CHEMISTRY (LL) W/CNCT >BI<
13th Edition
ISBN: 9781260572384
Author: Chang
Publisher: MCG
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Chapter 2, Problem 2.4QP
What is meant by the term “fundamental particle”?
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Chapter 2 Solutions
CHEMISTRY (LL) W/CNCT >BI<
Ch. 2.1 - The atoms of elements A (blue) and B (orange) form...Ch. 2.3 - How many protons, neutrons, and electrons are in...Ch. 2.3 - What is the atomic number of an element if one of...Ch. 2.3 - How many neutrons are in an atom of 114Cd?Ch. 2.3 - Which of the following two symbols provides more...Ch. 2.4 - In viewing the periodic table, do chemical...Ch. 2.4 - Identify the following as a metal, metalloid, or...Ch. 2.5 - What does S8 signify? How does it differ from 8S?Ch. 2.5 - Determine the number of protons and electrons for...Ch. 2.5 - Prob. 3RCF
Ch. 2.6 - Write the empirical formula for caffeine...Ch. 2.6 - Prob. 4PECh. 2.6 - Prob. 1RCFCh. 2.6 - Prob. 2RCFCh. 2.7 - Name the following compounds: (a) PbO and (b)...Ch. 2.7 - Prob. 6PECh. 2.7 - Name the following molecular compounds: (a) NF3...Ch. 2.7 - Prob. 8PECh. 2.7 - Prob. 9PECh. 2.7 - Prob. 1RCFCh. 2.7 - Prob. 2RCFCh. 2.7 - Prob. 3RCFCh. 2.7 - Prob. 4RCFCh. 2.7 - Prob. 5RCFCh. 2.8 - Prob. 1RCFCh. 2 - Prob. 2.1QPCh. 2 - Name the types of radiation known to be emitted by...Ch. 2 - Compare the properties of the following: ...Ch. 2 - What is meant by the term fundamental particle?Ch. 2 - Describe the contributions of the following...Ch. 2 - Describe the experimental basis for believing that...Ch. 2 - The diameter of a helium atom is about 1 102 pm....Ch. 2 - Prob. 2.8QPCh. 2 - Use the helium-4 isotope to define atomic number...Ch. 2 - Why do all atoms of an element have the same...Ch. 2 - What do we call atoms of the same elements with...Ch. 2 - Explain the meaning of each term in the symbol...Ch. 2 - What is the mass number of an iron atom that has...Ch. 2 - Calculate the number of neutrons in 239Pu.Ch. 2 - Prob. 2.15QPCh. 2 - Indicate the number of protons, neutrons, and...Ch. 2 - Write the appropriate symbol for each of the...Ch. 2 - Write the appropriate symbol for each of the...Ch. 2 - What is the periodic table, and what is its...Ch. 2 - State two differences between a metal and a...Ch. 2 - Write the names and symbols for four elements in...Ch. 2 - Define, with two examples, the following terms:...Ch. 2 - Prob. 2.23QPCh. 2 - Describe the changes in properties (from metals to...Ch. 2 - Consult a handbook of chemical and physical data...Ch. 2 - Group the following elements in pairs that you...Ch. 2 - Prob. 2.27QPCh. 2 - Prob. 2.28QPCh. 2 - Describe the two commonly used molecular models.Ch. 2 - Prob. 2.30QPCh. 2 - Prob. 2.31QPCh. 2 - Prob. 2.32QPCh. 2 - Identify the following as elements or compounds:...Ch. 2 - Prob. 2.34QPCh. 2 - Give the number of protons and electrons in each...Ch. 2 - Give the number of protons and electrons in each...Ch. 2 - Pair