 - Explain why the symbol for an atom of the element...Ch. 2 - Explain why the symbol for the element sulfur and...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Write the molecular and empirical formulas of the...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Determine the empirical formulas for the following...Ch. 2 - Write the empirical formulas for the following...Ch. 2 - Open the Build a Molecule simulation...Ch. 2 - Use the Build a Molecule simulation...Ch. 2 - Use the Build a Molecule simulation...Ch. 2 - Write a sentence that describes how to determine...Ch. 2 - Compare 1 mole of H2, 1 mole of o2, and 1 mole of...Ch. 2 - Which contains the greatest mass of oxygen: 0.75...Ch. 2 - Which contains the greatest number of moles of...Ch. 2 - How are the molecular mass and the molar mass of a...Ch. 2 - Calculate the molar mass of each of the following...Ch. 2 - Calculate the molar mass of each of the following:...Ch. 2 - Calculate the empirical or molecular formula mass...Ch. 2 - Calculate the molar mass of each of the following:...Ch. 2 - Determine the number of moles of compound and the...Ch. 2 - Determine the mass of each of the following: (a)...Ch. 2 - Determine the number of moles of the compound and...Ch. 2 - Determine the mass of each of the following: (a)...Ch. 2 - The approximate minimum daily dietary requirement...Ch. 2 - Determine the mass in grams of each of the...Ch. 2 - A 55-kg woman has 7.5103 mol of hemoglobin (...Ch. 2 - Determine the number of atoms and the mass of...Ch. 2 - Determine which of the following contains the...Ch. 2 - Determine which of the following contains the...Ch. 2 - Diamond is one form of elemental carbon. An...Ch. 2 - The Cullinan diamond was the largest natural...Ch. 2 - One 53-gram serving of a particular cereal...Ch. 2 - A certain nut crunch cereal contains 11.0 grams of...Ch. 2 - A tube of toothpaste contains 0.76 g of sodium...Ch. 2 - Which of the following represents the least number...
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- i need help with the followingarrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. atm ☑ 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HCN is a weak acid. acids: 0.29 mol of NaOH is added to 1.0 L of a 1.2M HCN solution. bases: ☑ other: 0.09 mol of HCl is added to acids: 1.0 L of a solution that is bases: 0.3M in both HCN and KCN. other: 0,0,... ? 00. 18 Ar 日arrow_forward
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