Introductory Chemistry: A Foundation
9th Edition
ISBN: 9781337399425
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 2, Problem 126AP
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Chapter 2 Solutions
Introductory Chemistry: A Foundation
Ch. 2.1 - Exercise 2.1 Write the numbers 357 and 0.0055 in...Ch. 2.2 - What if you were not allowed to use units for one...Ch. 2.5 - Exercise 2.2 Give the number of significant...Ch. 2.5 - Exercise 2.3 Give the answer for each calculation...Ch. 2.6 - Exercise 2.4 Wine is often bottled in 0.750-L...Ch. 2.6 - Exercise 2.5 Racing cars at the Indianapolis Motor...Ch. 2.7 - Exercise 2.6 Which temperature is colder, 172 K or...Ch. 2.7 - Exercise 2.7 Hot tubs are often maintained at 41...Ch. 2.7 - Exercise 2.8 An antifreeze solution in a car’s...Ch. 2.8 - Exercise 2.9A student wants to identify the main...
Ch. 2 - a. There are 365 days/year, 24 hours/day, 12...Ch. 2 - You go to a convenience store to buy candy and...Ch. 2 - When a marble is dropped into a beaker of water,...Ch. 2 - Consider water in each graduated cylinder as...Ch. 2 - What is the numerical value of a conversion...Ch. 2 - For each of the following numbers, indicate which...Ch. 2 - Consider the addition of “1 5.4” to “28.” What...Ch. 2 - Consider multiplying “26.2” by “16.43.” What would...Ch. 2 - In lab you report a measured volume of 128.7 mL of...Ch. 2 - Sketch two pieces of glassware: one that can...Ch. 2 - Oil floats on water but is “thicker” than water....Ch. 2 - Show how converting numbers to scientific notation...Ch. 2 - You are driving 65mph and take your eyes oil the...Ch. 2 - You have a1.0cm3 sample of lead and a1.0cm3 sample...Ch. 2 - The beakers shown below have different precisions....Ch. 2 - True or false? For any mathematical operation...Ch. 2 - Complete the following and explain each in your...Ch. 2 - For each of the following figures, a through d,...Ch. 2 - For the pin shown below, why is the third digit...Ch. 2 - Why can the length of the pin shown below not be...Ch. 2 - Use the figure below to answer the following...Ch. 2 - A represents a quantitative observation.Ch. 2 - Although your textbook lists (he rules for...Ch. 2 - When a large or small number is written in...Ch. 2 - When a large or small number is written in...Ch. 2 - Will the power of 10 have apositiveor...Ch. 2 - Prob. 6QAPCh. 2 - Express each of the following numbers...Ch. 2 - Rewrite each of the following as an “ordinary”...Ch. 2 - By how many places must the decimal point be...Ch. 2 - By how many places must the decimal point be...Ch. 2 - Prob. 11QAPCh. 2 - Write each of the following numbers as “ordinary”...Ch. 2 - Write each of the following numbers...Ch. 2 - Prob. 14QAPCh. 2 - What are the fundamental units of mass, length,...Ch. 2 - Give the metric prefix that corresponds to each of...Ch. 2 - Students often have trouble relating measurements...Ch. 2 - Students often have trouble relating measurements...Ch. 2 - Students often have trouble relating measurements...Ch. 2 - Students often have trouble relating measurements...Ch. 2 - The road sign I just passed says “New York City...Ch. 2 - The GPS in my car indicates that t have 100. mi...Ch. 2 - The tablecloth on my dining room table is 2 in...Ch. 2 - Who is taller, a man who is 1.62 in tall or a...Ch. 2 - The fundamental SI unit of length is the meter....Ch. 2 - 26. Which English unit of length or distance is...Ch. 2 - The unit of volume in the metric system is the...Ch. 2 - Which metric system unit is most appropriate for...Ch. 2 - When a measuring scale is used properly to the...Ch. 2 - In lab you report a measured volume of 158.6 mL of...Ch. 2 - For the pin shown in Fig. 2.5, why is the third...Ch. 2 - Why can the length of the pin shown in Fig. 2.5...Ch. 2 - Indicate the number of significant figures in each...Ch. 2 - Indicate the number of significant figures implied...Ch. 2 - When we round off a number, if the number to the...Ch. 2 - In a multiple-step calculation, is it better to...Ch. 2 - Round off each of the following numbers to three...Ch. 2 - Round off each of the following numbers to two...Ch. 2 - Round off each of the following numbers to the...Ch. 2 - Round off each of the following numbers to the...Ch. 2 - Consider the calculation indicated below:...Ch. 2 - The following water measurements are made: 18 mL...Ch. 2 - When the calculation(2.31)(4.9795103)/(1.9971104)...Ch. 