Use of tritium as a component of fluorescent watch dials and its half life is given. The year upto which the time at night can be read using the given kind of watch is to be calculated. Concept introduction: A process through which an unstable nuclide looses its energy due to excess of protons or neutrons is known as radioactive decay. The cause of instability of a nuclide is its inefficiency in holding the nucleus together. Tritium was used as a component of fluorescent watch dials during world war 2 To determine: The year up to which the time at night can be read using the given kind of watch.

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Last Name, Firs Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $ 4th total 21 total 4H total ZH 2H Statistical H < 3°C-H werkst - product bund abstraction here leads to the mo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Proclict 6 Number of Unique Mono-Chlorinated Products f Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary 'H H-Cl Waterfox

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Chapter 19, Problem 65AE

Interpretation Introduction

Interpretation: Use of tritium as a component of fluorescent watch dials and its half life is given. The year upto which the time at night can be read using the given kind of watch is to be calculated.

Concept introduction: A process through which an unstable nuclide looses its energy due to excess of protons or neutrons is known as radioactive decay. The cause of instability of a nuclide is its inefficiency in holding the nucleus together. Tritium was used as a component of fluorescent watch dials during world war 2

To determine: The year up to which the time at night can be read using the given kind of watch.

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Last Name, Firs Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $ 4th total 21 total 4H total ZH 2H Statistical H < 3°C-H werkst - product bund abstraction here leads to the mo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Proclict 6 Number of Unique Mono-Chlorinated Products f Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary 'H H-Cl Waterfox

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