General Chemistry
7th Edition
ISBN: 9780073402758
Author: Chang, Raymond/ Goldsby
Publisher: McGraw-Hill College
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Chapter 2, Problem 2.25QP
Interpretation Introduction
Interpretation:
Difference between atom and molecule has to be given.
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Draw the anti-Markovnikov product of the hydration of this alkene.
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Explanation
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 2 Solutions
General Chemistry
Ch. 2.1 - Review of Concepts
The atoms of elements A (blue)...Ch. 2.2 - Review of Concepts
Which two of the three...Ch. 2.3 - Practice Exercise How many protons, neutrons, and...Ch. 2.3 - What is the atomic number of an element if one of...Ch. 2.4 - Prob. 1RCCh. 2.5 - Prob. 1RCCh. 2.6 - Prob. 1PECh. 2.6 - Prob. 2PECh. 2.6 - Prob. 3PECh. 2.6 - Prob. 1RC
Ch. 2.7 - Prob. 1PECh. 2.7 - Prob. 2PECh. 2.7 - Prob. 3PECh. 2.7 - Prob. 4PECh. 2.7 - Prob. 5PECh. 2.8 - Prob. 1RCCh. 2 - Prob. 2.1QPCh. 2 - Prob. 2.2QPCh. 2 - Prob. 2.3QPCh. 2 - 2.4 Describe the contributions of these scientists...Ch. 2 - 2.5 A sample of a radioactive element is found to...Ch. 2 - 2.6 Describe the experimental basis for believing...Ch. 2 - Prob. 2.7QPCh. 2 - 2.8 Roughly speaking, the radius of an atom is...Ch. 2 - Prob. 2.9QPCh. 2 - Prob. 2.10QPCh. 2 - 2.11 What is the mass number of an iron atom that...Ch. 2 - Prob. 2.12QPCh. 2 - Prob. 2.13QPCh. 2 - Prob. 2.14QPCh. 2 - Prob. 2.15QPCh. 2 - Prob. 2.16QPCh. 2 - Prob. 2.17QPCh. 2 - Prob. 2.18QPCh. 2 - Prob. 2.19QPCh. 2 - Prob. 2.20QPCh. 2 - Prob. 2.21QPCh. 2 - Prob. 2.22QPCh. 2 - Prob. 2.23QPCh. 2 - Prob. 2.24QPCh. 2 - Prob. 2.25QPCh. 2 - Prob. 2.26QPCh. 2 - Prob. 2.27QPCh. 2 - Prob. 2.28QPCh. 2 - Prob. 2.29QPCh. 2 - Prob. 2.30QPCh. 2 - 2.31 Identify the following as elements or...Ch. 2 - Prob. 2.32QPCh. 2 - Prob. 2.33QPCh. 2 - Prob. 2.34QPCh. 2 - Prob. 2.35QPCh. 2 - Prob. 2.36QPCh. 2 - Prob. 2.37QPCh. 2 - Prob. 2.38QPCh. 2 - Prob. 2.39QPCh. 2 - Prob. 2.40QPCh. 2 - Prob. 2.41QPCh. 2 - Prob. 2.42QPCh. 2 - Prob. 2.43QPCh. 2 - Prob. 2.44QPCh. 2 - Prob. 2.45QPCh. 2 - Prob. 2.46QPCh. 2 - Prob. 2.47QPCh. 2 - Prob. 2.48QPCh. 2 - Prob. 2.49QPCh. 2 - Prob. 2.50QPCh. 2 - Prob. 2.51QPCh. 2 - Prob. 2.52QPCh. 2 - Prob. 2.53QPCh. 2 - Prob. 2.54QPCh. 2 - Prob. 2.55QPCh. 2 - Prob. 2.56QPCh. 2 - Prob. 2.57QPCh. 2 - Prob. 2.58QPCh. 2 - Prob. 2.59QPCh. 2 - Prob. 2.60QPCh. 2 - Prob. 2.62QPCh. 2 - Prob. 2.63QPCh. 2 - Prob. 2.64QPCh. 2 - Prob. 2.65QPCh. 2 - Prob. 2.66QPCh. 2 - Prob. 2.67QPCh. 2 - Prob. 2.68QPCh. 2 - Prob. 2.69QPCh. 2 - Prob. 2.70QPCh. 2 - Prob. 2.71QPCh. 2 - Prob. 2.72QPCh. 2 - Prob. 2.73QPCh. 2 - Prob. 2.74QPCh. 2 - Prob. 2.75QPCh. 2 - Prob. 2.76SPCh. 2 - Prob. 2.77SPCh. 2 - Prob. 2.78SPCh. 2 - Prob. 2.79SPCh. 2 - Prob. 2.80SPCh. 2 - Prob. 2.81SPCh. 2 - Prob. 2.82SP
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