General Chemistry
11th Edition
ISBN: 9781305859142
Author: Ebbing, Darrell D., Gammon, Steven D.
Publisher: Cengage Learning,
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Chapter 2, Problem 2.66QP
Nitric acid is composed of HNO3 molecules. A sample weighing 4.50 g contains 4.30 × 1022 HNO3 molecules. How many nitrogen atoms are in this sample? How many oxygen atoms are in 61.0 g of nitric acid?
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 2 Solutions
General Chemistry
Ch. 2.1 - Like Dalton, chemists continue to model atoms...Ch. 2.2 - Prob. 2.2CCCh. 2.3 - A nucleus consists of 17 protons and 18 neutrons....Ch. 2.4 - Chlorine consists of the following isotopes:...Ch. 2.5 - By referring to the periodic table (Figure 2.15 or...Ch. 2.5 - Consider the elements He, Ne, and Ar. Can you come...Ch. 2.6 - Prob. 2.4ECh. 2.6 - Classify each of the following as either an ionic...Ch. 2.8 - Prob. 2.5CCCh. 2.8 - Prob. 2.5E
Ch. 2.8 - Prob. 2.6ECh. 2.8 - Prob. 2.6CCCh. 2.8 - Prob. 2.7ECh. 2.8 - Prob. 2.8ECh. 2.8 - Prob. 2.9ECh. 2.8 - Prob. 2.10ECh. 2.8 - Washing soda has the formula Na2CO310H2O. What is...Ch. 2.8 - Prob. 2.12ECh. 2.8 - Prob. 2.7CCCh. 2.10 - Prob. 2.13ECh. 2 - Describe atomic theory and discuss how it explains...Ch. 2 - Two compounds of iron and chlorine, A and B,...Ch. 2 - Explain the operation of a cathode-ray tube....Ch. 2 - Prob. 2.4QPCh. 2 - Prob. 2.5QPCh. 2 - What are the different kinds of particles in the...Ch. 2 - Describe how protons and neutrons were discovered...Ch. 2 - Oxygen consists of three different _____, each...Ch. 2 - Describe how Dalton obtained relative atomic...Ch. 2 - Briefly explain how a mass spectrometer works....Ch. 2 - Define the term atomic weight. Why might the...Ch. 2 - What is the name of the element in Group 4A and...Ch. 2 - Prob. 2.13QPCh. 2 - Prob. 2.14QPCh. 2 - Prob. 2.15QPCh. 2 - What is the fundamental difference between an...Ch. 2 - Prob. 2.17QPCh. 2 - Which of the following models represent a(n): a...Ch. 2 - Prob. 2.19QPCh. 2 - Prob. 2.20QPCh. 2 - How many protons, neutrons, and electrons are in...Ch. 2 - The atomic weight of Ga is 69.72 amu. There are...Ch. 2 - Prob. 2.23QPCh. 2 - A chunk of an unidentified element (lets call it...Ch. 2 - Average Atomic Weight Part 1: Consider the four...Ch. 2 - Model of the Atom Consider the following...Ch. 2 - One of the early models of the atom proposed that...Ch. 2 - A friend is trying to balance the following...Ch. 2 - Given that the periodic table is an organizational...Ch. 2 - Prob. 2.30QPCh. 2 - Prob. 2.31QPCh. 2 - Match the molecular model with the correct...Ch. 2 - Consider a hypothetical case in which the charge...Ch. 2 - Prob. 2.34QPCh. 2 - Prob. 2.35QPCh. 2 - You perform a chemical reaction using the...Ch. 2 - Prob. 2.37QPCh. 2 - Prob. 2.38QPCh. 2 - Prob. 2.39QPCh. 2 - Prob. 2.40QPCh. 2 - A student has determined the mass-to-charge ratio...Ch. 2 - The mass-to-charge ratio for the positive ion F+...Ch. 2 - The following table gives the number of protons...Ch. 2 - The following table gives the number of protons...Ch. 2 - Naturally occurring chlorine is a mixture of the...Ch. 2 - Naturally occurring nitrogen is a mixture of 14N...Ch. 2 - What is the nuclide symbol for the nucleus that...Ch. 2 - An atom contains 34 protons and 45 neutrons. What...Ch. 2 - Ammonia is a gas with a characteristic pungent...Ch. 2 - Hydrogen sulfide is a gas with the odor of rotten...Ch. 2 - Calculate the atomic weight of an element with two...Ch. 2 - An element has two naturally occurring isotopes...Ch. 2 - An element has three naturally occurring isotopes...Ch. 2 - An element has three naturally occurring isotopes...Ch. 2 - While traveling to a distant universe, you...Ch. 2 - While roaming a parallel universe, you discover...Ch. 2 - Identify the group and period for each of the...Ch. 2 - Prob. 2.58QPCh. 2 - Prob. 2.59QPCh. 2 - Prob. 2.60QPCh. 