The major product, when the given amine undergoes exhaustive methylation, treatment with Ag 2 O , and heating is to be predicted. Concept introduction: Hofmann elimination reactions comprise the conversion of an amine into an alkene . The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Question

1. How many neighbors does the proton that produces the multiplet below have? 2. 3. اللـ Draw a partial structure from the multiplet below. (The integration of the multiplet is 6) M Using the additivity constants found in appendix G of your lab manual, calculate the approximate chemical shifts of the protons indicated below. (Show your work!!!) B A Br SH

Answer 1

Question

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

1. How many neighbors does the proton that produces the multiplet below have? 2. 3. اللـ Draw a partial structure from the multiplet below. (The integration of the multiplet is 6) M Using the additivity constants found in appendix G of your lab manual, calculate the approximate chemical shifts of the protons indicated below. (Show your work!!!) B A Br SH

1) Suppose 0.1 kg ice at 0°C (273K) is in 0.5kg water at 20°C (293K). What is the change in entropy of the ice as it melts at 0°? To produce the original "water gas" mixture, carbon (in a combustible form known as coke) is reacted with steam: 131.4 kJ + H20(g) + C(s) → CO(g) + H2(g) From this information and the equations in the previous problem, calculate the enthalpy for the combustion or carbon to form carbon dioxide. kindly show me how to solve this long problem. Thanks

4. An 'H-NMR of a compound is acquired. The integration for signal A is 5692 and the integration for signal B is 25614. What is the simplest whole number ratio of protons for signals A and B? (Show your work!!!) 5. Assign the carbons in the NMR below as either carbonyl, aromatic, or alkyl. 200 150 100 50 ō (ppm) 1

Answer 2

Question

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 6

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 7

Chapter 19.14, Problem 19.20P

(a)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The formation of major product, when the given amine undergo exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The major product, when the given amine undergoes exhaustive methylation, treatment with Ag2O, and heating is to be predicted.

Concept introduction:

Hofmann elimination reactions comprise the conversion of an amine into an alkene. The quaternary ammonium salt is formed as an intermediate in these reactions followed by beta elimination to form the desired product. The major alkene will have less substitution at double bond of the alkene compound.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 21

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 22

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 23

Trending nowThis is a popular solution!

Answer 24

Trending nowThis is a popular solution!

Answer 25

Trending nowThis is a popular solution!

Answer 26

Trending now

Answer 27

This is a popular solution!

Answer 28

See solution

Check out sample textbook solution

Answer 29

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author explains how Hofmann elimination reactions comprise the conversion of an amine into an alkene.

Chapter 19 Solutions