BIOCHEMISTRY (LL)
9th Edition
ISBN: 9781337805100
Author: Campbell
Publisher: CENGAGE L
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Chapter 19, Problem 22RE
RECALL What are the similarities and differences between the reactions catalyzed by pyruvate dehydrogenase and
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12. When glutamic acid is heated to 180°C., it loses a molecule of water to form a
lactam. The bond that creates the lactam is an amide bond that forms between the
amino nitrogen and the carbon of the side chain -COOH group. What is the most
reasonable structure for this lactam? (NOTE: The structure of glutamic acid is shown
in Question 1.)
COOH
COOH
ا کچھ جو کچھ
C
D
COOH
B
COOH
E
COOH
10. Which one of the
following compounds is
the major organic product
of the series of reactions
shown here?
Ph
A
OH
Ph
B
CO₂Et
Br
-H
Ν ΚΑ
CO₂Et
1. NaOEt
1. NaOH, H₂O
2. H3O+
2. PhCH2CH2Br
3. heat
NH2
Ph
OH
NH2
0
OH
Ph
OH
NH2
Ph
D
NH2
E
OH
1. What is the isoelectric point of glutamic acid?
(Glutamic acid has pKa1 2.10, pKa2 4.07, pKaз 9.47)
A) pH 2.1
D) pH 6.8
B) pH 3.1
C) pH 4.1
E) pH 9.5
HO
NH2
Glutamic acid
(shown without charges)
OH
Chapter 19 Solutions
BIOCHEMISTRY (LL)
Ch. 19 - RECALL Which pathways are involved in the...Ch. 19 - RECALL How many ATPs can be produced from one...Ch. 19 - RECALL What are the different names used to...Ch. 19 - Prob. 4RECh. 19 - Prob. 5RECh. 19 - Prob. 6RECh. 19 - Prob. 7RECh. 19 - RECALL What three molecules produced during the...Ch. 19 - RECALL How many enzymes are involved in mammalian...Ch. 19 - RECALL Briefly describe the dual role of lipoic...
Ch. 19 - Prob. 11RECh. 19 - Prob. 12RECh. 19 - Prob. 13RECh. 19 - Prob. 14RECh. 19 - RECALL Why is the reaction catalyzed by citrate...Ch. 19 - RECALL What does it mean when an enzyme has the...Ch. 19 - Prob. 17RECh. 19 - RECALL With respect to stereochemistry, what is...Ch. 19 - Prob. 19RECh. 19 - Prob. 20RECh. 19 - Prob. 21RECh. 19 - RECALL What are the similarities and differences...Ch. 19 - Prob. 23RECh. 19 - Prob. 24RECh. 19 - Prob. 25RECh. 19 - RECALL Why can we say that production of a GTP is...Ch. 19 - Prob. 27RECh. 19 - RECALL ATP is a competitive inhibitor of NADH...Ch. 19 - RECALL Is the conversion of fumarate to malate a...Ch. 19 - REFLECT AND APPLY We have seen one of the four...Ch. 19 - Prob. 31RECh. 19 - Prob. 32RECh. 19 - Prob. 33RECh. 19 - Prob. 34RECh. 19 - REFLECT AND APPLY How does an increase in the...Ch. 19 - REFLECT AND APPLY How does an increase in the...Ch. 19 - Prob. 37RECh. 19 - Prob. 38RECh. 19 - Prob. 39RECh. 19 - Prob. 40RECh. 19 - REFLECT AND APPLY How could the expression milking...Ch. 19 - Prob. 42RECh. 19 - Prob. 43RECh. 19 - Prob. 44RECh. 19 - BIOCHEMICAL CONNECTIONS Why is it possible for...Ch. 19 - RECALL Describe the various purposes of the citric...Ch. 19 - REFLECT AND APPLY The intermediates of glycolysis...Ch. 19 - Prob. 48RECh. 19 - REFLECT AND APPLY Many soft drinks contain citric...Ch. 19 - RECALL NADH is an important coenzyme in catabolic...Ch. 19 - BIOCHEMICAL CONNECTIONS What are the anaplerotic...Ch. 19 - REFLECT AND APPLY Why is acetyl-CoA considered the...Ch. 19 - Prob. 53RE
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- Br Mg, ether 1. HCHO (formaldehyde) 2. H+, H₂O PCC 1. NH3, HCN ? (pyridinium chlorochromate) 2. H2O, HCI 11. Which one of the following compounds is the major organic product of the series of reactions shown above? Ph. Ph. OH NH2₂ A Ph. Ή NH2 B OH Ph Η Ph OH NH2 NH2₂ NH₂ C D Earrow_forwardB A 6. Which ONE of the labeled bonds in the tripeptide on the right is a peptide bond: H₂N N 'N' OH C H A, B, C, D or E? HN E OHarrow_forwardQuestions 8-9 are 0.4 points each. The next two questions relate to the peptide whose structure is shown here. To answer these questions, you should look at a table of H2N/.. amino acid structures. You don't have to memorize the structures of the amino acids. IZ 8. What is the N-terminal amino acid of this peptide? A) proline B) aspartic acid C) threonine 9. What is the C-terminal amino acid of this peptide? A) proline B) aspartic acid C) threonine N OH D) valine E) leucine D) valine E) leucine NH "OH OHarrow_forward
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- f. The genetic code is given below, along with a short strand of template DNA. Write the protein segment that would form from this DNA. 5'-A-T-G-G-C-T-A-G-G-T-A-A-C-C-T-G-C-A-T-T-A-G-3' Table 4.5 The genetic code First Position Second Position (5' end) U C A G Third Position (3' end) Phe Ser Tyr Cys U Phe Ser Tyr Cys Leu Ser Stop Stop Leu Ser Stop Trp UCAG Leu Pro His Arg His Arg C Leu Pro Gln Arg Pro Leu Gin Arg Pro Leu Ser Asn Thr lle Ser Asn Thr lle Arg A Thr Lys UCAG UCAC G lle Arg Thr Lys Met Gly Asp Ala Val Gly Asp Ala Val Gly G Glu Ala UCAC Val Gly Glu Ala Val Note: This table identifies the amino acid encoded by each triplet. For example, the codon 5'-AUG-3' on mRNA specifies methionine, whereas CAU specifies histidine. UAA, UAG, and UGA are termination signals. AUG is part of the initiation signal, in addition to coding for internal methionine residues. Table 4.5 Biochemistry, Seventh Edition 2012 W. H. Freeman and Company B eviation: does it play abbreviation:arrow_forwardAnswer all of the questions please draw structures for major productarrow_forwardfor glycolysis and the citric acid cycle below, show where ATP, NADH and FADH are used or formed. Show on the diagram the points where at least three other metabolic pathways intersect with these two.arrow_forward
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