ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
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Chapter 2, Problem 2.42AP
Interpretation Introduction

(a)

Interpretation:

The dipole moment of the anti-conformation of 1, 2-dibromoethane, Br-CH2-CH2-Br is to be stated and the answer is to be explained.

Concept introduction:

The dipole moment is defined as the charge separation between two atoms or ions in a covalent or ionic bond. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.

If any structure is symmetrical, then overall dipole moment will be zero, and the bond becomes non-polar. Also, a bond can be considered polar if there is some electronegativity difference between the atoms.

Interpretation Introduction

(b)

Interpretation:

The dipole moment of a gauche conformation of 1, 2-dibromoethane is to be calculated.

Concept introduction:

The dipole moment is defined as the charge separation between two atoms or ions in a covalent or ionic bond. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.

If any structure is symmetrical, then overall dipole moment will be zero, and the bond becomes non-polar. Also, a bond can be considered polar if there is some electronegativity difference between the atoms.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3
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Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).
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