ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
ORGANIC CHEMISTRY-PRINT (LL)-W/WILEY
4th Edition
ISBN: 9781119761105
Author: Klein
Publisher: WILEY
Question
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Chapter 19.3, Problem 5CC

a)

Interpretation Introduction

Interpretation:

To determine the necessary reagent to achieve the following transformation.

Concept Introduction:

Reagent: it is a substance or compound added to a chemical reaction and which donates a chemical ingredient (a compound of mixture, typically of organic or inorganic substance.

Examples include the Collins reagent, Fenton’s reagent and the most popular Grignard’s reagent etc…

Ozonolysis: it’s an organic reaction where the unsaturated bonds alkanes and alkynes compounds are broken with ozone.

Alkenes and alkynes form organic compound, which have multiple carbon-carbon bond and it has been replaced by a carbonyl group.

Oxidizing reagent: it’s composed of oxidant and oxidizer. It has a tendency to oxidized the other substance.

It’s formed when a molecule or ions loose its electron.

Common oxidizing agents are oxygen, hydrogen peroxide, and halogens.

Redox reaction: redox reaction is that type of reaction where both oxidation and reduction takes place.

This is the popular Aromatic electrophilic substitution reaction and are classified into two types

1-Friedel Craft Alkylation:-It involves the alkylation of an aromatic ring with an alkyl halide using a strong Lewis acid catalyst with anhydrous Ferrichloride as a catalyst and thhe alkyl group attached at the former site of the chloride ion.

2-Fridel Craft Acylation: - It involves the acylation of aromatic rings with an acyl chloride using a strong Lewis acid catalyst. Like AlCl3 catalyst.

b)

Interpretation Introduction

Interpretation:

To determine the necessary reagent to achieve the following transformation.

Concept Introduction:

Reagent: it is a substance or compound added to a chemical reaction and which donates a chemical ingredient (a compound of mixture, typically of organic or inorganic substance.

Examples include the Collins reagent, Fenton’s reagent and the most popular Grignard’s reagent etc…

Ozonolysis: it’s an organic reaction where the unsaturated bonds alkanes and alkynes compounds are broken with ozone.

Alkenes and alkynes form organic compound, which have multiple carbon-carbon bond and it has been replaced by a carbonyl group.

Oxidizing reagent: it’s composed of oxidant and oxidizer. It has a tendency to oxidized the other substance.

It’s formed when a molecule or ions loose its electron.

Common oxidizing agents are oxygen, hydrogen peroxide, and halogens.

Redox reaction: redox reaction is that type of reaction where both oxidation and reduction takes place.

This is the popular Aromatic electrophilic substitution reaction and are classified into two types

1-Friedel Craft Alkylation:-It involves the alkylation of an aromatic ring with an alkyl halide using a strong Lewis acid catalyst with anhydrous Ferrichloride as a catalyst and thhe alkyl group attached at the former site of the chloride ion.

2-Fridel Craft Acylation: - It involves the acylation of aromatic rings with an acyl chloride using a strong Lewis acid catalyst. Like AlCl3 catalyst.

c)

Interpretation Introduction

Interpretation:

To determine the necessary reagent to achieve the following transformation.

Concept Introduction:

Reagent: it is a substance or compound added to a chemical reaction and which donates a chemical ingredient (a compound of mixture, typically of organic or inorganic substance.

Examples include the Collins reagent, Fenton’s reagent and the most popular Grignard’s reagent etc…

Ozonolysis: it’s an organic reaction where the unsaturated bonds alkanes and alkynes compounds are broken with ozone.

Alkenes and alkynes form organic compound, which have multiple carbon-carbon bond and it has been replaced by a carbonyl group.

Oxidizing reagent: it’s composed of oxidant and oxidizer. It has a tendency to oxidized the other substance.

It’s formed when a molecule or ions loose its electron.

Common oxidizing agents are oxygen, hydrogen peroxide, and halogens.

Redox reaction: redox reaction is that type of reaction where both oxidation and reduction takes place.

This is the popular Aromatic electrophilic substitution reaction and are classified into two types

1-Friedel Craft Alkylation:-It involves the alkylation of an aromatic ring with an alkyl halide using a strong Lewis acid catalyst with anhydrous Ferrichloride as a catalyst and thhe alkyl group attached at the former site of the chloride ion.

