Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Question
Chapter 2, Problem 2.20QE
Interpretation Introduction
Interpretation:
The missing component in the name chromium chloride for the compound
Concept Introduction:
In case of naming an ionic compound, the name of metal is given first followed by the name of nonmetal with suffix “ide”. The elements from group IB and IIB have fixed charges. Apart from these, the other metals have variable charges. If the ionic compound contains the metals which can possess variable charges, the charge present on the metal has to be entered in the name using Roman numberal after the name of metal.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 2 Solutions
Chemistry: Principles and Practice
Ch. 2 - Prob. 2.1QECh. 2 - State how Daltons atomic theory explains (a) the...Ch. 2 - Prob. 2.3QECh. 2 - Prob. 2.4QECh. 2 - Prob. 2.5QECh. 2 - Prob. 2.6QECh. 2 - Prob. 2.7QECh. 2 - Describe the arrangement of protons, neutrons, and...Ch. 2 - Prob. 2.9QECh. 2 - Prob. 2.10QE
Ch. 2 - A mass spectrometer determines isotopic masses to...Ch. 2 - Prob. 2.12QECh. 2 - Prob. 2.13QECh. 2 - Prob. 2.14QECh. 2 - Prob. 2.15QECh. 2 - Prob. 2.16QECh. 2 - Sulfur dioxide, SO2, is a molecular compound that...Ch. 2 - Prob. 2.18QECh. 2 - Prob. 2.19QECh. 2 - Prob. 2.20QECh. 2 - Prob. 2.21QECh. 2 - Prob. 2.22QECh. 2 - Prob. 2.23QECh. 2 - Prob. 2.24QECh. 2 - Prob. 2.25QECh. 2 - Prob. 2.26QECh. 2 - Prob. 2.27QECh. 2 - Prob. 2.28QECh. 2 - Prob. 2.29QECh. 2 - Give the complete symbol (XZA), including atomic...Ch. 2 - Prob. 2.31QECh. 2 - Prob. 2.32QECh. 2 - Prob. 2.33QECh. 2 - Prob. 2.34QECh. 2 - Prob. 2.35QECh. 2 - Prob. 2.36QECh. 2 - Prob. 2.37QECh. 2 - Prob. 2.38QECh. 2 - Prob. 2.39QECh. 2 - Prob. 2.40QECh. 2 - Prob. 2.41QECh. 2 - Prob. 2.42QECh. 2 - Prob. 2.43QECh. 2 - Prob. 2.44QECh. 2 - Prob. 2.45QECh. 2 - Prob. 2.46QECh. 2 - Prob. 2.47QECh. 2 - Prob. 2.48QECh. 2 - Prob. 2.49QECh. 2 - Prob. 2.50QECh. 2 - Prob. 2.51QECh. 2 - Prob. 2.52QECh. 2 - Prob. 2.53QECh. 2 - Prob. 2.54QECh. 2 - Prob. 2.55QECh. 2 - Prob. 2.56QECh. 2 - Prob. 2.57QECh. 2 - Prob. 2.58QECh. 2 - Prob. 2.59QECh. 2 - Prob. 2.60QECh. 2 - Prob. 2.61QECh. 2 - Prob. 2.62QECh. 2 - Prob. 2.63QECh. 2 - Prob. 2.64QECh. 2 - Prob. 2.65QECh. 2 - Prob. 2.66QECh. 2 - Prob. 2.67QECh. 2 - Prob. 2.68QECh. 2 - Prob. 2.69QECh. 2 - Prob. 2.70QECh. 2 - Prob. 2.71QECh. 2 - Prob. 2.72QECh. 2 - Prob. 2.73QECh. 2 - Prob. 2.74QECh. 2 - Prob. 2.75QECh. 2 - Prob. 2.76QECh. 2 - Prob. 2.77QECh. 2 - Prob. 2.78QECh. 2 - Prob. 2.79QECh. 2 - Prob. 2.80QECh. 2 - Prob. 2.81QECh. 2 - Prob. 2.82QECh. 2 - Prob. 2.83QECh. 2 - Prob. 2.84QECh. 2 - Prob. 2.85QECh. 2 - Prob. 2.86QECh. 2 - Prob. 2.87QECh. 2 - Prob. 2.88QECh. 2 - Prob. 2.89QECh. 2 - Prob. 2.90QECh. 2 - Prob. 2.91QECh. 2 - Prob. 2.92QECh. 2 - Prob. 2.93QECh. 2 - Prob. 2.94QECh. 2 - Prob. 2.95QECh. 2 - Prob. 2.96QECh. 2 - Write the formula of (a) manganese(III) sulfide....Ch. 2 - Prob. 2.98QECh. 2 - Prob. 2.99QECh. 2 - Prob. 2.100QECh. 2 - Prob. 2.101QECh. 2 - Prob. 2.102QECh. 2 - Prob. 2.103QECh. 2 - Prob. 2.104QECh. 2 - Prob. 2.105QECh. 2 - Prob. 2.106QECh. 2 - Prob. 2.107QECh. 2 - Prob. 2.108QECh. 2 - Prob. 2.109QECh. 2 - Prob. 2.110QECh. 2 - Prob. 2.111QECh. 2 - Prob. 2.112QECh. 2 - Prob. 2.113QECh. 2 - Prob. 2.114QECh. 2 - Prob. 2.115QECh. 2 - Prob. 2.116QECh. 2 - Prob. 2.117QECh. 2 - Prob. 2.118QECh. 2 - Prob. 2.119QECh. 2 - Prob. 2.120QECh. 2 - Prob. 2.121QECh. 2 - Prob. 2.122QECh. 2 - Prob. 2.123QECh. 2 - Prob. 2.124QECh. 2 - Prob. 2.125QECh. 2 - Prob. 2.126QECh. 2 - Prob. 2.127QECh. 2 - Prob. 2.128QECh. 2 - Prob. 2.129QECh. 2 - Prob. 2.130QECh. 2 - Prob. 2.131QECh. 2 - Prob. 2.132QECh. 2 - Prob. 2.133QECh. 2 - Prob. 2.134QECh. 2 - Prob. 2.135QECh. 2 - Prob. 2.136QE
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