To propose: The mechanism for the given reaction. Interpretation: The mechanism for the given reaction is to be proposed. Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines . Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 1

Question

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 2

Question

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 3

Question

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 4

Question

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

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Answer 5

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 6

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 7

Chapter 19, Problem 19.55SP

(a)

Interpretation Introduction

To propose: The mechanism for the given reaction.

Interpretation: The mechanism for the given reaction is to be proposed.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 8

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 9

(b)

Interpretation Introduction

To describe: The reason that given reaction readily displaces fluoride as the leaving group.

Interpretation: The reason that given reaction readily displaces fluoride as the leaving group is to be described.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 10

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 11

(c)

Interpretation Introduction

To describe: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene.

Interpretation: The reason that given reaction stops with the desired products, rather than reacting with another dinitrofluorobenzene are to be predicted.

Concept introduction: The organic compounds which contain the functional groups containing a nitrogen atom with a lone pair of electrons are amines. Amines are the derivatives of ammonia. They have more than one hydrogen atoms. These hydrogen atoms can replace with an alkyl or aryl group. Amines can act as both bases and nucleophiles due to the unshared electron pair.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 19.2A - Prob. 19.1P Ch. 19.2B - Prob. 19.2P Ch. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4P Ch. 19.4 - Prob. 19.5P Ch. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7P Ch. 19.8C - Prob. 19.8P Ch. 19.8C - Prob. 19.9P Ch. 19.8D - a. Show how fragmentation occurs to give the base...

Solution Summary: The author proposes the mechanism for the given reaction.

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Chapter 19 Solutions