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Chemistry
- Calculate G and K at 25C for the reactions in Exercises 38 and 42.arrow_forwarda Calculate K1, at 25C for phosphoric acid: H3PO4(aq)H+(aq)+H2PO4(aq) b Which thermodynamic factor is the most significant in accounting for the fact that phosphoric acid is a weak acid? Why ?arrow_forwardCalculate K at 25°C for each of the reactions referred to in Question 32. Assume smallest whole-number coefficients.arrow_forward
- Use the values for G f in Appendix 1 to calculate Ksp for barium sulfate at 25C. Compare with the value given in Chapter 15.arrow_forwardThe standard potential, E, for the reaction of Zn(s) and Cl2(g) is +2.12 V. What is the standard free energy change, rG, for the reaction?arrow_forwardUsing the following data, calculate the value of Ksp for Ba(NO3)2, one of the least soluble of the common nitrate salts. Species Gfo Ba2+(aq) 561 KJ/mol NO3(aq) 109 KJ/mol Ba(NO3)2(s) 797KJ/molarrow_forward
- The following reaction occurs in pure water: H2O(l)+H2O(l)H3O+(aq)+OH-(aq) which is often abbreviated as H2O(l)H+(aq)+OH-(aq) For this reaction, G = 79.9 kJ/mol at 25C. Calculate the value of G for this reaction at 25C when [OH] = 0.15 M and [H+] = 0.71 M.arrow_forward12.67 Hydrofluoric acid is a weak acid used in the building industry to etch patterns into glass for elegant windows. Because it dissolves glass, it is the only inorganic acid that must be stored in plastic containers. A 0.1 M solution of HF has a pH of 2.1. Calculate [Hj0"| in this solution.arrow_forwardCalculate K for the reaction SnO2(s) + 2 CO(g) Sn(s) + 2 CO2(g) given the following information: SnO2(s)+2H2(g)Sn(s)+2H2O(g)K=8.12H2(g)+CO2(g)H2O(g)+CO(g)K=0.771arrow_forward
- The equilibrium constant for a reaction is 31015 (a) Without carrying out any calculation, discuss whether ?G° for the reaction is positive or negative. (b) Calculate ?G° for this reaction.arrow_forwardWithout doing any calculations, predict the sign of rS for the following reaction: Zn(s) + 2 HCl(aq) ZnCl2(aq) + H2(g) (a) rS 0 (b) rS = 0 (c) rS 0arrow_forwardCalculate the ΔG° (in kJ/mol) for the following reaction at 25.0℃.K^+1(aq) + Li(s) → K(s) + Li^+1(aq)arrow_forward
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