(a) Interpretation: The dynamic model of the given process is to be developed. Concept introduction: For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances. The process models generally include algebraic relationships which commence from thermodynamics , transport phenomena , chemical kinetics, and physical properties of the processes. In steady-state process, the accumulation in the process is taken as zero.

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Answer 1

Question

Chapter 2, Problem 2.6E

Interpretation Introduction

(a)

Interpretation:

The dynamic model of the given process is to be developed.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

In steady-state process, the accumulation in the process is taken as zero.

Interpretation Introduction

(b)

Interpretation:

The degree of freedom analysis for the given process is to be done and all the parameters, input, output, and disturbance variables are to be identified.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Degree of freedom analysis of a process model ensures that its model equations are solvable. The expression to calculate the degree of freedom is:

NF=NV−NE .........(5)

Here, NF is the number of degree of freedom for the process model, NV is the total number of process variables, and NE is the total number of independent equations written for the process model.

Interpretation Introduction

(c)

Interpretation:

Any modification in the dynamic model of the given process to account for the presence of exothermic reaction occurring in compartment 2 is to be explained.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

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2. A moving bed adsorption column needs to be designed to separate hydrophobic proteins from a fermentation broth. The following adsorption equilibrium data was observed in preliminary isotherm studies. The resin used was activated carbon with a porosity of 0.2. The overall mass transfer coefficient was determined to be 10 h¹, and the ratio of volumetric flow rate of broth to resin is 10. Determine the diameter of the column if the column height is limited to 2.5 m (indoor operation) with a flow rate of 20 m³/h, influent concentration of 7 g/L, and effluent concentration of 0.1 g/L. qi (mg/kg) Ci (g/L) 0.1 4.7 7.5 0.25 10.6 0.5 15.0 1.0 23.7 2.5 33.5 5.0 41.1 7.5

3. You are given a mixture of four proteins, whose properties are listed in the table below. Propose a process to purify each protein so that you end up with four solutions of pure protein. What resin would you use to bind the protein(s)? What changes to the buffer would you make to desorb the protein(s)? Contains an N-terminal His6-tag. Two 50 kDa subunits contain a non-heme Fe2+ in the active site. Protein Size (kDa) pl Specific Properties A 100 6.0 B 40 7.7 C 240 8.3 Ꭰ 225 5.5 Contains FAD redox center and an NADH binding domain. Composed of six 40-kDa subunits, each of which contains a [2Fe-2S] cluster. Composed of three subunits: 100 kDa structural subunit, 75 kDa subunit with a molybdopterin center, and 50 kDa subunit with FAD and an NADH binding domain.

Answer 2

Question

Chapter 2, Problem 2.6E

Interpretation Introduction

(a)

Interpretation:

The dynamic model of the given process is to be developed.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

In steady-state process, the accumulation in the process is taken as zero.

Interpretation Introduction

(b)

Interpretation:

The degree of freedom analysis for the given process is to be done and all the parameters, input, output, and disturbance variables are to be identified.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Degree of freedom analysis of a process model ensures that its model equations are solvable. The expression to calculate the degree of freedom is:

NF=NV−NE .........(5)

Here, NF is the number of degree of freedom for the process model, NV is the total number of process variables, and NE is the total number of independent equations written for the process model.

Interpretation Introduction

(c)

Interpretation:

Any modification in the dynamic model of the given process to account for the presence of exothermic reaction occurring in compartment 2 is to be explained.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

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Answer 3

Question

Chapter 2, Problem 2.6E

Interpretation Introduction

(a)

Interpretation:

The dynamic model of the given process is to be developed.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

In steady-state process, the accumulation in the process is taken as zero.

Interpretation Introduction

(b)

Interpretation:

The degree of freedom analysis for the given process is to be done and all the parameters, input, output, and disturbance variables are to be identified.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Degree of freedom analysis of a process model ensures that its model equations are solvable. The expression to calculate the degree of freedom is:

NF=NV−NE .........(5)

Here, NF is the number of degree of freedom for the process model, NV is the total number of process variables, and NE is the total number of independent equations written for the process model.

