CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
8th Edition
ISBN: 9781305079298
Author: Masterton
Publisher: Cengage Learning
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Chapter 19, Problem 40QAP
Interpretation Introduction
Interpretation: The reason for diamagnetic nature of
Concept introduction: A transition metal cation has no outer s- electrons available for bonding, rather the inner d -electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d- orbitals according to Hund’s rule which results in a maximum number of unpaired electrons.The abbreviated electronic configuration of an element depicts the electronic configuration of the elements which represents the noble gas configuration.
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Chapter 19 Solutions
CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
Ch. 19 - Prob. 1QAPCh. 19 - Prob. 2QAPCh. 19 - Prob. 3QAPCh. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAPCh. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAPCh. 19 - Prob. 8QAPCh. 19 - Prob. 9QAPCh. 19 - Prob. 10QAP
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- Calculate the spin multiplicity for [Ni(H2O)6]2+arrow_forwardDoes either cis-[Co(en)2Cl2]+ or trans-[Co(en)2Cl2]- have optical isomers?arrow_forward[CoF6]3- absorbs 700 nm (red) radiation whereas [Co(H2O)6]3+ absorbs 600 nm (orange) radiation. Please draw the crystal field splitting of the above two complexes. Clearly label the orbitals and show the electron occupation.arrow_forward
- Indicate how many stereoisomers are possible for each compound. square planar [Pt (NH₂)₂Cl₂]: tetrahedral [NiCl₂Br]²¯: octahedral [Fe (CO) 4C1₂]: stereoisomer(s) stereoisomer(s) stereoisomer(s)arrow_forwardWhich compound do you expect to absorb the highest energy photon? [Co(H2O)6]3+ [Co(NH3)6]3+ [CoF6]-3 [Co(CN)6 ]-3arrow_forwardThe delta octahedral of [Ru(H20)6]3+ is larger than that of [Fe(H20)6]3+. Briefly explain. Answer:arrow_forward
- When water ligands in [Ti(H2O)6]3+ are replaced by CN- ligands to give [Ti(CN)6]3-, the maximum absorption shifts from 500 nm to 450 nm. Is this shift in the expected direction? Explain.arrow_forwardGiven the spectrochemical series, which of the following would absorb light of the shortest wavelength? a) [CoCl6]3- b) [Co(H2O)6]3+ c) [Co(NH3)6]3+ d) [Co(NH3)5Cl]2+ e) [Co(CN)6]3-arrow_forwardExplain why the hydrolysis of [Co(NH3)5Cl]2+ in the presence of base muchfaster than that of [Co(py)5Cl]2+? Illustrate your answer with suitable diagrams.arrow_forward
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