EBK CHEMICAL PRINCIPLES
8th Edition
ISBN: 8220101425812
Author: DECOSTE
Publisher: Cengage Learning US
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Chapter 19, Problem 50E
Interpretation Introduction
Interpretation: The reason for the compounds of copper(II) being colored and copper(I) are not colored needs to be explained. Also, whether
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What are the structure for the possible stereoisomers of [Mn(H2O)2(ox)2].
Please draw the structure of the possible
product for the following reaction, and how
does the
oxidation state of metal ion formally change in
this reaction?
(a) trans-Ir(CO)C((PPH3)2 + H2 →
(b) H3C-Mn(CO)5 + P(CH3)Ph2 → (no gas
evolved)
Why is [Fe(OH2)6]3+ prepared in an acidic solution?
A. It is a Bronsted acid in aqueous solution
B. It is stabilized against reduction in acid
C. It is not soluble in water at pH = 7.0
D. All of the choices
Chapter 19 Solutions
EBK CHEMICAL PRINCIPLES
Ch. 19 - Prob. 1DQCh. 19 - Prob. 2DQCh. 19 - Prob. 3DQCh. 19 - Prob. 4DQCh. 19 - Prob. 5DQCh. 19 - Prob. 6ECh. 19 - Prob. 7ECh. 19 - What two first-row transition metals have...Ch. 19 - Prob. 9ECh. 19 - Prob. 10E
Ch. 19 - Prob. 11ECh. 19 - Prob. 12ECh. 19 - Prob. 13ECh. 19 - Prob. 14ECh. 19 - Prob. 15ECh. 19 - Define each of the following terms. a....Ch. 19 - Prob. 17ECh. 19 - When a metal ion has a coordination number of 2,...Ch. 19 - The compound cisplatin, Pt(NH3)2Cl2 , has been...Ch. 19 - Prob. 20ECh. 19 - Prob. 21ECh. 19 - Prob. 22ECh. 19 - Prob. 23ECh. 19 - Prob. 24ECh. 19 - Prob. 25ECh. 19 - Prob. 26ECh. 19 - Prob. 27ECh. 19 - Prob. 28ECh. 19 - Prob. 29ECh. 19 - Prob. 30ECh. 19 - Prob. 31ECh. 19 - Prob. 32ECh. 19 - Prob. 33ECh. 19 - Prob. 34ECh. 19 - Prob. 35ECh. 19 - Prob. 36ECh. 19 - Prob. 37ECh. 19 - For the process Co(NH3)5Cl2++Cl2Co(NH3)4Cl2++NH3...Ch. 19 - Prob. 39ECh. 19 - Prob. 40ECh. 19 - Prob. 41ECh. 19 - Prob. 42ECh. 19 - Prob. 43ECh. 19 - Prob. 44ECh. 19 - Prob. 45ECh. 19 - Prob. 46ECh. 19 - Prob. 47ECh. 19 - Prob. 48ECh. 19 - Prob. 49ECh. 19 - Prob. 50ECh. 19 - Prob. 51ECh. 19 - Prob. 52ECh. 19 - Prob. 53ECh. 19 - Consider the complex ions...Ch. 19 - Prob. 55ECh. 19 - Prob. 56ECh. 19 - How many unpaired electrons are in the following...Ch. 19 - Prob. 58ECh. 19 - Prob. 59ECh. 19 - Prob. 60ECh. 19 - Prob. 61ECh. 19 - Prob. 62ECh. 19 - Prob. 63ECh. 19 - Prob. 64ECh. 19 - Prob. 65ECh. 19 - Prob. 66ECh. 19 - Prob. 67ECh. 19 - Prob. 68ECh. 19 - Prob. 69AECh. 19 - Prob. 70AECh. 19 - Prob. 71AECh. 19 - Prob. 72AECh. 19 - Prob. 73AECh. 19 - Prob. 74AECh. 19 - Prob. 75AECh. 19 - Prob. 76AECh. 19 - Prob. 77AECh. 19 - Prob. 78AECh. 19 - Prob. 79AECh. 19 - Prob. 80AECh. 19 - Prob. 81AECh. 19 - Prob. 82AECh. 19 - Prob. 83AECh. 19 - Prob. 84AECh. 19 - Prob. 85AECh. 19 - Prob. 86AECh. 19 - Prob. 87AECh. 19 - Prob. 88AECh. 19 - Prob. 89AECh. 19 - Prob. 90AECh. 19 - Prob. 91AECh. 19 - Prob. 92AECh. 19 - Prob. 93AECh. 19 - Prob. 94AECh. 19 - Prob. 95AECh. 19 - Prob. 96AECh. 19 - Prob. 97CPCh. 19 - Prob. 98CPCh. 19 - Prob. 99CPCh. 19 - Prob. 100CPCh. 19 - Prob. 101CPCh. 19 - Prob. 102CPCh. 19 - Prob. 103CPCh. 19 - Prob. 104CP