the following species that contain the same...Ch. 2 - Write the correct symbols for the atoms that...Ch. 2 - What does a chemical formula represent? What is...Ch. 2 - Define molecular formula and empirical formula....Ch. 2 - Give an example of a case in which two molecules...Ch. 2 - Prob. 2.42QPCh. 2 - Prob. 2.43QPCh. 2 - Prob. 2.44QPCh. 2 - Prob. 2.45QPCh. 2 - Prob. 2.46QPCh. 2 - What are the empirical formulas of the following...Ch. 2 - What are the empirical formulas of the following...Ch. 2 - Write the molecular formula of glycine, an amino...Ch. 2 - Write the molecular formula of ethanol. The color...Ch. 2 - Prob. 2.51QPCh. 2 - Prob. 2.52QPCh. 2 - Prob. 2.53QPCh. 2 - Prob. 2.54QPCh. 2 - Prob. 2.55QPCh. 2 - Prob. 2.56QPCh. 2 - Prob. 2.57QPCh. 2 - Prob. 2.58QPCh. 2 - Name these compounds: (a) Na2CrO4, (b) K2HPO4, (c)...Ch. 2 - Prob. 2.60QPCh. 2 - Prob. 2.61QPCh. 2 - Prob. 2.62QPCh. 2 - Sulfur (S) and fluorine (F) form several different...Ch. 2 - Prob. 2.64QPCh. 2 - Prob. 2.65QPCh. 2 - In which one of the following pairs do the two...Ch. 2 - Prob. 2.67QPCh. 2 - Prob. 2.68QPCh. 2 - Determine the molecular and empirical formulas of...Ch. 2 - What is wrong with or ambiguous about the phrase...Ch. 2 - Prob. 2.71QPCh. 2 - Which of the following are elements, which are...Ch. 2 - Prob. 2.73QPCh. 2 - Prob. 2.74QPCh. 2 - Each of the following pairs of elements will react...Ch. 2 - Match the descriptions [(a)(h)] with each of the...Ch. 2 - Explain why anions are always larger than the...Ch. 2 - Prob. 2.78QPCh. 2 - Caffeine, shown here, is a psychoactive stimulant...Ch. 2 - Prob. 2.80QPCh. 2 - Prob. 2.81QPCh. 2 - Prob. 2.82QPCh. 2 - Fill in the blanks in the following table.Ch. 2 - Prob. 2.84QPCh. 2 - Write the formula of the common ion derived from...Ch. 2 - Prob. 2.86QPCh. 2 - Prob. 2.87QPCh. 2 - Of the 118 elements known, only two are liquids at...Ch. 2 - Prob. 2.89QPCh. 2 - Prob. 2.90QPCh. 2 - Prob. 2.91QPCh. 2 - Prob. 2.92QPCh. 2 - Prob. 2.93QPCh. 2 - Prob. 2.94QPCh. 2 - List five elements each that are (a) named after...Ch. 2 - Prob. 2.96QPCh. 2 - Fluorine reacts with hydrogen (H) and deuterium...Ch. 2 - Prob. 2.98QPCh. 2 - Identify each of the following elements: (a) a...Ch. 2 - Prob. 2.100QPCh. 2 - Show the locations of (a) alkali metals, (b)...Ch. 2 - Fill the blanks in the following table.Ch. 2 - Prob. 2.103QPCh. 2 - In Section 2.1 it was pointed out that mass and...Ch. 2 - Draw all possible structural formulas of the...Ch. 2 - Prob. 2.106QPCh. 2 - Draw two different structural formulas based on...Ch. 2 - Prob. 2.108QPCh. 2 - Prob. 2.109QPCh. 2 - A monatomic ion has a charge of +2. The nucleus of...Ch. 2 - In the following 2 2 crossword, each letter must...Ch. 2 - Prob. 2.112QPCh. 2 - Prob. 2.113QPCh. 2 - Prob. 2.114QPCh. 2 - Prob. 2.115QPCh. 2 - Prob. 2.116QPCh. 2 - Prob. 2.117QPCh. 2 - Prob. 2.118QPCh. 2 - Prob. 2.119QPCh. 2 - Prob. 2.120QPCh. 2 - Prob. 2.121QPCh. 2 - One technique proposed for recycling plastic...
