
Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134566290
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 19, Problem 9SAQ
Interpretation Introduction
Interpretation:
To find out the Ecell for an
Concept Introduction:
To generate electrical energy using the electrochemical cell, the
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 19 Solutions
Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
Ch. 19 - Prob. 1ECh. 19 - Explain the difference between a voltaic (or...Ch. 19 - Prob. 3ECh. 19 - Prob. 4ECh. 19 - Prob. 5ECh. 19 - Prob. 6ECh. 19 - What is the definition of the standard cell...Ch. 19 - Describe the basic features of a cell diagram (or...Ch. 19 - Why do some electrochemical cells employ inert...Ch. 19 - Describe the standard hydrogen electrode (SHE) and...
Ch. 19 - How is the cell potential of an electrochemical...Ch. 19 - Prob. 12ECh. 19 - Prob. 13ECh. 19 - How can Table 19.1be used to predict whether or...Ch. 19 - Explain why Ecell , Grxn , and K are all...Ch. 19 - Does a redox reaction with a small equilibrium...Ch. 19 - How does Ecell depend on the concentrations of the...Ch. 19 - Prob. 18ECh. 19 - What is a concentration electrochemical cell?Ch. 19 - What are the anode and cathode reactions in a...Ch. 19 - What are the anode and cathode reactions in a...Ch. 19 - Prob. 22ECh. 19 - What is a fuel cell? What is the most common type...Ch. 19 - The anode of an electrolytic cell must be...Ch. 19 - What species is oxidized, and what species is...Ch. 19 - If an electrolytic cell contains a mixture of...Ch. 19 - Why does the electrolysis of an aqueous sodium...Ch. 19 - What is overvoltage in an electrochemical cell?...Ch. 19 - How is the amount of current flowing through an...Ch. 19 - Prob. 30ECh. 19 - Prob. 31ECh. 19 - Prob. 32ECh. 19 - Balance each redox reaction occurring in acidic...Ch. 19 - Prob. 34ECh. 19 - Balance each redox reaction occurring in acidic...Ch. 19 - Prob. 36ECh. 19 - Prob. 37ECh. 19 - Balance each redox reaction occurring in basic...Ch. 19 - Prob. 39ECh. 19 - Prob. 40ECh. 19 - Calculate the standard cell potential for each of...Ch. 19 - Prob. 42ECh. 19 - Consider the voltaic cell: Determine the direction...Ch. 19 - Prob. 44ECh. 19 - Use line notation to represent each...Ch. 19 - Use line notation to represent each...Ch. 19 - a sketch of the voltaic cell represented by the...Ch. 19 - Prob. 48ECh. 19 - Determine whether or not each redox reaction...Ch. 19 - Prob. 50ECh. 19 - Which metal could you use to reduce Mn2+ ions but...Ch. 19 - Prob. 52ECh. 19 - Prob. 53ECh. 19 - Prob. 54ECh. 19 - Prob. 55ECh. 19 - Prob. 56ECh. 19 - Calculate Ecell for each balanced redox reaction...Ch. 19 - Prob. 58ECh. 19 - Prob. 59ECh. 19 - Which metal is the best reducing agent? Mn Al Ni...Ch. 19 - Use tabulated electrode potentials to calculate...Ch. 19 - Use tabulated electrode potentials to calculate...Ch. 19 - Prob. 63ECh. 19 - Calculate the equilibrium constant for each of the...Ch. 19 - Calculate the equilibrium constant for the...Ch. 19 - Prob. 66ECh. 19 - Calculate Grxn and Ecell for a redox reaction