Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134564586
Author: Timberlake
Publisher: PEARSON
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Chapter 2, Problem 2.114APP
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its just one question with parts till (g) JUST ONE QUESTION with its parts spread out in the form of different images attached 2 IMAGES ATTACHED PLEASE SEE ALL, please answer EACH part till the end and dont just provide wordy explanations wherever asked for structures or diagrams, please DRAW DRAW them on a paper and post clearly!! answer the full question with all details EACH PART CLEARLY please thanks!!
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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is
paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex.
a) Identify if the [Cr(CN)6] anionic complex has 4 long and
2 short bonds (left side of figure) or if the complex has 4
short and 2 long bonds (right side of figure) with respect
to Oh symmetry. Use crystal field theory to answer this
question. Explain/rationalize your decision. Can the
provided information decide on the order of orbital
energies?
Dah
Tetragonal Distortion
ய
Dab
z-compression
z-elongation
x and y elongation
O symmetry
x and y compression
E
eg d² dx²-y²
t2g
dxy dxz dyz
Question 4 a) continued:
Provide your explanations in the space below.
b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic
phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc
as well as the paramagnetic and…
Chapter 2 Solutions
Chemistry: An Introduction to General Organic and Biological Chemistry (13th Edition)
Ch. 2.1 - Write the abbreviation for each of the following:...Ch. 2.1 - Write the abbreviation for each of the following:...Ch. 2.1 - State the type of measurement in each of the...Ch. 2.1 - Prob. 2.4PPCh. 2.1 - Prob. 2.5PPCh. 2.1 - Prob. 2.6PPCh. 2.1 - Prob. 2.7PPCh. 2.1 - On a typical day, medical personnel may encounter...Ch. 2.2 - 2.9 How many significant figures are in each of...Ch. 2.2 - How many significant figures are in each of the...
Ch. 2.2 - 2.11 In which of the following pairs do both...Ch. 2.2 - 2.12 In which of the following pairs do both...Ch. 2.2 - 2.13 Indicate if the zeros are significant in each...Ch. 2.2 - 2.14 Indicate if the zeros are significant in each...Ch. 2.2 - 2.15 Write each of the following in scientific...Ch. 2.2 - 2.16 Write each of the following in scientific...Ch. 2.2 - Identify the numbers in each of the following...Ch. 2.2 - Prob. 2.18PPCh. 2.2 - Prob. 2.19PPCh. 2.2 - Prob. 2.20PPCh. 2.2 - Identify each of the following as measured or...Ch. 2.2 - Prob. 2.22PPCh. 2.3 - Round off each of the following calculator answers...Ch. 2.3 - Prob. 2.24PPCh. 2.3 - Prob. 2.25PPCh. 2.3 - Prob. 2.26PPCh. 2.3 - Prob. 2.27PPCh. 2.3 - Prob. 2.28PPCh. 2.3 - Prob. 2.29PPCh. 2.3 - Prob. 2.30PPCh. 2.4 - 2.31 Write the abbreviation for each of the...Ch. 2.4 - Write the abbreviation for each of the following...Ch. 2.4 - Prob. 2.33PPCh. 2.4 - Prob. 2.34PPCh. 2.4 - Write the numerical value for each of the...Ch. 2.4 - Prob. 2.36PPCh. 2.4 - Prob. 2.37PPCh. 2.4 - Use a prefix to write the name for each of the...Ch. 2.4 - Complete each of the following metric...Ch. 2.4 - Prob. 2.40PPCh. 2.4 - Prob. 2.41PPCh. 2.4 - Prob. 2.42PPCh. 2.5 - Why can two conversion factors be written for an...Ch. 2.5 - Prob. 2.44PPCh. 2.5 - Prob. 2.45PPCh. 2.5 - Prob. 2.46PPCh. 2.5 -
2.47 Write the equality and two conversion...Ch. 2.5 - Write the equality and two conversion factors, and...Ch. 2.5 - Write the equality and two conversion factors, and...Ch. 2.5 - Prob. 2.50PPCh. 2.5 - Write the equality and two conversion factors, and...Ch. 2.5 - Write the equality and two conversion factors, and...Ch. 2.5 - Prob. 2.53PPCh. 2.5 -
2.54 Write an equality and two conversion...Ch. 2.6 - Perform each of the following conversions using...Ch. 2.6 - Perform each of the following conversions using...Ch. 2.6 -
2.57 Perform each of the following conversions...Ch. 2.6 - Perform each of the following conversions using...Ch. 2.6 - Use metric conversion factors to solve each of the...Ch. 2.6 - Use metric conversion factors to solve each of the...Ch. 2.6 - Prob. 2.61PPCh. 2.6 - Solve each of the following problems using one or...Ch. 2.6 - Using conversion factors, solve each of the...Ch. 2.6 - Prob. 2.64PPCh. 2.6 - Prob. 2.65PPCh. 2.6 - Using conversion factors, solve each of the...Ch. 2.7 -
2.67 Determine the density (g/mL) for each of the...Ch. 2.7 - Determine the density (g/mL) for each of the...Ch. 2.7 - Prob. 2.69PPCh. 2.7 - What is the density (g/mL) of each of the...Ch. 2.7 - Prob. 2.71PPCh. 2.7 - Prob. 2.72PPCh. 2.7 - Prob. 2.73PPCh. 2.7 - Prob. 2.74PPCh. 2.7 - Prob. 2.75PPCh. 2.7 - Prob. 2.76PPCh. 2.7 - Prob. 2.77PPCh. 2.7 - Solve each of the following problems: a. A glucose...Ch. 2.7 - Prob. 2.79PPCh. 2.7 - Prob. 2.80PPCh. 2 - In which of the fo1losing pairs do both numbers...Ch. 2 - In which of the following pairs do both numbers...Ch. 2 - Indicate if each of the following is answered with...Ch. 2 - Prob. 2.84UTCCh. 2 - State the temperature on the Celsius thermometer...Ch. 2 - Prob. 2.86UTCCh. 2 - Prob. 2.87UTCCh. 2 - A shipping box has a length of 7.00 in., a width...Ch. 2 - Prob. 2.89UTCCh. 2 - Prob. 2.90UTCCh. 2 - Prob. 2.91UTCCh. 2 - Prob. 2.92UTCCh. 2 - Prob. 2.93UTCCh. 2 - Prob. 2.94UTCCh. 2 - Prob. 2.95APPCh. 2 - Prob. 2.96APPCh. 2 - Prob. 2.97APPCh. 2 - Prob. 2.98APPCh. 2 - Prob. 2.99APPCh. 2 - Prob. 2.100APPCh. 2 - Prob. 2.101APPCh. 2 - Prob. 2.102APPCh. 2 - Prob. 2.103APPCh. 2 - Prob. 2.104APPCh. 2 - Prob. 2.105APPCh. 2 - Prob. 2.106APPCh. 2 - Prob. 2.107APPCh. 2 - Prob. 2.108APPCh. 2 - Prob. 2.109APPCh. 2 - Prob. 2.110APPCh. 2 - Prob. 2.111APPCh. 2 - Prob. 2.112APPCh. 2 - Prob. 2.113APPCh. 2 - Prob. 2.114APPCh. 2 - Prob. 2.115CPCh. 2 - Prob. 2.116CPCh. 2 -
2.117 A car travels at 55 mi/h and gets 11 km/L...Ch. 2 - A sunscreen preparation contains 2.50% benzyl...Ch. 2 - Prob. 2.119CPCh. 2 - Prob. 2.120CPCh. 2 - Prob. 2.121CPCh. 2 - Prob. 2.122CP
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