2 - Prob. 2.61QPCh. 2 - Prob. 2.62QPCh. 2 - The normal form of the element sulfur is a...Ch. 2 - White phosphorus is available in sticks, which...Ch. 2 - A 4.19-g sample of nitrous oxide (an anesthetic,...Ch. 2 - Nitric acid is composed of HNO3 molecules. A...Ch. 2 - A sample of ammonia, NH3, contains 1.2 1023...Ch. 2 - A sample of ethanol (ethyl alcohol), C2H3OH,...Ch. 2 - Prob. 2.69QPCh. 2 - What molecular formula corresponds to each of the...Ch. 2 - Prob. 2.71QPCh. 2 - Prob. 2.72QPCh. 2 - Prob. 2.73QPCh. 2 - Ammonium phosphate, (NH4)3PO4, has how many oxygen...Ch. 2 - Prob. 2.75QPCh. 2 - Prob. 2.76QPCh. 2 - Name the following compounds. a Na2SO4 b Na3N c...Ch. 2 - Name the following compounds. a CaO b Mn2O3 c...Ch. 2 - Prob. 2.79QPCh. 2 - Prob. 2.80QPCh. 2 - Prob. 2.81QPCh. 2 - For each of the following binary compounds, decide...Ch. 2 - Give systematic names to the following binary...Ch. 2 - Prob. 2.84QPCh. 2 - Prob. 2.85QPCh. 2 - Prob. 2.86QPCh. 2 - Prob. 2.87QPCh. 2 - Prob. 2.88QPCh. 2 - Prob. 2.89QPCh. 2 - Give the name and formula of the acid...Ch. 2 - Prob. 2.91QPCh. 2 - Prob. 2.92QPCh. 2 - Prob. 2.93QPCh. 2 - Prob. 2.94QPCh. 2 - For the balanced chemical equation Ca(NO3)2 +...Ch. 2 - In the equation 2PbS + O2 2PbO + 2SO2, how many...Ch. 2 - Balance the following equations. a Sn + NaOH ...Ch. 2 - Balance the following equations. a Ca3(PO4)2 +...Ch. 2 - Prob. 2.99QPCh. 2 - Solid sodium metal reacts with water, giving a...Ch. 2 - Prob. 2.101QPCh. 2 - Prob. 2.102QPCh. 2 - Two samples of different compounds of nitrogen and...Ch. 2 - Two samples of different compounds of sulfur and...Ch. 2 - In a series of oil-drop experiments, the charges...Ch. 2 - In a hypothetical universe, an oil-drop experiment...Ch. 2 - Compounds of europium. Eu, are used to make color...Ch. 2 - Cesium, Cs, is used in photoelectric cells...Ch. 2 - Prob. 2.109QPCh. 2 - One isotope of a metallic element has mass number...Ch. 2 - Obtain the fractional abundances for the two...Ch. 2 - Silver has two naturally occurring isotopes, one...Ch. 2 - Prob. 2.113QPCh. 2 - Prob. 2.114QPCh. 2 - Prob. 2.115QPCh. 2 - Prob. 2.116QPCh. 2 - Prob. 2.117QPCh. 2 - Prob. 2.118QPCh. 2 - Name the following compounds. a Sn3(PO4)2 b NH4NO2...Ch. 2 - Name the following compounds. a Cu(NO2)3 b (NH4)3P...Ch. 2 - Prob. 2.121QPCh. 2 - Prob. 2.122QPCh. 2 - Prob. 2.123QPCh. 2 - Name the following molecular compounds a ClF4 b...Ch. 2 - Prob. 2.125QPCh. 2 - Balance the following equations. a NaOH + H2CO3 ...Ch. 2 - A monatomic ion has a charge of +4. The nucleus of...Ch. 2 - A monatomic ion has a charge of +1. The nucleus of...Ch. 2 - Natural carbon, which has an atomic weight of...Ch. 2 - A sample of natural chlorine, has an atomic weight...Ch. 2 - Prob. 2.131QPCh. 2 - Prob. 2.132QPCh. 2 - Prob. 2.133QPCh. 2 - Prob. 2.134QPCh. 2 - Prob. 2.135QPCh. 2 - Ammonia gas reacts with molecular oxygen gas to...Ch. 2 - A hypothetical element X is found to have an...Ch. 2 - A monotomic ion has a charge of +3. The nucleus of...Ch. 2 - A small crystal of CaCl2 that weighs 0.12 g...Ch. 2 - Prob. 2.140QPCh. 2 - Prob. 2.141QPCh. 2 - The IO3, anion is called iodate. There are three...Ch. 2 - Prob. 2.143QPCh. 2 - From the following written description, write the...Ch. 2 - Prob. 2.145QPCh. 2 - Name the following compounds: a HCl(g) b HBr(aq) c...Ch. 2 - During nuclear decay a 238U atom can break apart...Ch. 2 - Prob. 2.148QPCh. 2 - There are 2.619 1022 atoms in 1.000 g of sodium....Ch. 2 - There are 1.699 1022 atoms in 1.000 g of...Ch. 2 - A sample of green crystals of nickel(II) sulfate...Ch. 2 - Cobalt(II) sulfate heptahydrate has pink-colored...Ch. 2 - A sample of metallic element X, weighing 3.177 g,...Ch. 2 - A sample of metallic element X, weighing 4.315 g,...Ch. 2 - Prob. 2.156QPCh. 2 - The element europium exists in nature as two...
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