with...Ch. 19 - Prob. 68ECh. 19 - Prob. 69ECh. 19 - Prob. 70ECh. 19 - Prob. 71ECh. 19 - Prob. 72ECh. 19 - Prob. 73ECh. 19 - Prob. 74ECh. 19 - Prob. 75ECh. 19 - Consider the concentration cell: Label the anode...Ch. 19 - Prob. 77ECh. 19 - Prob. 78ECh. 19 - Prob. 79ECh. 19 - Prob. 80ECh. 19 - Refer to the tabulated values of Gf in Appendix...Ch. 19 - Refer to the tabulated values of Gf in Appendix...Ch. 19 - Prob. 83ECh. 19 - Prob. 84ECh. 19 - Prob. 85ECh. 19 - Prob. 86ECh. 19 - Prob. 87ECh. 19 - Which products are obtained in the electrolysis of...Ch. 19 - Write equations for the half-reactions that occur...Ch. 19 - Which products are obtained in the electrolysis of...Ch. 19 - Prob. 91ECh. 19 - Write equations for the half-reactions that occur...Ch. 19 - Prob. 93ECh. 19 - Prob. 94ECh. 19 - Prob. 95ECh. 19 - Silver can be electroplated at the cathode of an...Ch. 19 - A major source of sodium metal is the electrolysis...Ch. 19 - Prob. 98ECh. 19 - Prob. 99ECh. 19 - Prob. 100ECh. 19 - Consider the molecular view of an AL strip and...Ch. 19 - Consider the molecular view of an electrochemical...Ch. 19 - Prob. 103ECh. 19 - Prob. 104ECh. 19 - The cell potential of this electrochemical cell...Ch. 19 - Prob. 106ECh. 19 - Prob. 107ECh. 19 - Consider the reaction shown here occurring at...Ch. 19 - Prob. 109ECh. 19 - What voltage can theoretically be achieved in a...Ch. 19 - A battery relies on the oxidation of magnesium and...Ch. 19 - A rechargeable battery is constructed based on a...Ch. 19 - If a water electrolysis cell operates at a current...Ch. 19 - Prob. 114ECh. 19 - Prob. 115ECh. 19 - Prob. 116ECh. 19 - Calculate Grxn and K for each reaction. The...Ch. 19 - Calculate Grxn and K for each reaction. The...Ch. 19 - The molar mass of a metal (M) is 50.9 g/mol; it...Ch. 19 - A metal forms the fluoride MF3. Electrolysis of...Ch. 19 - A sample of impure tin of mass 0.535 g is...Ch. 19 - Prob. 122ECh. 19 - Prob. 123ECh. 19 - A 215 mL sample of a 0.500 M NaCl solution with an...Ch. 19 - Prob. 125ECh. 19 - Prob. 126ECh. 19 - Prob. 127ECh. 19 - Prob. 128ECh. 19 - Prob. 129ECh. 19 - Prob. 130ECh. 19 - Prob. 131ECh. 19 - Three electrolytic cells are connected in a...Ch. 19 - Prob. 133ECh. 19 - Prob. 134ECh. 19 - Prob. 135ECh. 19 - Prob. 136ECh. 19 - Prob. 137ECh. 19 - Prob. 138ECh. 19 - Prob. 139ECh. 19 - Prob. 140ECh. 19 - Design a device that uses as electrochemical cell...Ch. 19 - Using a library or the Internet, research a fuel...Ch. 19 - Prob. 143ECh. 19 - Balance the redox reaction equation (occurring in...Ch. 19 - Prob. 2SAQCh. 19 - Prob. 3SAQCh. 19 - Refer to Table 19.1 to determine which statement...Ch. 19 - Prob. 5SAQCh. 19 - The Zn/Zn2+ electrode has a standard electrode...Ch. 19 - Refer to Table 19.1 to calculate G for the...Ch. 19 - A redox reaction has an Ecell=0.56V . What can you...Ch. 19 - Prob. 9SAQCh. 19 - Prob. 10SAQCh. 19 - Prob. 11SAQCh. 19 - Prob. 12SAQCh. 19 - Which reaction occurs at the cathode of an...Ch. 19 - Copper is plated onto the cathode of an...Ch. 19 - Prob. 15SAQ
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