PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
PHYSICAL CHEMISTRY. VOL.1+2 (LL)(11TH)
11th Edition
ISBN: 9780198826910
Author: ATKINS
Publisher: Oxford University Press
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Chapter 19, Problem 19A.2AE
Interpretation Introduction

Interpretation:

The argon gas pressure required to create given collision rate at 425K on circular path surface with 1.5 mm diameter has to be calculated.

Concept Introduction:

The surface which is exposed to gas gets constantly attacked that result in formation of freshly prepared surface very quickly. This quick formation can be estimated using kinetic theory of gas which derive expression for collision flux, Zw as follows,

    Zw = p(2πMkTNA)

Here,    p = Pressure

    NA = Avogadro’s number

    M = Molar mass

    k = Boltzmann’s constant

    T = Temperature.

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