2 - You are asked to determine the perimeter of the...Ch. 2 - When the sum 4.9965 + 2.11 + 3.887 is calculated,...Ch. 2 - How many digits after the decimal point should he...Ch. 2 - Evaluate each of the following mathematical...Ch. 2 - Evaluate each of the following mathematical...Ch. 2 - Without actually performing the calculations...Ch. 2 - Without actually performing the calculations...Ch. 2 - How many significant digits should be used to...Ch. 2 - Evaluate each of the following and write the...Ch. 2 - A represents a ratio based on an equivalence...Ch. 2 - How many significant figures are understood for...Ch. 2 - Given that 1 mi = 1760 yd, determine what...Ch. 2 - Given that 1 in. = 2.54 cm exactly, indicate what...Ch. 2 - For Exercises 57 and 58, apples cost $1.75 per...Ch. 2 - For Exercises 57 and 58, apples cost $1.75 per...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - 12.01 g of carbon contains6.021023 carbon atoms....Ch. 2 - Los Angeles and Honolulu are 2558 mi apart. What...Ch. 2 - The United States has high-speed trains running...Ch. 2 - The radius of an atom is on the order of1010 m....Ch. 2 - The temperature scale used in everyday life in...Ch. 2 - The point of water is at 32° on the Fahrenheit...Ch. 2 - Prob. 69QAPCh. 2 - The freezing point of water is _________ K.Ch. 2 - On both the Celsius and Kelvin temperature scales,...Ch. 2 - On which temperature scale (°F, °C, or K) does 1...Ch. 2 - Make the following temperature conversions: 44.2...Ch. 2 - Carry out the indicated temperature conversions. ...Ch. 2 - Convert the following Fahrenheit temperatures to...Ch. 2 - Convert the following Celsius temperatures to...Ch. 2 - The “Chemistry in Focus” segmentTiny...Ch. 2 - Perform the indicated temperature conversions. 275...Ch. 2 - Prob. 79QAPCh. 2 - The most common units for density are ___________.Ch. 2 - A kilogram of lead occupies a much smaller volume...Ch. 2 - If a solid block of glass, with a volume of...Ch. 2 - Is the density of a gaseous substance likely to be...Ch. 2 - What property of density makes it useful as an aid...Ch. 2 - Referring to Table 2.8, which substance listed is...Ch. 2 - Referring to Table 2.8, determine whether...Ch. 2 - For the masses and volumes indicated, calculate...Ch. 2 - For the masses and volumes indicated, calculate...Ch. 2 - The element bromine at room temperature is a...Ch. 2 - Sunflower oil has a density of 0.920 g/mL. What is...Ch. 2 - If 1000. mL of linseed oil has a mass of 929 g....Ch. 2 - A material will float on the surface of a liquid...Ch. 2 - Iron has a density of 7.87 g/cm3. If 52.4 g of...Ch. 2 - You want to make a rectangular box that weighs 2.0...Ch. 2 - Use the information in Table 2.8 to calculate the...Ch. 2 - Use the information in Table 2.8 to calculate the...Ch. 2 - 97. Indicate the number of significant digits in...Ch. 2 - Express each of the following as an “ordinary”...Ch. 2 - Write each of the following numbers in standard...Ch. 2 - For the measurement 0.003040 meters, indicate...Ch. 2 - Make the following conversions. 1 .25 in. to feet...Ch. 2 - On the planet Xgnu, the most common units of...Ch. 2 - You pass a road sign saying “New York 110 km.” If...Ch. 2 - Which of the following statements is (are) true? A...Ch. 2 - Suppose your car is rated at 45 mi/gal for highway...Ch. 2 - Prob. 106APCh. 2 - For a pharmacist dispensing pills or capsules, it...Ch. 2 - On the planet Xgnu, the natives have 14 fingers....Ch. 2 - For a material to float on the surface of water,...Ch. 2 - A gas cylinder having a volume of 10.5 L contains...Ch. 2 - Using Table 2.8, calculate the volume of 25.0 g of...Ch. 2 - Ethanol and benzene dissolve in each other. When...Ch. 2 - When 2891 is written in scientific notation, the...Ch. 2 - For each of the following numbers, if the number...Ch. 2 - For each of the following numbers, if the number...Ch. 2 - Prob. 116APCh. 2 - For each of the following numbers, by how many...Ch. 2 - For each of the following numbers, by how many...Ch. 2 - Express each of the following numbers in...Ch. 2 - Express each of the following as an “ordinary”...Ch. 2 - Prob. 121APCh. 2 - Prob. 122APCh. 2 - Prob. 123APCh. 2 - Draw a piece of lab glassware that can...Ch. 2 - Which distance is farther, 100 km or 50 mi?Ch. 2 - 1L= ________dm3= ________cm3= ________mLCh. 2 - The volume 0.250 L could also be expressed as mL.Ch. 2 - The distance 10.5 cm could also be expressed as m.Ch. 2 - Would an automobile moving at a constant speed of...Ch. 2 - Which weighs more, 0.001 g of water or 1 mg of...Ch. 2 - Which weighs more, 4.25 g of gold or 425 mg of...Ch. 2 - The length 500 m can also be expressed as nm.Ch. 2 - A perfect cube of unknown elemental composition...Ch. 2 - You are working on a project where you need the...Ch. 2 - Indicate the number of significant figures in each...Ch. 2 - Prob. 136APCh. 2 - Round off each of the following numbers to the...Ch. 2 - Prob. 138APCh. 2 - Prob. 139APCh. 2 - Prob. 140APCh. 2 - Prob. 141APCh. 2 - A rectangular solid measures 1.0 in by 2.4 mm by...