Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Textbook Question
Chapter 2, Problem 12E
Identify the decimal part, the exponential part, and the exponent of the number
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
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Print Last Name, First Name Initial
Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Chapter 2 Solutions
Chemistry In Focus
Ch. 2 - The volume of a liquid can be measured with a...Ch. 2 - Scientific Notation Express the number 0.0000023...Ch. 2 - Prob. 2SCCh. 2 - Prob. 3SCCh. 2 - Converting Between Units Convert 34.0 cm to...Ch. 2 - Prob. 2.3YTCh. 2 - Extracting Information from Graphical Data The...Ch. 2 - Solving Word Problems...Ch. 2 - Solving Word Problems Involving Units Raised to a...Ch. 2 - Prob. 2.7YT
Ch. 2 - Prob. 2.8YTCh. 2 - Without doing any calculations, determine whether...Ch. 2 - Prob. 1ECh. 2 - Prob. 2ECh. 2 - Prob. 3ECh. 2 - What is the difference between reporting the...Ch. 2 - Prob. 5ECh. 2 - Prob. 6ECh. 2 - Prob. 7ECh. 2 - Prob. 8ECh. 2 - Prob. 9ECh. 2 - What is a conversion factor? Give two examples of...Ch. 2 - Prob. 11ECh. 2 - Identify the decimal part, the exponential part,...Ch. 2 - What is density? Give two examples of possible...Ch. 2 - Since oil floats on water, what can you say about...Ch. 2 - Express each of the following in scientific...Ch. 2 - Express each of the following numbers in...Ch. 2 - Express each of the following in decimal notation:...Ch. 2 - Express each of the following in decimal notation:...Ch. 2 - The circumference of Earth at the equator is...Ch. 2 - The distance from New York to Los Angeles is 2777...Ch. 2 - A can of soda contains 12 fluid ounces. What is...Ch. 2 - A laboratory beaker can hold 150mL. How many fluid...Ch. 2 - A car has a fuel efficiency of 27 miles per...Ch. 2 - A European rental car can travel 17 km on a liter...Ch. 2 - Perform each of the following conversions within...Ch. 2 - Perform each of the following conversions within...Ch. 2 - Prob. 27ECh. 2 - Perform the following conversions between the...Ch. 2 - A pond has a surface area of 1552m2. Convert this...Ch. 2 - An orange has a volume of 54cm3. Convert this...Ch. 2 - Prob. 31ECh. 2 - Prob. 32ECh. 2 - A runner runs at a pace of 8.5 minutes per mile....Ch. 2 - A driver drives an average speed of 58 miles per...Ch. 2 - A sports utility vehicle gets 12 miles per gallon...Ch. 2 - A hybrid electric vehicle (HEV) is a car with both...Ch. 2 - The following graph shows the concentration of an...Ch. 2 - The following graph shows the historical...Ch. 2 - A 28.4-cm3 sample of titanium has a mass of...Ch. 2 - A 1.5-cm3 sample of silicon has a mass of 3.5 g....Ch. 2 - A 5.00-L sample of pure glycerol has a mass of...Ch. 2 - A 3.80-mL sample of mercury has a mass of 51.4g....Ch. 2 - Ethylene glycol (antifreeze) has a density of...Ch. 2 - A thief plans to steal a bar of gold from a womans...Ch. 2 - Prob. 45ECh. 2 - A proton has a radius of approximately 110-13 cm...Ch. 2 - What did Einstein mean when he said, The most...Ch. 2 - Prob. 48ECh. 2 - Prob. 49ECh. 2 - Prob. 50ECh. 2 - Prob. 51ECh. 2 - Consider each of the following balances. Which one...Ch. 2 - Each of the following coins is photographed to...Ch. 2 - Obtain an outdoor thermometer and record the...
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