Atkins' Physical chemistry
11th Edition
ISBN: 9780198814740
Author: ATKINS, P. W. (peter William), 1940- (author.)
Publisher: Oxford University Press,
expand_more
expand_more
format_list_bulleted
Videos
Question
Chapter 19, Problem 19B.4P
Interpretation Introduction
Interpretation:
The volume of hydrogen molecule required to form a monolayer has to be calculated. Also, the surface area of the copper sample has to be estimated.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Question 19
0/2 pts 3
Details
You have a mixture of sodium chloride (NaCl) and potassium chloride (KCl) dissolved in water
and want to separate out the Cl- ions by precipitating them out using silver ions (Ag+). The
chemical equation for the net ionic reaction of NaCl and KCl with silver nitrate, AgNO3, is shown
below.
Ag+(aq) + Cl(aq) → AgCl(s)
The total mass of the NaCl/KCl mixture is 1.299 g. Adding 50.42 mL of 0.381 M solution
precipitates out all of the Cl-.
What are the masses of NaCl and KCl in the mixture?
Atomic masses:
g: Mass of NaCl
g: Mass of KCL
Ag = 107.868 g
mol-
1
Cl = 35.453 g mol-
1
K = 39.098 g mol-
N = 14.007 g mol−1
Na = 22.99 g mol−1
0 = 15.999 g mol
1
Question Help: ✓ Message instructor
Submit Question
Part 1. Draw monomer units of the following products and draw their reaction mechanism (with arrow pushing)
Polyester fiber
Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol
B)pthalic anhydride + anhydrous sodium acetate + glycerol
Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any.
If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers).
If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products.
If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each)
Chapter 19 Solutions
Atkins' Physical chemistry
Ch. 19 - Prob. 19A.1STCh. 19 - Prob. 19B.1STCh. 19 - Prob. 19B.2STCh. 19 - Prob. 19D.2STCh. 19 - Prob. 19A.2DQCh. 19 - Prob. 19A.2AECh. 19 - Prob. 19A.2BECh. 19 - Prob. 19A.2PCh. 19 - Prob. 19A.4PCh. 19 - Prob. 19B.1AE
Ch. 19 - Prob. 19B.1BECh. 19 - Prob. 19B.2AECh. 19 - Prob. 19B.5AECh. 19 - Prob. 19B.5BECh. 19 - Prob. 19B.6AECh. 19 - Prob. 19B.6BECh. 19 - Prob. 19B.7AECh. 19 - Prob. 19B.7BECh. 19 - Prob. 19B.8AECh. 19 - Prob. 19B.8BECh. 19 - Prob. 19B.9AECh. 19 - Prob. 19B.9BECh. 19 - Prob. 19B.2PCh. 19 - Prob. 19B.4PCh. 19 - Prob. 19B.11PCh. 19 - Prob. 19C.1DQCh. 19 - Prob. 19C.1AECh. 19 - Prob. 19C.1BECh. 19 - Prob. 19C.1PCh. 19 - Prob. 19C.2PCh. 19 - Prob. 19C.3PCh. 19 - Prob. 19D.1DQCh. 19 - Prob. 19D.2DQCh. 19 - Prob. 19D.1AECh. 19 - Prob. 19D.1BECh. 19 - Prob. 19D.2AECh. 19 - Prob. 19D.2BECh. 19 - Prob. 19D.3AECh. 19 - Prob. 19D.3BECh. 19 - Prob. 19D.4AECh. 19 - Prob. 19D.4BECh. 19 - Prob. 19D.5BECh. 19 - Prob. 19D.6AECh. 19 - Prob. 19D.6BECh. 19 - Prob. 19D.8AECh. 19 - Prob. 19D.8BECh. 19 - Prob. 19D.2PCh. 19 - Prob. 19D.3PCh. 19 - Prob. 19D.5PCh. 19 - Prob. 19D.6PCh. 19 - Prob. 19.5IA
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 3. What starting material would you use to synthesize 3-hydroxypentanoic acid using a NaBH4 reduction?arrow_forward1. Give stereochemical (Fischer projection) formulas for all (but no extras) the stereoisomers that could theoretically form during the reduction of a. the carbonyl group of 2-methyl-3--pentanone b. both carbonyl groups of 2,4-pentanedione (careful!) 2. Predict the products of the reduction of O=CCH2CH2CH2C=O with a. LiAlH4 b. NaBH4 CH3 OHarrow_forwardWhich of the following compounds can be synthesized using one reaction from any alkene, as a major product? If it can be synthesized, propose a route, and you may use any other starting materials, reagents and solvents as needed. If you do not think that it can be synthesized as a major product from an alkene, explain in detail why.arrow_forward
- Draw the stepwise mechanism (with arrow pushing)arrow_forwarda) Explain why product 1 is the kinetic product and product 2 is the thermodynamic product. b) Draw the reaction coordinate diagram for the reaction pathway generating each product. c) State the Arrhenius Equation and explain the terms with their physical significance. d) State and explain which reaction pathway has a higher rate constant. What happens to the rate constant if the temperature has increased?arrow_forwardI just need help with A,F,G,Harrow_forward
- QUESTION 1 Write the IUPAC names for the following compounds. (a) (b) 2 H₂C CH (c) Br (d) HO (e) COOHarrow_forwardneed help finding the product of these reactionsarrow_forwardPart 1. Draw monomer units of the following products and draw their reaction mechanism 1) Bakelite like polymer Using: Resorcinol + NaOH + Formalin 2) Polyester fiber Using a) pthalic anhydride + anhydrous sodium acetate + ethylene glycol B)pthalic anhydride + anhydrous sodium acetate + glycerol 3) Temporary cross-linked polymer Using: 4% polyvinyl alcohol+ methyl red + 4% sodium boratearrow_forward
- Using the table of Reactants and Products provided provide the correct letter that corresponds with the Carboxylic acid that is formed in the reaction below. 6 M NaOH Acid-workup WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES A) Pool of Reagents for Part B CI B) OH C) E) CI J) racemic F) K) OH N) OH P) G) OH D) HO H) L) M) HO Q) R) CI Aarrow_forwardIn the table below, the exact chemical structures for Methyl salicylate can be represented by the letter WRITE THE CORRECT LETTER ONLY DO NOT WRITE EXTRA WORDS OR PHRASES CI B) A) E) Cl racemic F) J) CI K) N) OH P) Pool of Reagents for Part B OH OH G) L) OH D) HO H) M) HO Q) R) CIarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
DISTINCTION BETWEEN ADSORPTION AND ABSORPTION; Author: 7activestudio;https://www.youtube.com/watch?v=vbWRuSk-BhE;License: Standard YouTube License, CC-BY
Difference Between Absorption and Adsorption - Surface Chemistry - Chemistry Class 11; Author: Ekeeda;https://www.youtube.com/watch?v=e7Ql2ZElgc0;License: Standard Youtube License