It is to be explained whether NaCl will be more or less soluble in acetone (CH 3 ) 2 C = O than in di-tert-butyl ketone [(CH 3 ) 3 C] 2 C = O . Concept introduction: Ionic compounds dissolve in polar solvents. Larger the dipole moment of the polar solvent, better the ions solvated and greater the solubility of the ionic compound. When an ionic compound dissolves in a polar solvent, the free ions can interact with the solvent molecule through ion-dipole interactions. In such ion-dipole interactions, the positive end of the solvent dipole attracts anions and the negative end attracts cations. Each ion participates in multiple ion-dipole interactions with the solvent, and ions get solvated. The stability of these ion-dipole interactions is greater than that of ion-ion interactions in ionic compounds, which makes the mixture more stable.

Question

2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Answer 1

Question

Chapter 2, Problem 2.57P

Interpretation Introduction

Interpretation:

It is to be explained whether NaCl will be more or less soluble in acetone (CH3)2C = O than in di-tert-butyl ketone[(CH3)3C]2C = O.

Concept introduction:

Ionic compounds dissolve in polar solvents. Larger the dipole moment of the polar solvent, better the ions solvated and greater the solubility of the ionic compound.

When an ionic compound dissolves in a polar solvent, the free ions can interact with the solvent molecule through ion-dipole interactions. In such ion-dipole interactions, the positive end of the solvent dipole attracts anions and the negative end attracts cations. Each ion participates in multiple ion-dipole interactions with the solvent, and ions get solvated. The stability of these ion-dipole interactions is greater than that of ion-ion interactions in ionic compounds, which makes the mixture more stable.

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2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5