PRINCIPLES+REACTIONS
PRINCIPLES+REACTIONS
8th Edition
ISBN: 9781337759632
Author: Masterton
Publisher: CENGAGE L
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Chapter 19, Problem 34QAP
Interpretation Introduction

(a)

Interpretation:

The abbreviated orbital diagram and number of unpaired electrons in metal ion Cd2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s- electrons available for bonding, rather the inner d -electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d- orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(b)

Interpretation:

The abbreviated orbital diagram and number of unpaired electrons in metal ion Fe2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s- electrons available for bonding, rather the inner d -electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d- orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(c)

Interpretation:

The abbreviated orbital diagram and number of unpaired electrons in metal ion Pt2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s- electrons available for bonding, rather the inner d -electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d- orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(d)

Interpretation:

The abbreviated orbital diagram and number of unpaired electrons in metal ion Mn2+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s- electrons available for bonding, rather the inner d -electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d- orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

Interpretation Introduction

(e)

Interpretation:

The abbreviated orbital diagram and number of unpaired electrons in metal ion Ni3+ needs to be determined.

Concept introduction:

A transition metal cation has no outer s- electrons available for bonding, rather the inner d -electrons (in case of 3d transition metal elements) are available for making coordinate bonds with the ligands. Electrons are distributed in the five d- orbitals according to Hund’s rule which results in a maximum number of unpaired electrons. The abbreviated electronic configuration of an element depicts the electronic configuration of the elements by making use of noble gas configuration as they have fully-filled electron shells.

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Chapter 19 Solutions

PRINCIPLES+REACTIONS

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