(a)
Interpretation:
The structure should be drawn for each of the given (IUPAC) molecule.
Concept introduction:
Systematic Name :It is standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC(international Union for pure and applied Chemistry)rules. IUPAC names consist of three parts in major namely prefix and word.
Prefix represents the substituent present in the molecule .it can be any alkyl group and
Suffix represent the substituent present in the
molecule. It can be any
Root word represents the longest continuous carbon skeleton present in the organic molecule.
Common Name it is quite opposite to systematic name which is used for branched groups.
Chirality It refers to a carbon atom in a molecule that contain four different substituents.
Enantiomers: they are chiral molecule whose mirror images are not superimposable.
R&S Nomenclature: It is used to assign the molecule using the CIP rules.
The CIP-rules are as follows:
Select the chiral carbon and assign the number according to the decreasing
If the numbering follows clockwise direction then molecule is term R and if it follows anti-clockwise direction then molecule is termed as S.
(b)
Interpretation:
The structure should be drawn for each of the given (IUPAC) molecule.
Concept introduction:
Systematic Name :It is standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC(international Union for pure and applied Chemistry)rules. IUPAC names consist of three parts in major namely prefix and word.
Prefix represents the substituent present in the molecule .it can be any alkyl group and carboxylic acid, alcohol etc.…
Suffix represent the substituent present in the molecule. It can be any alkene, alkyne, alcohol, carboxylic acid, alcohol etc.…
Root word represents the longest continuous carbon skeleton present in the organic molecule.
Common Name it is quite opposite to systematic name which is used for branched groups.
Chirality It refers to a carbon atom in a molecule that contain four different substituents.
Enantiomers: they are chiral molecule whose mirror images are not superimposable.
R&S Nomenclature: It is used to assign the molecule using the CIP rules.
The CIP-rules are as follows:
Select the chiral carbon and assign the number according to the decreasing atomic mass of atom attached to it.
If the numbering follows clockwise direction then molecule is term R and if it follows anti-clockwise direction then molecule is termed as S.
(c)
Interpretation:
The structure should be drawn for each of the given (IUPAC) molecule.
Concept introduction:
Systematic Name :It is standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC(international Union for pure and applied Chemistry)rules. IUPAC names consist of three parts in major namely prefix and word.
Prefix represents the substituent present in the molecule .it can be any alkyl group and carboxylic acid, alcohol etc.…
Suffix represent the substituent present in the molecule. It can be any alkene, alkyne, alcohol, carboxylic acid, alcohol etc.…
Root word represents the longest continuous carbon skeleton present in the organic molecule.
Common Name it is quite opposite to systematic name which is used for branched groups.
Chirality It refers to a carbon atom in a molecule that contain four different substituents.
Enantiomers: they are chiral molecule whose mirror images are not superimposable.
R&S Nomenclature: It is used to assign the molecule using the CIP rules.
The CIP-rules are as follows:
Select the chiral carbon and assign the number according to the decreasing atomic mass of atom attached to it.
If the numbering follows clockwise direction then molecule is term R and if it follows anti-clockwise direction then molecule is termed as S.
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Chapter 19 Solutions
ORGANIC CHEMISTRY (LL) >CUSTOM PACKAGE<
- 2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJarrow_forwardci Draw the major product(s) of the following reactions: (3 pts) CH3 HNO3/H2SO4 HNO3/ H2SO4 OCH3 (1 pts)arrow_forwardProvide the product for the reactionarrow_forward
- What is the net ionic equation for the reaction between tin(IV) sulfide and nitric acid?arrow_forwardThe combustion of 28.8 g of NH3 consumes exactly _____ g of O2. 4 NH3 + 7 O2 ----> 4 NO2 + 6 H2Oarrow_forwardWhat is the molecular formula of the bond-line structure shown below OH HO ○ C14H12O2 ○ C16H14O2 ○ C16H12O2 O C14H14O2arrow_forward
- Check all molecules that are acids on the list below. H2CO3 HC2H3O2 C6H5NH2 HNO3 NH3arrow_forwardFrom the given compound, choose the proton that best fits each given description. a CH2 CH 2 Cl b с CH2 F Most shielded: (Choose one) Least shielded: (Choose one) Highest chemical shift: (Choose one) Lowest chemical shift: (Choose one) ×arrow_forwardConsider this molecule: How many H atoms are in this molecule? How many different signals could be found in its 1H NMR spectrum? Note: A multiplet is considered one signal.arrow_forward
- For each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither. Compound m/z of M* peak m/z of M + 2 peak ratio of M+ : M + 2 peak Which element is present? A 122 no M + 2 peak not applicable (Choose one) B 78 80 3:1 (Choose one) C 227 229 1:1 (Choose one)arrow_forwardShow transformation from reactant to product, step by step. *see imagearrow_forwardCheck the box if the molecule contains the listed item. *See imagearrow_forward
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