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Chapter 19, Problem 1E
Interpretation Introduction

To determine: Define oxidation and reduction and the basic procedure for balancing redox reactions.

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Answer to Problem 1E

Solution:

Oxidation is the loss of electrons. Reduction is the gain of electrons.

Explanation of Solution

When an atom loses electrons, it undergoes oxidation and has an increase in its oxidation state, which is an increase in the charge. The reverse is true for a reduction, where reduction is when an atom gains electrons and has a decrease in oxidation state which decreases the charge on the atom. To properly balance a redox reaction, you must balance both number of atoms on each side of the reaction and the charge. Therefore, we use something called the half-reaction method of balancing which is described below:

  Al(s)+Cu2+(aq)Al3+(aq)+Cu(s)

First you can assign oxidation states to each atom to find which atoms are being oxidized and reduced. We can see that Al goes from a charge of 0 to 3+, therefore, it is being oxidized. The Cu goes from 2+ to 0, which is a reduction. So, now we separate the two processes into two half reactions:

Oxidation:

AlAl3+

Reduction:

Cu2+Cu

Now, we need to balance the atoms of each half reaction, but in this case they are already balanced. The next step is to balance the reaction regarding charges, so to counter the positive charge on either side of the reaction; we add electrons to make the charge equal on both sides:

  AlAl3++3e

  Cu2++2eCu

Now, we make the electrons in both half reactions equal, so we can multiply the top reaction by 2, and the bottom reaction by 3 resulting in 6 electrons total in each reaction:

  2Al2Al3++6e3Cu2++6e3Cu

Now, we can combine the two half reactions and cancelling any similar terms on both sides:

  2Al +3Cu2+2Al3++3Cu

Conclusion

Oxidation is the loss of electrons and reduction is the gain of electrons. To properly balance the reactions, we use half reactions which separate the oxidation and reduction. Then we ultimately balance the atoms and charges, multiply each reaction so the electrons are the same in each reaction, and then combine the reactions to obtain the overall balanced reaction equation.

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Chapter 19 Solutions

Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)

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Mn Al Ni...Ch. 19 - Use tabulated electrode potentials to calculate...Ch. 19 - Use tabulated electrode potentials to calculate...Ch. 19 - Prob. 63ECh. 19 - Calculate the equilibrium constant for each of the...Ch. 19 - Calculate the equilibrium constant for the...Ch. 19 - Prob. 66ECh. 19 - Calculate Grxn and Ecell for a redox reaction with...Ch. 19 - Prob. 68ECh. 19 - Prob. 69ECh. 19 - Prob. 70ECh. 19 - Prob. 71ECh. 19 - Prob. 72ECh. 19 - Prob. 73ECh. 19 - Prob. 74ECh. 19 - Prob. 75ECh. 19 - Consider the concentration cell: Label the anode...Ch. 19 - Prob. 77ECh. 19 - Prob. 78ECh. 19 - Prob. 79ECh. 19 - Prob. 80ECh. 19 - Refer to the tabulated values of Gf in Appendix...Ch. 19 - Refer to the tabulated values of Gf in Appendix...Ch. 19 - Prob. 83ECh. 19 - Prob. 84ECh. 19 - Prob. 85ECh. 19 - Prob. 86ECh. 19 - Prob. 87ECh. 19 - Which products are obtained in the electrolysis of...Ch. 19 - Write equations for the half-reactions that occur...Ch. 19 - Which products are obtained in the electrolysis of...Ch. 19 - Prob. 91ECh. 19 - Write equations for the half-reactions that occur...Ch. 19 - Prob. 93ECh. 19 - Prob. 94ECh. 19 - Prob. 95ECh. 19 - Silver can be electroplated at the cathode of an...Ch. 19 - A major source of sodium metal is the electrolysis...Ch. 19 - Prob. 98ECh. 19 - Prob. 99ECh. 19 - Prob. 100ECh. 19 - Consider the molecular view of an AL strip and...Ch. 19 - Consider the molecular view of an electrochemical...Ch. 19 - Prob. 103ECh. 19 - Prob. 104ECh. 19 - The cell potential of this electrochemical cell...Ch. 19 - Prob. 106ECh. 19 - Prob. 107ECh. 19 - Consider the reaction shown here occurring at...Ch. 19 - Prob. 109ECh. 19 - What voltage can theoretically be achieved in a...Ch. 19 - A battery relies on the oxidation of magnesium and...Ch. 19 - A rechargeable battery is constructed based on a...Ch. 19 - If a water electrolysis cell operates at a current...Ch. 19 - Prob. 114ECh. 19 - Prob. 115ECh. 19 - Prob. 116ECh. 19 - Calculate Grxn and K for each reaction. 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