Interpretation Introduction

(c)

Interpretation:

Any modification in the dynamic model of the given process to account for the presence of exothermic reaction occurring in compartment 2 is to be explained.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

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Answer 4

Question

Chapter 2, Problem 2.6E

Interpretation Introduction

(a)

Interpretation:

The dynamic model of the given process is to be developed.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

In steady-state process, the accumulation in the process is taken as zero.

Interpretation Introduction

(b)

Interpretation:

The degree of freedom analysis for the given process is to be done and all the parameters, input, output, and disturbance variables are to be identified.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Degree of freedom analysis of a process model ensures that its model equations are solvable. The expression to calculate the degree of freedom is:

NF=NV−NE .........(5)

Here, NF is the number of degree of freedom for the process model, NV is the total number of process variables, and NE is the total number of independent equations written for the process model.

Interpretation Introduction

(c)

Interpretation:

Any modification in the dynamic model of the given process to account for the presence of exothermic reaction occurring in compartment 2 is to be explained.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

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Answer 5

Chapter 2, Problem 2.6E

Interpretation Introduction

(a)

Interpretation:

The dynamic model of the given process is to be developed.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

In steady-state process, the accumulation in the process is taken as zero.

Interpretation Introduction

(b)

Interpretation:

The degree of freedom analysis for the given process is to be done and all the parameters, input, output, and disturbance variables are to be identified.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Degree of freedom analysis of a process model ensures that its model equations are solvable. The expression to calculate the degree of freedom is:

NF=NV−NE .........(5)

Here, NF is the number of degree of freedom for the process model, NV is the total number of process variables, and NE is the total number of independent equations written for the process model.

Interpretation Introduction

(c)

Interpretation:

Any modification in the dynamic model of the given process to account for the presence of exothermic reaction occurring in compartment 2 is to be explained.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Answer 6

Chapter 2, Problem 2.6E

Interpretation Introduction

(a)

Interpretation:

The dynamic model of the given process is to be developed.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

In steady-state process, the accumulation in the process is taken as zero.

Answer 7

Chapter 2, Problem 2.6E

Interpretation Introduction

(a)

Interpretation:

The dynamic model of the given process is to be developed.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

In steady-state process, the accumulation in the process is taken as zero.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The degree of freedom analysis for the given process is to be done and all the parameters, input, output, and disturbance variables are to be identified.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Degree of freedom analysis of a process model ensures that its model equations are solvable. The expression to calculate the degree of freedom is:

NF=NV−NE .........(5)

Here, NF is the number of degree of freedom for the process model, NV is the total number of process variables, and NE is the total number of independent equations written for the process model.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The degree of freedom analysis for the given process is to be done and all the parameters, input, output, and disturbance variables are to be identified.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Degree of freedom analysis of a process model ensures that its model equations are solvable. The expression to calculate the degree of freedom is:

NF=NV−NE .........(5)

Here, NF is the number of degree of freedom for the process model, NV is the total number of process variables, and NE is the total number of independent equations written for the process model.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Any modification in the dynamic model of the given process to account for the presence of exothermic reaction occurring in compartment 2 is to be explained.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Any modification in the dynamic model of the given process to account for the presence of exothermic reaction occurring in compartment 2 is to be explained.

Concept introduction:

For chemical processes, dynamic models consisting ordinary differential equations are derived through unsteady-state conservation laws. These laws generally include mass and energy balances.

The process models generally include algebraic relationships which commence from thermodynamics, transport phenomena, chemical kinetics, and physical properties of the processes.

Answer 12

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Ch. 2 - Prob. 2.1E Ch. 2 - Prob. 2.2E Ch. 2 - Prob. 2.3E Ch. 2 - Prob. 2.4E Ch. 2 - Prob. 2.5E Ch. 2 - Prob. 2.6E Ch. 2 - Prob. 2.7E Ch. 2 - Prob. 2.8E Ch. 2 - Prob. 2.9E Ch. 2 - Prob. 2.10E

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