GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS
3rd Edition
ISBN: 9780134466699
Author: FROST
Publisher: PEARSON
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Chapter 2, Problem 2.18PP
How are
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Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
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Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
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Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
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2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
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Chapter 2 Solutions
GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS
Ch. 2 - Where are the subatomic particles located in an...Ch. 2 - Prob. 2.2PPCh. 2 - Prob. 2.3PPCh. 2 - Prob. 2.4PPCh. 2 - How can you determine the following? a. the number...Ch. 2 - What can be determined from the following? a. the...Ch. 2 - Provide the name and atomic symbol of the element...Ch. 2 - Provide the name and atomic symbol of the element...Ch. 2 - Prob. 2.9PPCh. 2 - Prob. 2.10PP
Ch. 2 - Determine the number of protons, neutrons, and...Ch. 2 - Determine the number of protons, neutrons, and...Ch. 2 - Prob. 2.13PPCh. 2 - Prob. 2.14PPCh. 2 - Prob. 2.15PPCh. 2 - Prob. 2.16PPCh. 2 - Prob. 2.17PPCh. 2 - How are atomic mass and mass number similar? How...Ch. 2 - There are three naturally occurring isotopes of...Ch. 2 - Prob. 2.20PPCh. 2 - Prob. 2.21PPCh. 2 - Prob. 2.22PPCh. 2 - Prob. 2.23PPCh. 2 - Prob. 2.24PPCh. 2 - Prob. 2.25PPCh. 2 - Prob. 2.26PPCh. 2 - Prob. 2.27PPCh. 2 - Prob. 2.28PPCh. 2 - Prob. 2.29PPCh. 2 - Prob. 2.30PPCh. 2 - Prob. 2.31PPCh. 2 - Prob. 2.32PPCh. 2 - What does the unit sievert measure?Ch. 2 - Prob. 2.34PPCh. 2 - Prob. 2.35PPCh. 2 - Prob. 2.36PPCh. 2 - Prob. 2.37PPCh. 2 - Prob. 2.38PPCh. 2 - Prob. 2.39PPCh. 2 - Prob. 2.40PPCh. 2 - Prob. 2.41PPCh. 2 - Prob. 2.42PPCh. 2 - Prob. 2.43PPCh. 2 - Prob. 2.44PPCh. 2 - Complete the following statements: a. A...Ch. 2 - Complete the following statements: a. The mass...Ch. 2 - Prob. 2.47APCh. 2 - Prob. 2.48APCh. 2 - Prob. 2.49APCh. 2 - Prob. 2.50APCh. 2 - Prob. 2.51APCh. 2 - Prob. 2.52APCh. 2 - Prob. 2.53APCh. 2 - Prob. 2.54APCh. 2 - Prob. 2.55APCh. 2 - Prob. 2.56APCh. 2 - Prob. 2.57APCh. 2 - Prob. 2.58APCh. 2 - Prob. 2.59APCh. 2 - Prob. 2.60APCh. 2 - Prob. 2.61APCh. 2 - Prob. 2.62APCh. 2 - Prob. 2.63APCh. 2 - Prob. 2.64APCh. 2 - Prob. 2.65APCh. 2 - Prob. 2.66APCh. 2 - Prob. 2.67APCh. 2 - Prob. 2.68APCh. 2 - A 25-mL sample of chromium-51 contains 1.00 mCi....Ch. 2 - Prob. 2.70APCh. 2 - Prob. 2.71APCh. 2 - Prob. 2.72APCh. 2 - Prob. 2.73APCh. 2 - Prob. 2.74APCh. 2 - Prob. 2.75APCh. 2 - Prob. 2.76APCh. 2 - Prob. 2.77CPCh. 2 - Prob. 2.78CPCh. 2 - PET scans are useful for imaging areas of high...Ch. 2 - Prob. 1IA.1QCh. 2 - Prob. 1IA.2QCh. 2 - Prob. 1IA.3QCh. 2 - Prob. 1IA.4QCh. 2 - Prob. 1IA.5QCh. 2 - Prob. 1IA.6QCh. 2 - Prob. 1IA.7QCh. 2 - Prob. 1IA.8QCh. 2 - Prob. 1IA.9QCh. 2 - Prob. 1IA.10QCh. 2 - Prob. 1IA.11QCh. 2 - Prob. 2IA.1QCh. 2 - Prob. 2IA.2QCh. 2 - Prob. 2IA.3QCh. 2 - Prob. 2IA.4QCh. 2 - Prob. 1ICCh. 2 - Prob. 2IC
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