Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 2, Problem 100APP
The chapter sections to review are shown in parentheses at the end of each problem.
Round off or add zeros to the following calculated answers to give a final answer with three significant figures: (2.2)
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ
Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions
about this system:
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
atm
☑
18
Ar
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HCN is a weak acid.
acids:
0.29 mol of NaOH is added
to 1.0 L of a 1.2M HCN
solution.
bases:
☑
other:
0.09 mol of HCl is added to
acids:
1.0 L of a solution that is
bases:
0.3M in both HCN and
KCN.
other:
0,0,...
?
00.
18
Ar
日
Chapter 2 Solutions
Basic Chemistry
Ch. 2.1 - Write the abbreviation for each of the following:...Ch. 2.1 - Write the abbreviation for each of the following:...Ch. 2.1 - State the type of measurement in each of the...Ch. 2.1 - State the type of measurement in each of the...Ch. 2.1 - State the name of the unit and the type of...Ch. 2.1 - State the name of the unit and the type of...Ch. 2.1 - On a typical day, medical personnel may encounter...Ch. 2.1 - On a typical day, medical personnel may encounter...Ch. 2.2 - Use the metric ruler to measure the length in each...Ch. 2.2 - Determine the volume, in milliliters, of each...
Ch. 2.2 - How many significant figures are in each of the...Ch. 2.2 - How many significant figures are in each of the...Ch. 2.2 - In which of the following pairs do both numbers...Ch. 2.2 - In which of the following pairs do both numbers...Ch. 2.2 - Prob. 15PPCh. 2.2 - Prob. 16PPCh. 2.2 - Write each of the following in scientific notation...Ch. 2.2 - Write each of the following in scientific notation...Ch. 2.2 - Identify the numbers in each of the following...Ch. 2.2 - Prob. 20PPCh. 2.2 - Prob. 21PPCh. 2.2 - Identify the exact number(s), if any, in each of...Ch. 2.2 - Prob. 23PPCh. 2.2 - Identify each of the following as measured or...Ch. 2.3 - Round off each of the following calculator answers...Ch. 2.3 - Round off each of the calculator answers in...Ch. 2.3 - Round off or add zeros to each of the following to...Ch. 2.3 - Round off or add zeros to each of the following to...Ch. 2.3 - Perform each of the following operations, and give...Ch. 2.3 - Perform each of the following operations, and give...Ch. 2.3 - Prob. 31PPCh. 2.3 - Perform each of the following operations, and give...Ch. 2.4 - Write the abbreviation for each of the following...Ch. 2.4 - Write the abbreviation for each of the following...Ch. 2.4 - Write the complete name for each of the following...Ch. 2.4 - Prob. 36PPCh. 2.4 - Prob. 37PPCh. 2.4 - Prob. 38PPCh. 2.4 - Prob. 39PPCh. 2.4 - Prob. 40PPCh. 2.4 - Complete each of the following metric...Ch. 2.4 - Prob. 42PPCh. 2.4 - For each of the following pairs, which is the...Ch. 2.4 - For each of the following pairs, which is the...Ch. 2.5 - Why can two conversion factors be written for an...Ch. 2.5 - How can you check that you have written the...Ch. 2.5 - Write the equality and two conversion factors for...Ch. 2.5 - Write the equality and two conversion factors for...Ch. 2.5 - Prob. 49PPCh. 2.5 - Write the equality and two conversion factors, and...Ch. 2.5 - Write the equality and two conversion factors, and...Ch. 2.5 - Write the equality and two conversion factors, and...Ch. 2.5 - Write the equality and two conversion factors, and...Ch. 2.5 - Prob. 54PPCh. 2.5 - Prob. 55PPCh. 2.5 - Write an equality and two conversion factors for...Ch. 2.6 - Perform each of the following conversions using...Ch. 2.6 - Perform each of the following conversions using...Ch. 2.6 - Perform each of the following conversions using...Ch. 2.6 - Prob. 60PPCh. 2.6 - Use metric conversion factors to solve each of the...Ch. 2.6 - Use metric conversion factors to solve each of the...Ch. 2.6 - Solve each of the following problems using one or...Ch. 2.6 - Solve each of the following problems using one or...Ch. 2.6 - Using conversion factors, solve each of the...Ch. 2.6 - Using conversion factors, solve each of the...Ch. 2.6 - Using conversion factors, solve each of the...Ch. 2.6 - Using conversion factors, solve each of the...Ch. 2.7 - Determine the density (g/mL) for each of the...Ch. 2.7 - Determine the density (g/mL) for each of the...Ch. 2.7 - Prob. 71PPCh. 2.7 - What is the density (g/mL) of each of the...Ch. 2.7 - Use the density values in Table 2.10 to solve each...Ch. 2.7 - Use the density values in Table 2.10 to solve each...Ch. 2.7 - Use the density values in Table 2.10 to solve each...Ch. 2.7 - Use the density values in Table 2.10 to solve each...Ch. 2.7 - In an old trunk, you find a piece of metal that...Ch. 2.7 - Suppose you have two 100-mL graduated cylinders....Ch. 2.7 - Solve each of the following problems: a. A urine...Ch. 2.7 - Prob. 80PPCh. 2.7 - Prob. 81PPCh. 2.7 - a. Write an equality and two conversion factors...Ch. 2 - The chapter sections to review are shown in...Ch. 2 - The chapter sections to review are shown in...Ch. 2 - The chapter sections to review are shown in...Ch. 2 - Prob. 86UTCCh. 2 - Prob. 87UTCCh. 2 - The chapter sections to review are shown in...Ch. 2 - Prob. 89UTCCh. 2 - Prob. 90UTCCh. 2 - Prob. 91UTCCh. 2 - Prob. 92UTCCh. 2 - Prob. 93UTCCh. 2 - Prob. 94UTCCh. 2 - Prob. 95UTCCh. 2 - Prob. 96UTCCh. 2 - Prob. 97APPCh. 2 - The chapter sections to review are shown in...Ch. 2 - The chapter sections to review are shown in...Ch. 2 - The chapter sections to review are shown in...Ch. 2 - Prob. 101APPCh. 2 - Prob. 102APPCh. 2 - Prob. 103APPCh. 2 - Prob. 104APPCh. 2 - Prob. 105APPCh. 2 - Prob. 106APPCh. 2 - Prob. 107APPCh. 2 - Prob. 108APPCh. 2 - Prob. 109APPCh. 2 - Prob. 110APPCh. 2 - Prob. 111APPCh. 2 - Prob. 112APPCh. 2 - Prob. 113APPCh. 2 - Prob. 114APPCh. 2 - Prob. 115APPCh. 2 - Prob. 116APPCh. 2 - The water level in a graduated cylinder initially...Ch. 2 - Prob. 118APPCh. 2 - Prob. 119APPCh. 2 - Prob. 120APPCh. 2 - Prob. 121APPCh. 2 - Prob. 122APPCh. 2 - Prob. 123APPCh. 2 - Prob. 124APPCh. 2 - Prob. 125APPCh. 2 - Prob. 126APPCh. 2 - The following problems at related io the topics in...Ch. 2 - The following problems at related io the topics in...Ch. 2 - The following problems at related io the topics in...Ch. 2 - The following problems at related io the topics in...Ch. 2 - Prob. 131CPCh. 2 - The following problems at related io the topics in...Ch. 2 - Prob. 133CPCh. 2 - The following problems at related io the topics in...
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- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1arrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?arrow_forward
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