ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
ORGANIC CHEMISTRY SAPLING ACCESS + ETEX
6th Edition
ISBN: 9781319306977
Author: LOUDON
Publisher: INTER MAC
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Chapter 2, Problem 2.15P
Interpretation Introduction

(a)

Interpretation:

Two structures of the given compound are to be drawn using the abbreviations for substituent groups abbreviated as methyl groups for one structure and a five-carbon skeleton, two methyl groups, and a tert-butyl group for other structure is to be shown.

Concept introduction:

The skeletal structure of a compound is represented by the line having several vertices. These vertices in the skeletal structure represent the carbon atoms presents in the structure. In the skeletal structure, the valence of the carbon is satisfied by the hydrogen atoms which are not shown. If any atom other than carbon and hydrogen is present in the molecule then it is denoted by its symbol in the skeletal structure.

Interpretation Introduction

(b)

Interpretation:

The structure of the given compound using the abbreviations for substituent groups is to be drawn.

Concept introduction:

The skeletal structure of a compound is represented by the line having several vertices. These vertices in the skeletal structure represent the carbon atoms presents in the structure. In the skeletal structure, the valence of the carbon is satisfied by the hydrogen atoms which are not shown. If any atom other than carbon and hydrogen is present in the molecule then it is denoted by its symbol in the skeletal structure.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10
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