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Concept explainers
(a)
Interpretation:
The statement "in the modern periodic table, the elements are arranged in order of increasing
Concept introduction:
A periodic table is an arrangement of elements based on their
(b)
Interpretation:
The statement "elements in a period have similar chemical properties" is to be corrected.
Concept introduction:
A periodic table is an arrangement of elements based on their atomic number, properties and electronic configuration. The table is arranged into groups and periods. The elements which are metallic in nature, occupy the large lower-left portion of the table. The non-metals occupy the small upper-right portion of the table. Metalloids lie along the staircase line. Elements which appear in the same group have similar behaviour.
(c)
Interpretation:
The statement "elements can either be classified as either metalloids or non-metals" is to be corrected.
Concept introduction:
A periodic table is an arrangement of elements based on their atomic number, properties and electronic configuration. The table is arranged into groups and periods. The elements which are metallic in nature, occupy the large lower-left portion of the table. The non-metals occupy the small upper-right portion of the table. Metalloids lie along the staircase line. Elements which appear in the same group have similar behaviour.
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Chapter 2 Solutions
Chemistry: The Molecular Nature of Matter and Change
- Nonearrow_forwardNonearrow_forwardIn the solid state, oxalic acid occurs as a dihydrate with the formula H2C2O4 C+2H2O. Use this formula to calculate the formula weight of oxalic acid. Use the calculated formula weight and the number of moles (0.00504mol) of oxalic acid in each titrated unknown sample recorded in Table 6.4 to calculate the number of grams of pure oxalic acid dihydrate contained in each titrated unknown sample.arrow_forward
- 1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)arrow_forwardWrite the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.arrow_forwardNonearrow_forward
- 3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward
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