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - Perform each of the following conversions, being...Ch. 2 - The mean distance from the earth to (he sun ismi....Ch. 2 - Given that one metric ton = 1000 kg, how many...Ch. 2 - Convert the following temperatures to kelvins. 0°C...Ch. 2 - Carry out the indicated temperature conversions....Ch. 2 - For the masses and volumes indicated, calculate...Ch. 2 - A sample of a liquid solvent has a density of...Ch. 2 - An organic solvent has a density of 1.31 g/mL....Ch. 2 - A solid metal sphere has a volume of 4.2 ft3. The...Ch. 2 - A sample containing 33.42 g of metal pellets is...Ch. 2 - Prob. 154APCh. 2 - Prob. 155APCh. 2 - Prob. 156APCh. 2 - Prob. 157APCh. 2 - Prob. 158APCh. 2 - Complete the following table: Number Exponential...Ch. 2 - For each of the mathematical expressions given: a....Ch. 2 - The longest river in the world is the Nile River...Ch. 2 - Secretariat is known as the horse with the fastest...Ch. 2 - A friend tells you that it is 69. 1 °F outside....Ch. 2 - The hottest temperature recorded in the United...Ch. 2 - The density of osmium (the densest metal)...Ch. 2 - The radius of a neon atom is 69 pm, and its mass...
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- Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.arrow_forward-AG|F=2E|V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: Acidic solution -0.93 +0.38 -0.51 -0.06 H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3 -0.28 -0.50 → -0.50 Basic solution 3-1.12 -1.57 -2.05 -0.89 PO HPO →→H2PO2 P PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH, 0.0 -0.5- 2 3 9 3 -1.5 -2.0 Pa H,PO H,PO H,PO -3 -1 0 2 4 Oxidation state, N 2 b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…arrow_forwardThese two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?arrow_forward
- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 1 2 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Explanation Check Click and drag to start drawing a structure. 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Priva ×arrow_forwardPredict the products of this organic reaction: Explanation Check IN NaBH3CN H+ ? Click and drag to start drawing a structure. D 5 C +arrow_forwardPredict the products of this organic reaction: H3O+ + ? • Draw all the reasonable products in the drawing area below. If there are no products, because no reaction will occur, check the box under the drawing area. • Include both major and minor products, if some of the products will be more common than others. • Be sure to use wedge and dash bonds if you need to distinguish between enantiomers. No reaction. Click and drag to start drawing a structure. dmarrow_forward
- Iarrow_forwardDraw the anti-Markovnikov product of the hydration of this alkene. this problem. Note for advanced students: draw only one product, and don't worry about showing any stereochemistry. Drawing dash and wedge bonds has been disabled for esc esc ☐ Explanation Check F1 1 2 F2 # 3 F3 + $ 14 × 1. BH THE BH3 2. H O NaOH '2 2' Click and drag to start drawing a structure. F4 Q W E R A S D % 905 LL F5 F6 F7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility < & 6 7 27 8 T Y U G H I F8 F9 F10 F11 F12 9 0 J K L P + // command option Z X C V B N M H H rol option commandarrow_forwardAG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, Narrow_forward
- 4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)arrow_forward2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)arrow_forward5. Consider the compounds shown below as ligands in coordination chemistry and identify their denticity; comment on their ability to form chelate complexes. (6 points) N N A B N N N IN N Carrow_forward
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