In which one of the following pairs do the two species resemble each other most closely in chemical properties? Explain. (a) 1 1 H and 1 1 H + , (b) 7 14 N and 7 14 N 3 − , (c) 6 12 C and 6 13 C .
In which one of the following pairs do the two species resemble each other most closely in chemical properties? Explain. (a) 1 1 H and 1 1 H + , (b) 7 14 N and 7 14 N 3 − , (c) 6 12 C and 6 13 C .
Solution Summary: The author explains that the two species that are closely related in their chemical properties should be identified.
In which one of the following pairs do the two species resemble each other most closely in chemical properties? Explain. (a)
1
1
H
and
1
1
H
+
, (b)
7
14
N
and
7
14
N
3
−
, (c)
6
12
C
and
6
13
C
.
bre
The reaction sequence shown in Scheme 5 demonstrates the synthesis of a
substituted benzene derivative Q.
wolsd works 2
NH2
NaNO2, HCI
(apexe) 13× (1
HNO3, H2SO4
C6H5CIN2
0°C
HOTE
CHINO₂
N
O
*O₂H (
PO
Q
Я
Scheme 5
2 bag abouoqmics to sounde odi WEIC
(i)
Draw the structure of intermediate O.
[2 marks]
to noitsmot od: tot meinedogm, noit so oft listsb ni zaupaib bas wa
(ii) Draw the mechanism for the transformation of aniline N to intermediate O.
Spoilage
(b)
[6 marks]
(iii) Identify the reagent X used to convert compound O to the iodinated compound
[tom E
P.
vueimado oilovonsa ni moitos nolisbnolov ayd toes ai tedw nisiqx
(iv) Identify the possible structures of compound Q.
[2 marks]
[2 marks]
[shom 2]
(v)
bus noires goiribbeolovo xnivollot adj to subora sidab
Draw the mechanism for the transformation of intermediate P to compound Q.
[5 marks]
vi
(vi) Account for the regiochemical outcome observed in the reaction forming
compound Q.
[3 marks]
PROBLEM 4 Solved
Show how 1-butanol can be converted into the following compounds:
a.
PROBLEM 5+
b.
d.
-C=
N
Which alkene is the major product of this dehydration?
OH
H2SO4
heat
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NEET Chemistry | Group 14 Carbon Family | Theory & Problem Solving | In English | Misostudy; Author: Misostudy;https://www.youtube.com/watch?v=enOGIrcHh54;License: Standard YouTube License, CC-BY