Exploring Chemical Analysis
Exploring Chemical Analysis
5th Edition
ISBN: 9781429275033
Author: Daniel C. Harris
Publisher: Macmillan Higher Education
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Chapter 2, Problem 2.7P
Interpretation Introduction

Interpretation:

The true mass of water has to be calculated if the mass measured in air is 5.3974 g

Concept Introduction:

True mass:

The true mass of an object is a measure of its inherent inertia, and this is independent of buoyancy.  The true mass can be determined by weighing in a vacuum without buoyant forces.

The true mass can be determined by the formula:

    m = m'(1-dadw)/(1-dad)m = true massm'= mass measured in airda= density of air (0.0012g/mL near 1bar and 25 oC)dw= density of balance weights (8.0g/mL)d = density of object being weighed

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What spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.
Question 6 What is the major product of the following Diels-Alder reaction? ? Aldy by day of A. H о B. C. D. E. OB OD Oc OE OA
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