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- d. In Figure 4, each stationary phase shows some negative correlation between plate count and retention factor. In other words, as k' increases, N decreases. Explain this relationship between k' and N. Plate Count (N) 4000 3500 2500 2000 1500 1000 Figure 4. Column efficiency (N) vs retention factor (k') for 22 nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000 Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain k' less than 15, which was achieved for most solutes as follows: FMS (30/70 A/W), PGC (60/40), COZ (80/20). Slightly different compositions were used for the most highly retained solutes. All columns were 50 mm × 4.6 mm id and packed with 5 um particles, except for COZ, which was packed with 3 um particles. All other chromatographic conditions were constant: column length 5 cm, column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C, and injection volume 0.5 μL Log(k'x/K'ethylbenzene) FMS 1.5 1.0 0.5 0.0 ཐྭ ཋ ཤྩ བྷྲ ; 500 0 5 10…arrow_forwardf. Predict how the van Deemter curve in Figure 7 would change if the temperature were raised from 40 °C to 55 °C. Figure 7. van Desmter curves in reduced coordinates for four nitroalkane homologues (nitropropane, black; nitrobutane, red; nitropentane, blue; and nitrohexane, green) separated on the FMS phase. Chromatographic conditions: column dimensions 50 mm × 4.6 mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection volume 0.5 and column temperature 40 °C. No corrections to the plate heights have been made to account for extracolumn dispersion. Reduced Plate Height (h) ° 20 40 60 Reduced Velocity (v) 8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and standard are spiked with a fixed amount of toluene as an internal standard. The following data are obtained: Ppb benzene Peak area benzene Peak area toluene 10.0 252 376 Sample 533 368 What is the concentration of benzene in the sample?arrow_forwardLiquid chromatography has been used to track the concentration of remdesivir (a broad-spectrum antiviral drug, structure shown at right) in COVID patients undergoing experimental treatments. Intensity The authors provide the following details regarding standard solutions preparation: HN CN HO OH NH2 Remdesivir (RDV) stock solution (5000 µg/mL) was prepared by dissolving RDV drug powder using the mixture of DMSO: MeOH (30:70 v/v). The RDV working standard solutions for calibration and quality controls were prepared using methanol in concentrations of 100, 10, 1, 0.1, 0.01 µg/mL. 1, 2.5, 5, 7.5, 10, 25, 50, 75, 100, 250, 500, 1000, and 5000 ng/mL sample solutions were prepared freshly by spiking calibration standard solutions into the blank human plasma samples for method calibration. a) What type of calibration method is being described? Why do you think the authors chose this method as opposed to another? b) Based on the details provided in part a, describe an appropriate method blank…arrow_forward
- Recent advancements in liquid chromatography include the development of ultrahigh pressure liquid chromatography (UHPLC) and an increased use of capillary columns that had previously only been used with gas chromatography. Both of these advances have made the development of portable LC systems possible. For example, Axcend Corp. makes a portable system that uses a capillary column with an internal diameter of 150-μm-that is packed with 1.7-um stationary phase particles. In contrast, a traditional LC column has a 4.6 mm internal diameter and utilizes 5-um stationary phase particles. a) Explain one advantage that is afforded by the use of a capillary column in liquid chromatographic separation. Explain one disadvantage of capillary columns. b) Explain how the use of smaller stationary phase particles can improve the resolution of a separation. Include any relevant equations that support your explanation. c) A scientist at Rowan University is using the Axcend LC to conduct analyses of F…arrow_forwardThis paper describes the use of fullerene molecules, also known as buckyballs, as a stationary phase for liquid chromatography. The performance of the fullerene-modified stationary phase (FMS) is compared to that of a more common C18 stationary phase and to two other carbon-based stationary phases, PGC and COZ. A. 10A OM B. - Figure 1. Idealized drawing of the cross-section of a pore inside a silica particle, showing the relative densities of aminopropylsilyl (red/green) and fullerene (blue) groups: (A) full cross- section; (B) detailed view of covalent bonding of fullerene to the silica surface. Surface densities of silyl and fullerene groups were inferred from elemental composition results obtained at each stage of the synthesis (see Table 1). Absorbance (mAU, 220 nm) 700 600 500 400 300 200 100 a. Define selectivity, a, with words and an equation. b. Explain how the choice of stationary phase affects selectivity. c. Calculate the resolution of the nitrobenzene and toluene peaks in…arrow_forwardNormalized Intensity (a. u.) 0.5 1.0 A 3D-printed GC column (shown below) was created for use with "micro" gas chromatography applications. To prove its utility, it was used to separate a mixture of alkanes (C9-C18, C22, C24). For the separation shown below, the column temperature was ramped from 40 °C to 250 °C at a rate of 30 °C per minute. (a) 9 10 = 1 mm 12 13 15 22 0.0 0 100 200 300 400 Time (sec) a) What detector would you use for this analysis? Justify your selection. b) Explain how the chromatogram would change if the separation was run isothermally. c) Explain how the chromatogram would change if the temperature ramp were increased to 50 °C per minute.arrow_forward
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