2-Fridel Craft Acylation: - It involves the acylation of aromatic rings with an acyl chloride using a strong Lewis acid catalyst. Like AlCl3 catalyst.

d)

Interpretation Introduction

Interpretation:

To determine the necessary reagent to achieve the following transformation.

Concept Introduction:

Reagent: it is a substance or compound added to a chemical reaction and which donates a chemical ingredient (a compound of mixture, typically of organic or inorganic substance.

Examples include the Collins reagent, Fenton’s reagent and the most popular Grignard’s reagent etc…

Ozonolysis: it’s an organic reaction where the unsaturated bonds alkanes and alkynes compounds are broken with ozone.

Alkenes and alkynes form organic compound, which have multiple carbon-carbon bond and it has been replaced by a carbonyl group.

Oxidizing reagent: it’s composed of oxidant and oxidizer. It has a tendency to oxidized the other substance.

It’s formed when a molecule or ions loose its electron.

Common oxidizing agents are oxygen, hydrogen peroxide, and halogens.

Redox reaction: redox reaction is that type of reaction where both oxidation and reduction takes place.

This is the popular Aromatic electrophilic substitution reaction and are classified into two types

1-Friedel Craft Alkylation:-It involves the alkylation of an aromatic ring with an alkyl halide using a strong Lewis acid catalyst with anhydrous Ferrichloride as a catalyst and thhe alkyl group attached at the former site of the chloride ion.

2-Fridel Craft Acylation: - It involves the acylation of aromatic rings with an acyl chloride using a strong Lewis acid catalyst. Like AlCl3 catalyst.

e)

Interpretation Introduction

Interpretation:

To determine the necessary reagent to achieve the following transformation.

Concept Introduction:

Reagent: it is a substance or compound added to a chemical reaction and which donates a chemical ingredient (a compound of mixture, typically of organic or inorganic substance.

Examples include the Collins reagent, Fenton’s reagent and the most popular Grignard’s reagent etc…

Ozonolysis: it’s an organic reaction where the unsaturated bonds alkanes and alkynes compounds are broken with ozone.

Alkenes and alkynes form organic compound, which have multiple carbon-carbon bond and it has been replaced by a carbonyl group.

Oxidizing reagent: it’s composed of oxidant and oxidizer. It has a tendency to oxidized the other substance.

It’s formed when a molecule or ions loose its electron.

Common oxidizing agents are oxygen, hydrogen peroxide, and halogens.

Redox reaction: redox reaction is that type of reaction where both oxidation and reduction takes place.

This is the popular Aromatic electrophilic substitution reaction and are classified into two types

1-Friedel Craft Alkylation:-It involves the alkylation of an aromatic ring with an alkyl halide using a strong Lewis acid catalyst with anhydrous Ferrichloride as a catalyst and thhe alkyl group attached at the former site of the chloride ion.

2-Fridel Craft Acylation: - It involves the acylation of aromatic rings with an acyl chloride using a strong Lewis acid catalyst. Like AlCl3 catalyst.

f)

Interpretation Introduction

Interpretation:

To determine the necessary reagent to achieve the following transformation.

Concept Introduction:

Reagent: it is a substance or compound added to a chemical reaction and which donates a chemical ingredient (a compound of mixture, typically of organic or inorganic substance.

Examples include the Collins reagent, Fenton’s reagent and the most popular Grignard’s reagent etc…

Ozonolysis: it’s an organic reaction where the unsaturated bonds alkanes and alkynes compounds are broken with ozone.

Alkenes and alkynes form organic compound, which have multiple carbon-carbon bond and it has been replaced by a carbonyl group.

Oxidizing reagent: it’s composed of oxidant and oxidizer. It has a tendency to oxidized the other substance.

It’s formed when a molecule or ions loose its electron.

Common oxidizing agents are oxygen, hydrogen peroxide, and halogens.

Redox reaction: redox reaction is that type of reaction where both oxidation and reduction takes place.

This is the popular Aromatic electrophilic substitution reaction and are classified into two types

1-Friedel Craft Alkylation:-It involves the alkylation of an aromatic ring with an alkyl halide using a strong Lewis acid catalyst with anhydrous Ferrichloride as a catalyst and thhe alkyl group attached at the former site of the chloride ion.

2-Fridel Craft Acylation: - It involves the acylation of aromatic rings with an acyl chloride using a strong Lewis acid catalyst. Like AlCl3 catalyst.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv
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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."
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