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- The following reactions all occur in a blast furnace. Which of these are redox reactions? (a) 3Fe2O3(s)+CO(g)2Fe3O4(s)+CO2(g) (b) Fe3O4(s)+CO(g)3FeO(s)+CO2(g) (c) FeO(s)+CO(g)Fe(l)+CO2(g) (d) C(s)+O2(g)CO2(g) (e) C(s)+CO2(g)2CO(g) (f) CaCO3(s)CaO(s)+CO2(g) (g) CaO(s)+SiO2(s)CaSiO3(l)arrow_forwardPlatinum(II) forms many complexes, among them those with the following ligands. Give the formula and charge of each complex. (a) two ammonia molecules and one oxalate ion (C2O42-) (b) two ammonia molecules, one thiocyanate ion (SCN-), and one bromide ion (c) one ethylenediamine molecule and two nitrite ionsarrow_forwardWrite the formula and draw the structure of cis-tetraamminedichlorocobalt(III).arrow_forward
- Classify the metal centers in the following compounds in terms of their acidity, from hardest to softest: Mo(CO)6, MoCl3, MoCl2arrow_forwardWhich is more acidic and why? [Fe(H2O)6]2+ or [Fe(NH3)(H2O)5]2+arrow_forward[Fe(H2O)6]3+ (aq) + SCN1- ↔ Fe(H2O)5SCN]2+(aq) + heat yellow red For the above reaction, describe using Le Chatelier’s Principle what changes (color changes and shifts) would occur when each stress is applied to this equilibrium. Explain your answers. a) Add KSCN(aq) b) Decrease temperature c) Add AgNO3, which causes AgSCN to precipitate out.arrow_forward
- Write the formula for sodium diaqua-bis(oxalato)ruthenate(III).arrow_forwardMany transition metals and their compounds are used as catalysts. Given MnO2, FeCl3, Pt, and Ni, which would you select for producing CCl4 from CS2 and Cl2?arrow_forwardDraw the octahedral crystal field d orbital splitting diagrams for [Fe(OH2)6] 2+ and [Fe(CN)6] 3. Indicate if the diagrams are high spin and low spin. give the names of the d-orbitals (dxz, dxy, dzy, dz2, dx2 - y2) label the appropriate orbital sets eg* and t2g and show how the electrons populate the diagram. (Hint: Pairing energy for 3d orbitals Fe 2+ = 29875 cm-1, Fe 3+ = 19150 cm-1; delta OH for Fe(OH2)6]2+ = 14300 cm-1 and delta OH for [Fe(CN)6]3 - is 35000 cm-1arrow_forward
- 1. Draw the molecular orbital diagram for the following molecules: (a) NH3 (b) СО (c) CN 2. Explain how the backbonding occur between metal and CO ligand.arrow_forwardWhat type of isomerism is shown by [CO(NH3)5ONO]Cl2? (ii) On the basis of crystal field theory, write the electronic configuration for d4 ion if A0 < P. (iii) Write the hybridization and shape of [Fe(CN)6]3-. (Atomic number of Fe — 26)arrow_forward1. A sample of iron ore weighing 0.6428 g is dissolved in acid The iron is reduced to Fe* and titrated with 36.30 mL of a 0.1052 N solution of K,Cr207. (a) Calculate the percentage of iron (Fe) in the sample. (b) Express the percentage as Fe,03 rather than Fe. Hint: The reaction of Fe2+ with Cr,0,2 involves one electron to oxidize it to Fe*.arrow_forward
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